Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

CHARACTERIZATION OF LACTATE DEHYDROGENASE ISOZYME PATTERN AND MORPHOLOGY OF THREE MARINE FISH CELL LINES     

郭华荣  张士璀  李红岩  童裳亮  相建海 《中国海洋湖沼学报》2002,20(3):226-231

Three continuous marine fish cell lines of FG (i. e., Hounder Gill) from flounder (Paralichthys olivaceus) gill, SPH (i. e. , Sea Perch Heart) from sea perch (Lateolabrax japonicus) heart and RSBF (i.e., Red Sea Bream Fin) from red sea bream (Pagrosomus major) fin, were characterized by lactate dehydrogenase (LDH) isozyme and morphological analysis. The LDH isozyme patterns of these three cell lines and their corresponding tissues of origin were investigated and compared. The results showed: (1) No difference was found in the LDH isozyme patterns of FG and flounder gill tissue. However, the LDH isozyme patterns of SPH and RSBF were significantly different from their corresponding tissues of origin; (2) LDH isozyme patterns of FG, SPH and RSBF were markedly different from each other and could serve as genetic markers for species identification and detection of cross contamination. Morphological change analysis of these three cell lines in comparison to their original tissues indicated that FG cells still appeared epithelioid without morphological transformation. However, morphological changes were found in SPH and RSBF compared to their original tissues. Therefore, the cellular morphology was still plastic in the relatively stable culture conditions, and it was possible that change of LDH patterns wasrelated to morphological changes of fish cells in vitro.  相似文献   

丽江高美古台址和2m级望远镜项目(英文)     

陈东  王建成  许骏  罗国权  谭徽松  刘忠  张柏荣 《天文研究与技术》2003,(Z1)

自 1992年起云南天文台开始了在云南省西北部的天文选址。丽江高美古最终被选择作为未来中国地基天文光学观测的新址点。并且 ,在国家科技部 ,云南省政府 ,以及中科院的支持下 ,2m级天文望远镜项目在 2 0 0 0年 12月获得立项。在文中 ,我们简要的介绍了高美古台址的情况 ,并给出了 2 .4m望远镜的详细情况 ,以及其他相关情况。  相似文献   

射电源0420—014,1334—127和2345—167中的视超光速运动     

沈志强  万同山  洪晓瑜 《中国天文和天体物理学报》1997,(1)

本文叙述南天区 5GHzVLBI普查中新发现的视超光速射电源 ,0 4 2 0— 0 1 4,1 334—1 2 7和 2 345— 1 67,这些结果尚待进一步的观测加以证实  相似文献   

Characteristics of Light Transmission in Summer and Winter and Its Relation to Sediment Transport in the East China Sea     

白虹  胡敦欣  庞重光 《中国海洋湖沼学报》2003,21(4):329-334

INTRODUCTIONTheSubeiShoalandtheChangjiangRiverestuarineareainthewestoftheHuanghaiandEastChinaSeasisoneofthemarginalseasintheworld ,wheresuspendedmatterisextremelyhigh .Here ,notonlyistheretheTaiwanWarmCurrentoneoftheKuroshio’sbranchesintheEastChinaSea,butalsotheHuanghaiCoastalCurrent,andChangjiangDilutedWater.Sothestrongmixingbetweenthecoastalandoffshorewaterscomplicatessuspendedmatterdistributioninthisarea.HowthesuspendedmatterdischargedfromtheChangjiangRiverandtheabandonedHuan…  相似文献   

Muon flux at the geographical South Pole     

X. Bai  T.K. Gaisser  A. Karle  K. Rawlins  G.M. Spiczak  Todor Stanev 《Astroparticle Physics》2006,25(6):361-367

The muon flux at the South Pole was measured for five zenith angles, 0°, 15°, 35°, 82.13° and 85.15° with a scintillator muon telescope incorporating ice Cherenkov tank detectors as the absorber. We compare the measurements with other data and with calculations.  相似文献   

鄂尔多斯地块构造演化的古地磁学研究   总被引：15，自引：0，他引：15       下载免费PDF全文

程国良  白云虹  孙宇航 《地震地质》1988,10(2):81

鄂尔多斯地块与中朝地台其它地区相同时代地层的古地磁结果基本一致表明:晚二叠世以来,中朝地台经历了从低纬度(19°左右)向中纬度的北移过程,并伴有50°左右的逆时针旋转;晚二叠世—中三叠世地台北移10°(1000km)左右,而方位基本未变;中三叠世—中侏罗世主要发生50°左右的逆时针旋转,而北向位移不明显,这一旋转可能与杨子地台和中朝地台碰撞拼合有关,或者说是印支运动在该地区的反应,中侏罗世—早白垩世地块已基本和现代位置一致  相似文献   

Tetraploid induced by physical and chemical methods in Jinjiang oyster(Crassostrea rivularis)   总被引：1，自引：0，他引：1  

Rong Shoubai  Shi Shumei  Mo Qirong  Liu Shaeqiong  Liang Ze  Zhao Xiuzhu  Tong Wangdong  Li Shouwu  Li Yimin 《海洋学报(英文版)》1994,13(2):275-283

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渤海三维海洋温度和海流数值预报   总被引：3，自引：2，他引：3  

刘钦政  张建华  刘煜  王旭  李燕  白珊  吴辉碇 《海洋预报》2005,22(Z1):27-34

"十·五"期间,我国开展了三维海洋温度和海流数值预报的业务化研究工作.经过3年的努力,渤海三维海洋温度和海流数值预报系统研制完成,并于2003年10月,开始试预报.本文对该预报系统以及运行情况进行了介绍,并分析了所存在的问题和发展方向.  相似文献   

A New Probability of Detection Model for Updating Crack Distribution of Offshore Structures     

李典庆  张圣坤  唐文勇 《中国海洋工程》2003,17(3)

1 .IntroductionNondestructiveinspection (NDI)isveryimportantforensuringthereliabilityofoffshorestructuresintheirservicelives (Lauraetal.,1 996 ) .Itiswellknownthatdetectionofflawsinvolvesconsider ablestatisticaluncertainties.Asaresult,theprobabilityofdetection (POD)forallflawsofagivensizehasbeenusedintheliteraturetodefinethecapabilityofaparticularNDItechniqueinagivenen vironment.SincethedataofPODusuallyscatterlargely ,itisdifficulttodeterminewhichmodelfitstheavailabledatabest.Thismodelun…  相似文献