Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

A machine learning approach for predicting computational intensity and domain decomposition in parallel geoprocessing     

Peng Yue  Fan Gao  Boyi Shangguan  Zheren Yan 《International journal of geographical information science》2020,34(11):2243-2274

ABSTRACT

High performance computing is required for fast geoprocessing of geospatial big data. Using spatial domains to represent computational intensity (CIT) and domain decomposition for parallelism are prominent strategies when designing parallel geoprocessing applications. Traditional domain decomposition is limited in evaluating the computational intensity, which often results in load imbalance and poor parallel performance. From the data science perspective, machine learning from Artificial Intelligence (AI) shows promise for better CIT evaluation. This paper proposes a machine learning approach for predicting computational intensity, followed by an optimized domain decomposition, which divides the spatial domain into balanced subdivisions based on the predicted CIT to achieve better parallel performance. The approach provides a reference framework on how various machine learning methods including feature selection and model training can be used in predicting computational intensity and optimizing parallel geoprocessing against different cases. Some comparative experiments between the approach and traditional methods were performed using the two cases, DEM generation from point clouds and spatial intersection on vector data. The results not only demonstrate the advantage of the approach, but also provide hints on how traditional GIS computation can be improved by the AI machine learning.  相似文献   

ECOLOGICAL SERIES OF SOIL ANIMALS IN DARLIDAI MOUNTAIN   总被引：1，自引：0，他引：1  

HOUWei-ling FANHong 《中国地理科学(英文版)》2002,12(4):378-382

The ecological series of soil animals under the broad-leaved and pine mixed forest in Darlidai Mountainwas studied. Seven sample plots were selected according to different altitude gradients, which belong to different vegeta-tion types. By investigating and analyzing soil animals in every sample plot it is found that there are 45 groups and 1956individuals, which axe involved in 3 phylums, 7 classes, 16 orders, respectively. The altitude is a key factor which af-fects ecological series of soil animals. Both the groups and individuals of soil animals increase with altitude increasingunder certain conditions, which contrastes with ordinary cases, resulting from special micro-climate in studied area. Thegroups and individuls of soil animals are the most under the broad-leaved and pine forest on the top of the mountain, andthe least under Picea-Abies forest in the foot of the mountain.  相似文献   

广西小平阳岩溶区地裂缝形成因素分析     

张骏  卢玉东  孙建中  范文 《地球科学与环境学报》1996,(4)

８０年代以来，广西小平阳岩溶区出现了大量的地裂缝。通过调查研究．这些地裂缝的形成是受多种因素控制的．其中包括构造、土体性质、水的作用、地形地貌、气候及植被等因素。在上述因素中．构造是主导因素，上体性质是基础因素．其它则为诱发因素，也是因地质环境要素变化所引起的因素。主导因素是通过诱发因素起作用的．并最终通过土体性质因素导致产土地裂缝。  相似文献   

富氏谱分析法模拟地壳垂直运动的地学依据及其策应力模型     

张勤  范一中 《大地测量与地球动力学》2001,21(4):76-80

应用地壳波浪与镶嵌构造学说对富氏谱分析法提取地壳垂直形变信息的科学性做了地质学意义上的阐释 ,并提出了根据多期形变资料提取特定波段上构造策应力的数学模型  相似文献   

Optical Flash of GRB 990123: Constraints on the Physical Parameters of the Reverse Shock     

Yi-Zhong Fan  Zi-Gao Dai  Yong-Feng Huang  Tan Lu Department of Astronomy  Nanjing University  Nanjing 《中国天文和天体物理学报》2002,2(5):449-453

The optical flash accompanying GRB 990123 is believed to be powered by the reverse shock of a thin shell. With the best-fit physical parameters for GRB 990123 and the assumption that the parameters in the optical flash are the same as in the afterglow, we show that: 1) the shell is thick rather than thin, and we have provided the light curve for the thick shell case which coincides with the observation; 2) the theoretical peak flux of the optical flash accounts for only 3×10~-4 of the observed. In order to remove this discrepancy, the physical parameters, the electron energy and magnetic ratios, εe and εB, should be 0.61 and 0.39, which are very different from their values for the late afterglow.  相似文献   

Silicon limitation on primary production and its destiny in Jiaozhou Bay, China——Ⅳ：Study on cross-bay transect from estuary to ocean   总被引：1，自引：0，他引：1  

Yang Dongfang  Chen Yu  Gao Zhenhui  Zhang Jing  Wang Fan 《中国海洋湖沼学报》2005,23(1):72-90

The authors analyzed the data collected in the Ecological Station Jiaozhou Bay from May 1991 to November 1994, including 12 seasonal investigations, to determine the characteristics, dynamic cycles and variation trends of the silicate in the bay. The results indicated that the rivers around Jiaozhou Bay provided abundant supply of silicate to the bay. The silicate concentration there depended on river flow variation. The horizontal variation of silicate concentration on the transect showed that the silicate concentration decreased with distance from shorelines. The vertical variation of it showed that silicate sank and deposited on the sea bottom by phytoplankton uptake and death, and zooplankton excretion. In this way, silicon would endlessly be transferred from terrestrial sources to the sea bottom. The silicon took up by phytoplankton and by other biogeochemical processes led to insufficient silicon supply for phytoplankton growth. In this paper, a 2D dynamic model of river flow versus silicate concentration was established by which silicate concentrations of 0.028–0.062 μmol/L in seawater was yielded by inputting certain seasonal unit river flows (m³/s), or in other words, the silicate supply rate; and when the unit river flow was set to zero, meaning no river input, the silicate concentrations were between 0.05–0.69 μmol/L in the bay. In terms of the silicate supply rate, Jiaozhou Bay was divided into three parts. The division shows a given river flow could generate several different silicon levels in corresponding regions, so as to the silicon-limitation levels to the phytoplankton in these regions. Another dynamic model of river flow versus primary production was set up by which the phytoplankton primary production of 5.21–15.55 (mgC/m²·d)/(m³/s) were obtained in our case at unit river flow values via silicate concentration or primary production conversion rate. Similarly, the values of primary production of 121.98–195.33 (mgC/m²·d) were achieved at zero unit river flow condition. A primary production conversion rate reflects the sensitivity to silicon depletion so as to different phytoplankton primary production and silicon requirements by different phytoplankton assemblages in different marine areas. In addition, the authors differentiated two equations (Eqs. 1 and 2) in the models to obtain the river flow variation that determines the silicate concentration variation, and in turn, the variation of primary production. These results proved further that nutrient silicon is a limiting factor for phytoplankton growth. This study was funded by NSFC (No. 40036010), and the Director's Fund of the Beihai Sea Monitoring Center, the State Oceanic Administration.  相似文献   

复杂模型重力位场快速正反演方法及应用     

李庆春  潘作枢 《地球科学与环境学报》1990,(4)

提要 本文详细讨论了一种三维重力位场快速正反演方法。作者在前人工作的基础上,对算法作了行之有效的改进,通过对反演中的不稳定因素进行各种理论模型试算,得出保证迭代反演稳定收敛的准则,编制出可在微型机IBM—PC上运行的人机对话式自动正反演程序。本文还对各种不均质模型进行了模似计算并将该方法应用于某含油气沉积盆地的双层界面构造研究,揭示出了储油有利地段。  相似文献   

CHARACTERIZATION OF LACTATE DEHYDROGENASE ISOZYME PATTERN AND MORPHOLOGY OF THREE MARINE FISH CELL LINES     

郭华荣  张士璀  李红岩  童裳亮  相建海 《中国海洋湖沼学报》2002,20(3):226-231

Three continuous marine fish cell lines of FG (i. e., Hounder Gill) from flounder (Paralichthys olivaceus) gill, SPH (i. e. , Sea Perch Heart) from sea perch (Lateolabrax japonicus) heart and RSBF (i.e., Red Sea Bream Fin) from red sea bream (Pagrosomus major) fin, were characterized by lactate dehydrogenase (LDH) isozyme and morphological analysis. The LDH isozyme patterns of these three cell lines and their corresponding tissues of origin were investigated and compared. The results showed: (1) No difference was found in the LDH isozyme patterns of FG and flounder gill tissue. However, the LDH isozyme patterns of SPH and RSBF were significantly different from their corresponding tissues of origin; (2) LDH isozyme patterns of FG, SPH and RSBF were markedly different from each other and could serve as genetic markers for species identification and detection of cross contamination. Morphological change analysis of these three cell lines in comparison to their original tissues indicated that FG cells still appeared epithelioid without morphological transformation. However, morphological changes were found in SPH and RSBF compared to their original tissues. Therefore, the cellular morphology was still plastic in the relatively stable culture conditions, and it was possible that change of LDH patterns wasrelated to morphological changes of fish cells in vitro.  相似文献   

射电源0420—014,1334—127和2345—167中的视超光速运动     

沈志强  万同山  洪晓瑜 《中国天文和天体物理学报》1997,(1)

本文叙述南天区 5GHzVLBI普查中新发现的视超光速射电源 ,0 4 2 0— 0 1 4,1 334—1 2 7和 2 345— 1 67,这些结果尚待进一步的观测加以证实  相似文献