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1.
Re-Os isotope systematics and fractionation of siderophile elements in metal phases from CBa chondrites 
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下载免费PDF全文 Nao Nakanishi Tetsuya Yokoyama Satoki Okabayashi Tomohiro Usui Hikaru Iwamori 《Meteoritics & planetary science》2018,53(5):1051-1065
We report Os isotope compositions of metal grains in two CBa chondrites (Bencubbin and Gujba) determined using a micromilling sampling coupled with thermal ionization mass spectrometry, together with the abundances of major and trace siderophile elements obtained by electron probe microanalysis and femtosecond laser ablation inductively coupled plasma–mass spectrometry. The CBa metal grains presented 187Os/188Os ratios akin to carbonaceous chondrites with limited variations (0.1257–0.1270). Most of the CBa metal grains were scattered along a 187Re-187Os reference isochron of IIIAB iron meteorites, indicating that the CBa metals experienced limited Re-Os fractionation at the time of their formation. The Re/Os ratios of sampling spots for the CBa metals, recast from the observed 187Os/188Os ratios, had a positive correlation with their Os/Ir ratios. In addition, the metal grains showed a positive correlation in a Pd/Fe versus Ni/Fe diagram. These correlations suggest that the CBa metal grains have formed via equilibrium condensation or evaporation from a gaseous reservoir at ~10−4 bar with enhanced metal abundances. Compared to the Bencubbin metals, the Gujba metals are characterized by having systematically lower Pd/Fe and Ni/Fe ratios that span subchondritic values. Such a difference was most likely induced by the compositionally heterogeneous impact plume from which the metals were condensed. 相似文献
2.
Hiroyuki Usui Akihiro Teraki Kei-ichi Okunuki Toshiaki Satoh 《International journal of geographical information science》2020,34(11):2177-2203
ABSTRACT The aim of this article is to describe a convenient but robust method for defining neighbourhood relations among buildings based on ordinary Delaunay diagrams (ODDs) and area Delaunay diagrams (ADDs). ODDs and ADDs are defined as a set of edges connecting the generators of adjacent ordinary Voronoi cells (points representing centroids of building polygons) and a set of edges connecting two centroids of building polygons, which are the generators of adjacent area Voronoi cells, respectively. Although ADDs are more robust than ODDs, computation time of ODDs is shorter than that of ADDs (the order of their computation time complexity is O(nlogn)). If ODDs can approximate ADDs with a certain degree of accuracy, the former can be used as an alternative. Therefore, we computed the ratio of the number of ADD edges to that of ODD edges overlapping ADDs at building and regional scales. The results indicate that: (1) for approximately 60% of all buildings, ODDs can exactly overlap ADDs with extra ODD edges; (2) at a regional scale, ODDs can overlap approximately 90% of ADDs with 10% extra ODD edges; and (3) focusing on judging errors, although ADDs are more accurate than ODDs, the difference is only approximately 1%. 相似文献
3.
Tidal effect on dynamics of pore water nitrate in intertidal sediment of a eutrophic Estuary 总被引：2，自引：0，他引：2
To evaluate the effect of the tidal cycle on the pore water nitrate dynamics in intertidal sediment, concentrations of inorganic
nitrogen in water and sediment were monitored during tidal cycles in the mud flat of Tama Estuary, Japan. During submergence,
nitrate concentration was highest in the overlying water and decreased monotonically with increasing depth in the sediment,
suggesting that the primary source of nitrate in the sediment was nitrate transported from the overlying water. Pore water
nitrate decreased remarkably during the initial 3–4 hours after the onset of exposure. Thereafter, it was constant or slightly
increased until tidal flooding.In situ accumulation of nitrate at the end of exposure, however, did not exceed the nitrate concentrations in the overlying water.
The inhibition of nitrate reduction and the stimulation of nitrification would explain the change of nitrate concentration,
both consistent with the input of oxygen into the sediment following a 10 mm drop of the water table. In Tama Estuary sediments,
the effect of the tidal cycle on the removal of combined nitrogen is rather negative, because high nitrate concentrations
in the overlying water canceled the positive effect of nitrate accumulation by nitrification during exposure, while tidal
oxygen intrusion have an inhibitory effection sedimentary denitrification. 相似文献
4.
Sakamoto Kei Tsujino Hiroyuki Nakano Hideyuki Urakawa Shogo Toyoda Takahiro Hirose Nariaki Usui Norihisa Yamanaka Goro 《Ocean Dynamics》2019,69(10):1181-1202
Ocean Dynamics - In order to expand the coastal ocean monitoring and forecasting system of the Japan Meteorological Agency from the Seto Inland Sea to the entire coastal seas of Japan, a 2-km... 相似文献
5.
Norihisa Usui Hiroyuki Tsujino Hideyuki Nakano Satoshi Matsumoto 《Journal of Oceanography》2013,69(6):647-670
This study investigates the long-term variability of the Kuroshio path south of Japan. Sensitivity experiments using a data-assimilative model suggest that the duration of the large meander (LM) strongly depends on the Kuroshio transport; specifically, low transport leads to a long duration of the LM. Actually, we find a good correlation between the duration of the past LMs and the Sverdrup transport estimated by a wind-driven linear baroclinic vorticity model. Then we explore favorable conditions for the LM and find a close relationship between the Kuroshio Extension (KE) state and the LM. That is, a precondition for the LM that the Kuroshio path on the Izu Ridge is fixed at a deep channel located around 34°N is achieved during a stable KE state. In addition, westward propagating signals with negative anomalies in the Kuroshio region and high sea-surface height (SSH) state east of Taiwan are key for generation of a small meander southeast of Kyushu that triggers a subsequent LM. The signals related to the above conditions change the upstream Kuroshio transport and velocity, which are consistent with features indicated by the former observational studies. Using reanalysis data, we construct long-time series of indices for the three conditions, which explain well the past LMs. The indices suggest that long-term non-LM states around 1970 and in the 1990s were attributed to a low-SSH state east of Taiwan and an unstable KE state, respectively. 相似文献
6.
Molecular-scale mechanisms of distribution and isotopic fractionation of molybdenum between seawater and ferromanganese oxides 总被引：1，自引：0，他引：1
Teruhiko Kashiwabara Yoshio Takahashi Akira Usui 《Geochimica et cosmochimica acta》2011,75(19):5762-5784
The distribution of Mo between seawater and marine ferromanganese oxides has great impacts on concentration and isotopic composition of Mo in modern oxic seawater. To reveal the adsorption chemistry of Mo to ferromanganese oxides, we performed (i) detailed structural analyses of Mo surface complexes on δ-MnO2, ferrihydrite, and hydrogenetic ferromanganese oxides by L3- and K-edge XAFS, and (ii) adsorption experiments of Mo to δ-MnO2 and ferrihydrite over a wide range of pHs, ionic strengths, and Mo concentrations. XAFS analyses revealed that Mo forms distorted octahedral (Oh) inner-sphere complexes on δ-MnO2 whereas it forms a tetrahedral (Td) outer-sphere complex on ferrihydrite. In the hydrogenetic ferromanganese oxides, the dominant host phase of Mo was revealed to be δ-MnO2. These structural information are consistent with the macroscopic behaviors of Mo in adsorption experiments, and Mo concentration in modern oxic seawater can be explained by the equilibrium adsorption reaction on δ-MnO2. In addition, the large isotopic fractionation of Mo between seawater and ferromanganese oxides detected in previous studies can be explained by the structural difference between and adsorbed species on the δ-MnO2 phase in ferromanganese oxides. In contrast, smaller fractionation of Mo isotopes on ferrihydrite is due to little change in the Mo local structures during its adsorption to ferrihydrite.The structures of Mo species adsorbed on crystalline Fe (oxyhydr)oxides, goethite, and hematite were also investigated at pH 8 and I = 0.70 M (NaNO3). Our XAFS analyses revealed that Mo forms inner-sphere complexes on both minerals: Td edge-sharing (46%) and Oh double corner-sharing (54%) for goethite, and Td double corner-sharing (14%) and Oh edge-sharing (86%) for hematite. These structural information, combined with those for amorphous ferrihydrite and δ-MnO2, show the excellent correlation with the magnitude of adsorptive isotopic fractionation of Mo reported in previous studies: the proportion of Oh species or their magnitude of distortion in Mo surface complexes become larger in the order of ferrihydrite < goethite < hematite < δ-MnO2, a trend identical to the magnitude of isotopic fractionation.Based on the comparison with previous reports for Mo surface species on various oxides, the chemical factors that affect Mo surface complex structures were also discussed. The hydrolysis constant of cation in oxides, log KOH (or the acidity of the oxide surfaces, PZC) is well correlated with the mode of attachment (inner- or outer-sphere) of Mo surface complexes. Furthermore, the symmetric change in Mo species from Td to Oh is suggested to be driven by the formation of inner-sphere complexes on specific sites of the oxide surfaces. 相似文献
7.
Hiroyuki Usui Yasushi Asami 《International journal of geographical information science》2018,32(1):120-139
The size distribution of urban blocks is important for the characterisation of urban block patterns and is known to follow several parametric statistical distributions. However, it has not previously been analysed on the basis of a normative plane tessellation and in terms of urban block density and mean road width. In this article, we formulate the size distribution of Voronoi cells using the gamma distribution estimated by urban block density and mean road width. We found that (1) both log-normal and gamma distributions can be good candidates for the size distribution of urban blocks at the scale of a region that consists of regular urban blocks and that has a uniform road width; and (2) the size distribution of urban blocks depends on the balance between pattern and width improvement effects. Based on one study region in Tokyo, if the pattern improvement effect is more prominent than the width improvement effect, the mode of urban block sizes tends to be larger than if it is not. These findings are expected to provide scientific support for urban planning (e.g. land readjustment projects). 相似文献
8.
At four stations in Tokyo Bay, pore water profiles of dissolved organic carbon (DOC), nitrogen (DON), phosphorus (DOP), and inorganic nutrients were determined at 3-month intervals over 6 years. Concentrations of dissolved organic matter (DOM) and nutrients were significantly higher in pore waters than in the overlying waters. Pore water DOC, DON, and DOP concentrations in the upper most sediment layer (0–1 cm) ranged from 246 to 888 μM, from 14.6 to 75.9 μM, and from 0.02 to 9.83 μM, respectively. Concentrations of DOM and nutrients in pore waters occasionally showed clear seasonal trends and were highest in the summer and lowest in the winter. The seasonal trends in the pore water DOM concentrations were coupled with trends in the overlying water temperature and dissolved oxygen concentration. Benthic effluxes of DON and DOP were low compared with those of inorganic nutrients, accounting for only 1.0 and 1.5 % of the total benthic effluxes of nitrogen and phosphorus, respectively; thus benthic DOM fluxes were quantitatively insignificant to the inorganic nutrient fluxes in Tokyo Bay. The DOM fluxes represented about 7, 3, and 10 % of the riverine discharge of DOC, DON, and DOP to Tokyo Bay, respectively. 相似文献
9.
Which is more important for tropical cyclone (TC) intensity and intensification, sea surface temperature (SST) or tropical cyclone heat potential (TCHP)? Investigations using best-track TC central pressures, TRMM/TMI three-day mean SST data, and an estimated TCHP based on oceanic reanalysis data from 1998 to 2004, show that the central pressure is more closely related to TCHP accumulated from TC formation to its mature stages than to the accumulated SST and its duration. From an oceanic environmental viewpoint, a rapid deepening of TC central pressure occurs when TCHP is relatively high on a basin scale, while composite distributions of TCHP, vertical wind shear, lower tropospheric relative humidity, and wind speed occurring in cases of rapid intensification are different for each TC season. In order to explore the influence of TCHP on TC intensity and intensification, analyses using both oceanic reanalysis data and the results of numerical simulations based on an ocean general circulation model are performed for the cases of Typhoons Chaba (2004) and Songda (2004), which took similar tracks. The decrease in TCHP due to the passage of Chaba led to the suppression of Songda’s intensity at the mature stage, while Songda maintained its intensity for a relatively long time because induced near-inertial currents due to the passage of Chaba reproduced anticyclonic warm eddies appearing on the leftside of Chaba’s track before Songda passed by. This type of intensity-sustenance process caused by the passage of a preceding TC is often found in El Niño years. These results suggest that TCHP, but not SST, plays an important role in TC intensity and its intensification. 相似文献
10.
Tomohiro Usui Matthew Sanborn Harry Y. McSween Jr. 《Geochimica et cosmochimica acta》2010,74(24):7283-7306
Shergottites sampled two distinct geochemical reservoirs on Mars. Basaltic and olivine-phyric shergottites individually sampled both geochemically enriched and depleted reservoirs, whereas lherzolitic shergottites are previously known only to exhibit a relatively limited intermediate geochemical signature that may have resulted from the mixing of the two geochemical end-member reservoirs. Here we show that recently discovered shergottites Robert Massif (RBT) 04261 and RBT 04262 are the first examples of lherzolitic shergottites originating from the enriched reservoir.RBT 04261 and RBT 04262, initially identified as olivine-phyric shergottites, are actually lherzolitic shergottites. Both meteorites exhibit nearly identical textures and mineral compositions, suggesting that they should be paired. Each consists of two distinct textures: poikilitic and non-poikilitic. The poikilitic areas are composed of pyroxene oikocrysts enclosing olivine grains; all pyroxene oikocrysts have pigeonite cores mantled by augite. The non-poikilitic areas are composed of olivine, pyroxene, maskelynite and minor amounts of merrillite, chromite and ilmenite. Olivine and pyroxene show the lowest Mg-number, and maskelynite has the lowest anorthite component among the lherzolitic shergottites. Moreover, the modal abundances of maskelynite in these two meteorites are distinctly higher than the other lherzolitic shergottites.The rare earth element (REE) budgets of RBT 04261 and RBT 04262 are dominated by merrillite. The slightly light rare earth element (LREE)-enriched pattern of this mineral is similar to that of merrillite in the geochemically enriched basaltic shergottites Shergotty and Zagami, and unlike the LREE-depleted pattern of merrillite in the other lherzolitic shergottites. The REE patterns of both high- and low-Ca pyroxenes are also similar to those in Shergotty and Zagami. The REE pattern of a melt calculated to be in equilibrium with the core of a pyroxene oikocryst is parallel to that of the RBT 04262 whole-rock as well as whole-rock compositions of other geochemically enriched basaltic shergottites. These observations imply that RBT 04262 sampled an enriched and oxidized reservoir similar to that sampled by some of the basaltic shergottites and are consistent with an oxidizing condition for the formation of RBT 04262 (log fO2 = QFM-1.6).The petrographic and geochemical observations presented here suggest that RBT 04261 and RBT 04262 represent the most evolved magma among the lherzolitic shergottites and that this magma originated from a geochemically enriched reservoir on Mars. Based on an evaluation of the relationship between petrographic, geochemical and chronological signatures for shergottites including RBT 04261 and RBT 04262, we propose that both geochemically enriched and depleted shergottites were ejected from the same launch site on Mars. 相似文献