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Groundwater mixing between different aquifer types in a complex structural setting discerned by elemental and stable isotope geochemistry 
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下载免费PDF全文 Karst aquifers are well known for their intricate stratigraphy and geologic structures, which make groundwater characterization challenging because flowpaths and recharge sources are complex and difficult to evaluate. Geochemical data, collected from ten closely spaced production wells constructed in two karst aquifers (Bangor Limestone (Mb) and Tuscumbia Limestone/Fort Payne Chert (Mftp)) in Trussville, north‐central Alabama, illustrate two distinctive groundwater end‐members: (1) higher major ion, dissolved inorganic carbon, conductivity, alkalinity concentrations, heavier δ13C ratios (max: −10.2 ± 0.2‰ Vienna Pee Dee Belemnite (PDB)) and lower residence times (mean: 19.5 ± 2 years, n = 2) of groundwater in the Mb aquifer and (2) lower constituent concentrations, lighter δ13C ratios (min: −13.4 ± 0.2‰ PDB) and longer residence times of groundwater (mean: 23.6 ± 2 years, n = 4) in the Mftp aquifer. Summer and fall data and the binary mixing model show aquifer inter‐flow mixing along solution fractures and confirms the distinctive groundwater geochemistry of the two aquifers. Lowering of static water levels over the summer (drawdown from 2 to 5.2 m) leads to more reducing groundwater conditions (lower Eh values) and slightly enriched δ18O and δD ratios during the fall [δ18O: −4.8 ± 0.1 to −5.4 ± 0.1‰ Vienna Standard Mean Oceanic Water (VSMOW), n = 9; δD: −25.4 ± 1 to −27.4 ± 1‰ VSMOW, n = 9] when compared with summer season samples (δ18O: −5.1 ± 0.1 to −5.7 ± 0.1‰ VSMOW, n = 11; δD: −25.0 ± 1 to −30.6 ± 1‰ VSMOW, n = 11). GIS analyses confirm the localized origin of recharge to the investigated aquifers. The combination of GIS, field parameters and geochemistry analyses can be successfully used to identify recharge sources, evaluate groundwater flow and transport pathways and to improve understanding of how groundwater withdrawals impact the sustainability and susceptibility to contamination of karst aquifers. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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Assessing the extent and sources of nitrate contamination in the aquifer system of southern Baldwin County,Alabama 总被引：1，自引：0，他引：1
A regional-scale groundwater study was conducted over a 2-year period to assess the extent of nitrate contamination and source
identification for southern Baldwin County, AL. Groundwater wells were sampled and analyzed for nitrate and a host of other
geochemical parameters which revealed that extensive areas within aquifer zone A2 exhibited nitrate concentrations exceeding
regulatory limits. Spatial iso-concentration maps of nitrate were constructed using ArcGIS software to determine the extent
and severity of contamination for the aquifers underlying southern Baldwin County with the primary interest focused on the
heavily utilized aquifer zone A2. Nitrate levels in the central and northeastern portion of the study area were most extensive
with maximum concentrations of 63 mg/L likely resulting from agricultural inputs. Several other small regions throughout the
study area exhibited elevated levels of nitrate and chloride as high as 112 and 51.1 mg/L, respectively, and sources likely
vary (i.e., residential septic systems, animal waste to agriculture). With the exception of a few groundwater samples, there
was no obvious correlative relationship between chloride and nitrate concentration for data collected during the 2-year period.
Collectively, a general inverse relationship between nitrate concentrations and well depth was observed for the aquifer system
under investigation. The study provides an initial current data set of areas impacted or most vulnerable to nitrate contamination
and initial assessment of likely sources of nitrate in the region. 相似文献
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Sea level rise (SLR) as a result of global warming has an impact on the increasing inundation on the coastal area. Nowadays,
Semarang coastal area in Indonesia is already subject to coastal hazard due to tidal inundation and land subsidence. The impact
of the inundation is predicted to be even more severe with the scenario of sea level rise. This paper concentrates on the
risk assessment to the population, land use, and monetary losses as a result of coastal inundation under enhanced sea level
rise. This paper uses the scenario of the depth of inundation to generate coastal inundation model using GIS-Technology. Anticipatory
issues including methodology development for hazard assessment would be necessary for Semarang coastal area, and therefore,
geo-information technology can be considered as a useful tool to rapidly assess the impact of the coastal hazard and evaluate
the economic losses. 相似文献
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Liviu?Mihai?Irimia Cristian?Valeriu?PatricheEmail author Hervé?Quenol Lucian?Sf?c? Chris?Foss 《Theoretical and Applied Climatology》2018,131(3-4):1069-1081
Climate change is causing important shifts in the suitability of regions for wine production. Fine scale mapping of these shifts helps us to understand the evolution of vineyard climates, and to find solutions through viticultural adaptation. The aim of this study is to identify and map the structural and spatial shifts that occurred in the climatic suitability for wine production of the Cotnari wine growing region (Romania) between 1961 and 2013. Discontinuities in trends of temperature were identified, and the averages and trends of 13 climatic parameters for the 1961 to 1980 and 1981 to 2013 time periods were analysed. Using the averages of these climatic parameters, climate suitability for wine production was calculated at a resolution of 30 m and mapped for each time period, and the changes analysed. The results indicate shifts in the area’s historic climatic profile, due to an increase of heliothermal resources and precipitation constancy. The area’s climate suitability for wine production was modified by the loss of climate suitability for white table wines, sparkling wines and wine for distillates; shifts in suitability to higher altitudes by about 67 m, and a 48.6% decrease in the area suitable for quality white wines; and the occurrence of suitable climates for red wines at lower altitudes. The study showed that climate suitability for wine production has a multi-level spatial structure, with classes requiring a cooler climate being located at a higher altitude than those requiring a warmer climate. Climate change has therefore resulted in the shift of climate suitability classes for wine production to higher altitudes. 相似文献
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Paolo Soleri Valeriu Tudose Rob Fender Michiel van der Klis Peter G. Jonker 《Monthly notices of the Royal Astronomical Society》2009,399(1):453-464
We present the results of simultaneous X-ray and radio observations of the peculiar Z-type neutron star X-ray binary Cir X-1, observed with the Rossi X-ray Timing Explorer satellite and the Australia Telescope Compact Array in 2000 October and 2002 December. We identify typical Z-source behaviour in the power density spectra as well as characteristic Z patterns drawn in an X-ray hardness–intensity diagram. Power spectra typical of bright atoll sources have also been identified at orbital phases after the periastron passage, while orbital phases before the periastron passage are characterized by power spectra that are typical neither of Z nor of atoll sources. We investigate the coupling between the X-ray and the radio properties, focusing on three orbital phases when an enhancement of the radio flux density has been detected, to test the link between the inflow (X-ray) and the outflow (radio jet) to/from the compact object. In two out of three cases, we associate the presence of the radio jet to a spectral transition in the X-rays, although the transition does not precede the radio flare, as detected in other Z sources. An analogous behaviour has recently been found in the black hole candidate GX 339-4. In the third case, the radio light curve shows a similar shape to the X-ray light curve. We discuss our results in the context of jet models, considering also black hole candidates. 相似文献
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The present study tests the usefulness of SoLIM software and GIS techniques for the reconstruction of large vegetation formations from the mid-Holocene period in Romania. We used current reference climate data (temperature, precipitation) and the current extent of ecological regions in Romania to derive climate optimality functions for each vegetation formation. The optimality functions were used to simulate current and past distributions of vegetation. The results showed that the current and mid-Holocene simulated spatial distributions of vegetation are quite similar. Changes were found for about 14% of the Romanian territory (33 946 km2), the most important being the retreat of coniferous forests in favor of mixed forests and of mixed forests in favor of forest steppe. The former is validated by previous pollen-based studies showing the transition from coniferous forests to mixed forests that occurred in several areas of the country after the mid-Holocene. The study demonstrates the potential of this methodological approach to reconstruct past vegetation formations, and at the same time that it is a straightforward and expert knowledge-based method. Although our application uses only climate factors, the results can be further refined by incorporating additional drivers (soil and landform information, site-specific pollen and fossil data, wildfire data) for a more accurate inference of paleovegetation. 相似文献
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Traditional aquifer vulnerability techniques primarily rely on spatial property data for a region and are limited by their ability to directly or indirectly assess flow and transport processes occurring from the surface to depth within an aquifer system. The main objective of this study was to investigate groundwater vulnerability in terms of aquifer interconnectivity and flow dynamics. A combination of stable isotopes, groundwater age‐dating (radiocarbon), and geomorphic/geogenic spatial analyses was applied to a regional, highly developed coastal aquifer to explain the presence of nitrate at depth. The average δ13C value (?17.3 ± 2‰ VPDB, n = 27) is characteristic of groundwater originating from locally infiltrated precipitation through extensively cultivated soils. The average δ18O and δD values (?4.0 ± 0.1‰ VSMOW, n = 27; δD: ?19.3 ± 1‰ VSMOW, n = 27, respectively) are similar to precipitation water derived from maritime sources feeding the region's surface water and groundwater. Stable and radioactive isotopes reveal significant mixing between shallow and deep aquifers due to high velocities, hydraulic connection, and input of local recharge water to depths. Groundwater overdevelopment enhances deeper and faster modern water downward flux, amplifying aquifer vulnerability. Therefore, aquifer vulnerability is a variable, dependent on the type and degree of stress conditions experienced by a groundwater system as well as the geospatial properties at the near surface. 相似文献
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A two‐dimensional variable‐density groundwater flow and transport model was developed to provide a conceptual understanding of past and future conditions of nitrate (NO3) transport and estimate groundwater nitrate flux to the Gulf of Mexico. Simulation results show that contaminant discharge to the coast decreases as the extent of saltwater intrusion increases. Other natural and/or artificial surface waters such as navigation channels may serve as major sinks for contaminant loading and act to alter expected transport pathways discharging contaminants to other areas. Concentrations of NO3 in the saturated zone were estimated to range between 30 and 160 mg?L?1 as NO3. Relatively high hydraulic vertical gradients and mixing likely play a significant role in the transport processes, enhancing dilution and contaminant migration to depth. Residence times of NO3 in the deeper aquifers vary from 100 (locally) to about 300 years through the investigated aquifer system. NO3 mass fluxes from the shallow aquifers (0 to 5.7 × 104 mg?m?2?day?1) were primarily directed towards the navigation channel, which intersects and captures a portion of the shallow groundwater flow/discharge. Direct NO3 discharge to the sea (i.e. Gulf of Mexico) from the shallow aquifer was very low (0 to 9.0 × 101 mg · m?2?day?1) compared with discharge from the deeper aquifer system (0 to 8.2 × 103 mg?m?2?day?1). Both model‐calibrated and radiocarbon tracer‐determined contaminant flux estimates reveal similar discharge trends, validating the use of the model for density‐dependent flow conditions. The modelling approach shows promise to evaluate contaminant and nutrient loading for similar coastal regions worldwide. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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Patriche Cristian Valeriu Irimia Liviu Mihai 《Theoretical and Applied Climatology》2022,148(3-4):1035-1056
Theoretical and Applied Climatology - Climate change affects the viticulture sector worldwide in different ways, some countries reporting negative impacts, other positive effects, depending on the... 相似文献
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