Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

基于噪声谱比法的内蒙古西部地区台站场地响应研究     

张珂  王鑫  王树波  张红才  宋晓燕 《大地测量与地球动力学》2020,40(6):646-651

利用内蒙古西部12个台站的地脉动噪声数据，采用噪声谱比法研究台站的场地响应情况。分析表明，台站场地响应按曲线形态可分为3类，且可能受地形地貌、局部构造和台基状况等条件影响。对比分析噪声谱比法与Moya方法的场地响应结果发现，场地响应曲线形态基本一致，只有极少数台站存在明显差异。结果表明，内蒙古西部区域大部分台站的台基状况总体较好，场地响应曲线较为平坦，无明显频率放大点。  相似文献   

太阳发电机理论研究进展     

姜杰  汪景琇 《天文学进展》2005,23(2):121-134

太阳发电机理论主要解释太阳磁场的起源和演化，是太阳物理中最基本、最重要的问题之一．对它的研究不仅具有重要的科学价值，而且对空间天气的预测和空间技术的发展有一定的影响．随着日震学的发展，该理论也得到了很大改进。从相关观测入手，综述了发电机理论需解释的观测事实，以及为发电机理论提供约束的太阳内部动力学结构；介绍了基本理论和近来的主流模型，并指出尚待解决的问题和进一步的努力方向。  相似文献   

济宁市嘉祥县石灰岩矿山地质环境评价与治理   总被引：1，自引：0，他引：1       下载免费PDF全文

贾德旺  吕宝平  贺汉庭  王学森  范纯信 《山东国土资源》2006,22(5):54-57

在对嘉祥县石灰岩矿进行地质灾害危险性评估、矿山环境地质问题评价的基础上,建立了一套评价体系,其中地质灾害危险性评估分为2个评价指标,矿山环境地质问题评价分为2种要素3个指标,同时将矿山恢复治理难易程度也作为一个评价因子。评价过程中对各指标危害性大、中、小程度均单独赋值,然后将各指标的分值进行叠加,确定出矿山环境地质问题的等级,将概划出的13个评价单元分为极差、差、一般3个区。提出了强化矿山管理、植树造林、科学避让、修建拦水坝等保护与治理措施及建议。  相似文献   

重庆地面最高气温与最大风速年极值的渐近分布   总被引：3，自引：0，他引：3  

孟庆珍  王增武  冯新  梁秋枫 《成都信息工程学院学报》2004,19(3):436-441

利用重庆1951-1990年间地面最高气温和1956-1990年间地面最大风速年极值的记录,采用韦伯分布和耿贝尔分布分别对其渐近分布进行拟合.通过统计推断,找出重庆地面最高气温和地面最大风速年极值遵循的最佳渐近分布--韦伯分布.  相似文献   

王文升同志在全省国土资源工作座谈会暨全省土地调查工作会议上的讲话          下载免费PDF全文

王文升 《山东国土资源》2004,20(2):1-5

同志们:这次全省国土资源工作座谈会,是经省政府同意召开的。主要任务是传达学习中央人口资源环境工作座谈会和全国国土资源厅长座谈会精神,围绕树立和落实科学发展观,研究部署当前国土资源重点工作。赵克志副省长对这次会议十分重视,亲自到会并将作重要讲话。我们一定要认真抓好贯彻落实。下面,根据省厅党组研究的意见,我讲三个方面的问题。一、深刻领会中央精神,把握大局,坚持以科学发展观指导国土资源工作全国“两会”期间,中央召开人口资源环境工作座谈会,胡锦涛总书记、温家宝总理在会上发表了重要讲话,全面阐述了科学发展观的深刻内涵…  相似文献   

DISTRIBUTION OF 2-D MAGNETIC SADDLE POINTS AND MORPHOLOGY OF FLARE KERNELS IN SOLAR ACTIVE REGIONS     

Huaning  WANG 《Solar physics》1997,174(1-2):265-279

We extrapolated the 3-D fields above the photosphere, taking the observed photospheric magnetic fields in the active regions NOAA 6659 and 7321 as the boundary conditions of a linear force-free field model, and detected the singular points of the 2-D fields in a plane at the chromospheric level. These singular points can be described with the Poincaré index. Singular points with the index of +1 correspond to concentrations of magnetic flux, and those with the index of -1 to the saddle points in the plane. All of these singular points are connected by the lanes demarcating the 2-D magnetic cells in the plane. It has been confirmed that these saddle points are the intersections between separators and planes intersecting the 3-D fields. From comparisons between kernels of flares occurring in both regions and the saddle points, we found that there is a close morphological relationship between distributions of the saddle points and flare kernels. The main results are as follows: (a) The flare kernels tend to appear in areas with concentrating 2-D saddle points. (b) The morphology of the kernels is exactly confined by the lanes in the plane at chromospheric level. These facts seem favourable for the viewpoint that solar flares are closely related to magnetic separatrices and separators.  相似文献   

海岩小说的几种叙述模式及弊端     

姚国军  李霞 《广东海洋大学学报》2006,26(5):87-90

海岩的长篇小说《河流如血》再创出版高记录，但作家仍局限于特有的小说叙述模式，这部作品设能做到相应的创新。概言之，模式第一面是“刑侦＋恋爱”；模式第二面是“财子＋佳人”；模式第三面是“道德＋法制”。文学创作需要不断创新，创新的过程也是对创作模式的不断突破过程。作家应该警惕的是，不要让模式成为创作的桎梏。  相似文献   

小行星(360)Carlova自转参数的测定     

王晓彬  张西亮 《天文学报》2006,47(2):202-211

小行星自转参数的资料不仅可以为小行星碰撞演化提供数据,还可以为太阳系的演化研究提供依据．利用云南天文台1米望远镜对主带碳类小行星(360)Carlova进行了新的CCD测光观测,结合前人的测光资料,利用Epoch-方法对(360)的自转参数进行了反演计算,得到该小行星自转的恒星周期为0．25780417±0．00000003天,自转轴的黄道坐标为(95°±3,°40°±1°)．新的结果与前人的结果相比较为一致,其精度稍高于以前的估算结果．  相似文献   

胶东“玲珑-焦家式”金矿资源潜力与找矿   总被引：1，自引：1，他引：0  

李士先  王建收 《山东国土资源》2006,22(12):36-41

“玲珑焦家式”金矿的成岩成矿,从新太古代至中生代存在着继承性的成因关系,成矿具有长期性、多源性特点,但中生代燕山早期岩浆活动是主导成矿因素。区域化探成果显示胶东金矿直接矿源岩———郭家岭花岗岩金的丰度比原始矿源岩———早前寒武纪变质沉积岩系及侵入岩系金的丰度低1/2。郭家岭花岗岩面积在2 km2以上岩体定量估计金亏损总量与胶东金矿总量预测的资源量相当,从一个侧面展现了胶东金矿资源的潜力。望儿山金矿的找矿实践展示,焦家式金矿在1 000 m以下尚有巨大潜力,整个胶东金矿产区在3 000 m以上的资源潜力应在5000 t以上。  相似文献