排序方式： 共有63条查询结果，搜索用时 31 毫秒
1.
A.R. Salgueiro P. Freire vila H. Garcia Pereira J.M. Santos Oliveira 《Journal of Geochemical Exploration》2008,98(1-2):15
Based on an environmental geochemistry case study carried out in the neighbourhood of a W–Sn abandoned mine, the pollution in stream sediments was modelled through a Global Contamination Index. Such an index permits one to summarize the combination of deleterious elements in a single variable, obtained by the projection of samples onto the first axis of a PCASD (Principal Components Analysis of Standardized Data) applied to the entire n × p matrix containing the available concentrations of p = 16 elements in the set of n = 220 collected samples.In order to provide a sound basis for a coherent planning of the remediation process which will be put in operation in the affected area, it is necessary to balance the costs of reclaiming with the probabilities of exceeding the upper limits accepted for concentrations of environmentally harmful elements in sediments. Given these limits, they are back-transformed in the index values, providing a practical threshold between ‘clean’ and ‘contaminated’ samples. On the other hand, the minimum dimension of the cell to be reclaimed is restrained by the selected remediation process to be applied in the affected area. Hence, to meet the constraints of such a remediation process, it is required to estimate the probabilities of exceeding the index threshold in technologically meaningful sub-areas. For this end, the Indicator Block Kriging technique was applied, producing a series of maps where sub-areas to be reclaimed can be spotted for different probability levels. These maps, on which the decision making remediation agency can rely for its cost-benefit analysis, take into account both the spatial structure of ‘clean’ vs. ‘contaminated’ samples and the constraints of the reclaiming process. 相似文献
2.
Melchor Gonzlez-Dvila J. Magdalena Santana-Casiano Demetrio de Armas Jos Escnez Miguel Suarez-Tangil 《Marine Chemistry》2006,99(1-4):177
Measurements of surface partial pressure of CO2 and water column alkalinity, pHT, nutrients, oxygen, fluorescence and hydrography were carried out, south of the Canary Islands during September 1998. Cyclonic and anticyclonic eddies were alternatively observed from the northwestern area to the central area of the Canary Islands. Nutrient pumping and vertical uplifting of the deep chlorophyll maximum by cyclonic eddies were also ascertained by upward displacement of dissolved inorganic carbon. A model was applied to determine the net inorganic carbon balance in the cyclonic eddy. The fluxes were determined considering both the diffusive and convective contributions from the upward pumping and the corresponding horizontal transport of water outside the area. An increase in the total inorganic carbon concentration in the upper layers inside the eddy field of 133 mmol C m− 2 d− 1 was determined. The upward flux of inorganic carbon decreased the effect of the increased primary production on the carbon dioxide chemistry. The reduced fCO2 inside the cyclonic eddy, 15 μatm lower than that observed in non-affected surface water, was explained by thermodynamic aspects, biological activity, eddy upward pumping and diffusion and air–sea water exchange effects. 相似文献
3.
Frederico Sousa Guimares Alexandre Raphael Cabral Bernd Lehmann Francisco Javier Rios Moiss Augusto Bacellar vila Marco Paulo de Castro Glucia Nascimento Queiroga 《地学学报》2019,31(4):358-365
Native bismuth in the form of metallic melt has been considered instrumental to the formation of some metallic ore deposits via a mechanism dubbed the “Liquid Bismuth Collector Model.” Here, we provide petrographical documentation of trail‐forming, μm‐sized blebs of native bismuth in cassiterite–quartz veins from the Santa Bárbara greisen Sn deposit in the Rondônia tin province of northern Brazil. These inclusions suggest the trapping of a Bi melt that took place during vein formation, in a mechanism similar to the entrapment of fluid inclusions. 相似文献
4.
5.
The results of an extensive study of streamwater chemistry during stormflow events, for a montane Mediterranean area, are presented. Four groups of variables are identified as having contrasting behaviour: alkalinity and pH; nitrate and potassium; sulphate and chloride; sodium, calcium and magnesium. The results show a complex pattern of response to flow that can be broadly linked to: (1) antecedent hydrological conditions; (2) rainfall intensity; (3) supplies of water from chemically distinct areas within the catchment. However, comparisons between this study and a parallel one which examined the composition of waters within the catchment, show that it is presently impossible to quantify the relative supplies from each part of the catchment. The findings are reviewed in relation to analogous studies within a European setting and in relation to modelling initiatives. 相似文献
6.
Vyacheslav M. Zobin Carlos J. Navarro-Ochoa Gabriel A. Reyes-Dávila 《Bulletin of Volcanology》2006,69(2):141-147
In July–August 2003, the andesitic lava dome at Volcán de Colima, México, was destroyed by a sequence of explosions that replaced the 2×106 m3 dome with a crater 200 m across and 30 m deep. The two strongest explosions occurred on July 17 and August 28. The initial low-frequency impulses that they produced, which were recorded on broadband seismic records, allowed an estimation of the counter forces of the initiating process as being equal to 0.3×1011 N and 1×1011 N for the July and August events, respectively. The seismic characteristics follow the Nishimura-Hamaguchi scaling law for volcanic explosions, reflecting self-similarity in the processes initiating explosive events. The results also show that counter forces can discriminate between the sizes of explosive eruptions that are assigned the same magnitude by conventional methods of classification such as the Volcanic Explosivity Index. The increasing use of broadband seismometers may therefore provide the basis for using counter forces to determine the magnitude of explosive eruptions. 相似文献
7.
M. Gonzlez-Dvila J.M. Santana-Casiano A.G. Gonzlez N. Prez F.J. Millero 《Marine Chemistry》2009,115(1-2):118-124
The oxidation and reduction of nanomolar levels of copper in air-saturated seawater and NaCl solutions has been measured as a function of pH (7.17–8.49), temperature (5–35 °C) and ionic strength (0.1–0.7 M). The oxidation rates were fitted to an equation valid at different pH and ionic strength conditions in sodium chloride and seawater solutions:The reduction of Cu(II) was studied in both media for different initial concentrations of copper(II). When the initial Cu(II) concentration was 200 nM, the copper(I) productions were 20% and 9% for NaCl and seawater, respectively. The effect of speciation of copper(I) reduced from Cu(II) on the rates was studied. The Cu(I) speciation is dominated by the CuCl2− species. On the other hand, the neutral chloride CuCl species dominates the Cu(I) oxidation in the range of 0.1 M to 0.7 M chloride concentrations. 相似文献
8.
Sérgio P. Ávila Patrícia Madeira C. Marques da Silva Mário Cachão Bernard Landau Rui Quartau A. M. de Frias Martins 《第四纪科学杂志》2008,23(8):777-785
The Pleistocene (Eemian) outcrops of Lagoinhas and Prainha, located at Santa Maria Island (Azores), were investigated and their fossil mollusc content reported. These studies revealed that the last glaciation affected two groups of molluscs: the ‘warm‐guest’ gastropods with West African or Caribbean affinities (e.g. Conus spp., Cantharus variegatus, Bulla amygdala, Trachypollia nodulosa) and shallow bivalve species mainly associated with sandy habitats (Ensis minor, Lucinella divaricata, and probably Laevicardium crassum). In this paper we focus on this group of bivalves, which has since locally disappeared from the Azores. We relate the local disappearance of these bivalves in the Azores with the lack of sand in the shelf. The specific characteristics of the Santa Maria shelf combined with the sea‐level drop during the Weichselian prevented deposition of the lowstand deposits and permitted erosion of the previous ones, leaving the shelf without a sediment cover. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
9.
Matúš Hyžný Carlos S. Melo Ricardo S. Ramalho Ricardo Cordeiro Patrícia Madeira Lara Baptista A. Cristina Rebelo Cynthia Gómez Alfred Uchman Markes E. Johnson Björn Berning Sérgio P. Ávila 《第四纪科学杂志》2021,36(1):91-109
The presence of decapod crustaceans in the Pliocene and Pleistocene (MIS 5e) fossil record of Santa Maria Island (Azores Archipelago) is herein reviewed. Our study raises the number of fossil decapods from this island from one species to 10 taxa (three for the Pliocene and seven for the Last Interglacial). Four of these 10 taxa are reported for the first time in the fossil record, worldwide. A new species of a mud shrimp is also described (Upogebia azorensis n. sp.). Our study suggests that the Plio–Pleistocene decapod assemblages of the Azores did not differ significantly from modern ones, being dominated by species that are today widespread across the Webbnesia ecoregion, the Mediterranean Sea, and the eastern Atlantic shores, including the Azores. As far as can be judged from the limited fossil record, apparently no tropical crab species with a Cabo Verdean/Senegalese provenance reached the Azores during windows of opportunity associated with Glacial Termination 2 or with the initial setting of the Last Interglacial period. This contribution increases the total number of marine taxa reported for the Pliocene and Pleistocene outcrops of Santa Maria Island to 218 and 155, respectively, highlighting the scientific relevance of its palaeontological heritage. 相似文献
10.
Federico M. Dávila Mario E. Giménez Julieta C. Nóbile M. Patricia Martínez 《Basin Research》2012,24(6):615-636
The Pipanaco Basin, in the southern margin of the Andean Puna plateau at ca. 28°SL, is one of the largest and highest intermontane basins within the northernmost Argentine broken foreland. With a surface elevation >1000 m above sea level, this basin represents a strategic location to understand the subsidence and subsequent uplift history of high‐elevation depositional surfaces within the distal Andean foreland. However, the stratigraphic record of the Pipanaco Basin is almost entirely within the subsurface, and no geophysical surveys have been conducted in the region. A high‐resolution gravity study has been designed to understand the subsurface basin geometry. This study, together with stratigraphic correlations and flexural and backstripping analysis, suggests that the region was dominated by a regional subsidence episode of ca. 2 km during the Miocene‐Pliocene, followed by basement thrusting and ca. 1–1.5 km of sediment filling within restricted intermontane basin between the Pliocene‐Pleistocene. Based on the present‐day position of the basement top as well as the Neogene‐Present sediment thicknesses across the Sierras Pampeanas, which show slight variations along strike, sediment aggradation is not the most suitable process to account for the increase in the topographic level of the high‐elevation, close‐drainage basins of Argentina. The close correlation between the depth to basement and the mean surface elevations recorded in different swaths indicates that deep‐seated geodynamic process affected the northern Sierras Pampeanas. Seismic tomography, as well as a preliminary comparison between the isostatic and seismic Moho, suggests a buoyant lithosphere beneath the northern Sierras Pampeanas, which might have driven the long‐wavelength rise of this part of the broken foreland after the major phase of deposition in these Andean basins. 相似文献