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K. Styszko J. Szczurowski N. Czuma D. Makowska M. Kistler Ł. Uruski 《International Journal of Environmental Science and Technology》2018,15(3):493-506
This study investigated the removal efficiency of pharmaceuticals from aqueous solutions supported on chemically treated fly ash. The coal fly ash was supplied by the electric power station in Krakow, Poland. There are plenty of studies showing the utilization of fly ash as a low-cost adsorbent for wastewater containing heavy metals or dyes. Adsorption and immobilization of pharmaceuticals and personal care products on fly ash is a relatively new method but it is a very promising one. In this study, the adsorptive removal of diclofenac, ketoprofen, carbamazepine, bezafibrate, bisphenol A, 17α-ethinyl estradiol and estriol by HCl- and NaOH-treated fly ash was assessed. Chemical treatment of fly ash changed structures of particles and enhanced specific surface areas. HCl-treated fly ash was characterized by the highest BET specific surface area 47.9 m2 g?1 and unburned carbon content 8.1%. Isotherms for all compounds except for 17α-ethinyl estradiol (EE2) and estriol (E3) were linear. Higher linear regression coefficients (R 2) obtained for isotherms of EE2 and E3 show that the Freundlich model better describes their sorption. Adsorption coefficients K d varied between 109.5 (L kg?1) for bisphenol A and 471.5 (L kg?1) for bezafibrate. Freundlich constants (K F) for EE2 and E3 were 62.3 and 119.9 (µg1?1/n L1/n kg?1), respectively. Acid treatment of fly ash increased adsorption of diclofenac, ketoprofen, carbamazepine, bezafibrate and bisphenol A. Comparison of the octanol–water partitioning coefficients (log K OW) with the partitioning coefficients normalized on unburned carbon content (log K UC) revealed similarities but no strong correlation. The increasing of unburned carbon increased sorption of compounds to fly ash. 相似文献
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Poul Schiøler Karyne Rogers Richard Sykes Chris J. Hollis Brad Ilg Dylan Meadows Lucia Roncaglia Chris Uruski 《Marine and Petroleum Geology》2010
Detailed palynofacies analysis of sidewall core samples taken from below, within and above the Tartan Formation (Thanetian, Late Paleocene, 58.7–55.8 Ma), a potential source rock in the epeiric Great South Basin, shows that the formation is characterised by very high percentages of degraded brown phytoclasts, rare marine algae and amorphous organic matter and thereby represents a mix of terrestrial and marine kerogen. The results indicate that the formation was deposited in a marginally marine (hyposaline), proximal environment under bottom conditions that varied from anoxic to oxic along a nearshore–offshore transect. Samples from the upper part of the underlying Wickliffe Formation indicate deposition in a marginal to normal marine, proximal environment under anoxic to oxic bottom environments. The lower part of the overlying Laing Formation was deposited in an open marine, relatively distal setting under anoxic to oxic bottom environments. 相似文献
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Jean-Yves Collot Jean Delteil Keith B. Lewis Bryan Davy Geoffroy Lamarche Jean-Christophe Audru Phil Barnes Franck Chanier Eric Chaumillon Serge Lallemand Bernard Mercier de Lepinay Alan Orpin Bernard Pelletier Marc Sosson Bertrand Toussaint Chris Uruski 《Marine Geophysical Researches》1996,18(2-4):357-381
The southern Kermadec-Hikurangi convergent margin, east of New Zealand, accommodates the oblique subduction of the oceanic Hikurangi Plateau at rates of 4–5 cm/yr. Swath bathymetry and sidescan data, together with seismic reflection and geopotential data obtained during the GEODYNZ-SUD cruise, showed major changes in tectonic style along the margin. The changes reflect the size and abundance of seamounts on the subducting plateau, the presence and thickness of trench-fill turbidites, and the change to increasing obliquity and intracontinental transpression towards the south. In this paper, we provide evidence that faulting with a significant strike-slip component is widespread along the entire 1000 km margin. Subduction of the northeastern scrap of the Hikurangi Plateau is marked by an offset in the Kermadec Trench and adjacent margin, and by a major NW-trending tear fault in the scarp. To the south, the southern Kermadec Trench is devoid of turbidite fill and the adjacent margin is characterized by an up to 1200 m high scarp that locally separates apparent clockwise rotated blocks on the upper slope from strike-slip faults and mass wasting on the lower slope. The northern Hikurangi Trough has at least 1 km of trench-fill but its adjacent margin is characterized by tectonic erosion. The toe of the margin is indented by 10–25 km for more than 200 km, and this is inferred to be the result of repeated impacts of the large seamounts that are abundant on the northern Hikurangi Plateau. The two most recent impacts have left major indentations in the margin. The central Hikurangi margin is characterized by development of a wide accretionary wedge on the lower slope, and by transpression of presubduction passive margin sediments on the upper slope. Shortening across the wedge together with a component of strike-slip motion on the upper slope supports an interpretation of some strain partitioning. The southern Hikurangi margin is a narrow, mainly compressive belt along a very oblique, apparently locked subduction zone. 相似文献
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The islands of New Zealand cover an area of approximately 250,000 km2, but the New Zealand Exclusive Economic Zone (EEZ) extends to around 4 million km2 and recent confirmation of New Zealand’s Extended Continental Shelf (ECS) has added a further 1.7 million km2 to the country’s marine estate. Within the 5.7 million km2 of New Zealand’s marine territory, approximately 1.2 million km2 are underlain by sedimentary accumulations which may be thick enough to expel petroleum. 相似文献
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