Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Wavelet Spectrum Analysis Of Eit/Soho Images     

V. Delouille  J. De Patoul  J. F. Hochedez  L. Jacques  J. P. Antoine 《Solar physics》2005,228(1-2):301-321

The extreme ultraviolet imaging telescope (EIT) of SOHO offers a unique record of the solar atmosphere for its sampling in temperature, field of view, resolution, duration, and cadence. To investigate globally and locally its topology and evolution during the solar cycle, we consider a multi-scale approach, and more precisely we use the wavelet spectrum. We present three results among the applications of such a procedure. First, we estimate the typical dimension of the supergranules as seen in the 30.4 nm passband, and we show that the evolution of the characteristic network scale is almost in phase with the solar cycle. Second, we build pertinent time series that give the evolution of the signal energy present in the corona at different scales. We propose a method that detects eruptions and post-flaring activity in EUV image sequences. Third, we introduce a new way to extract active regions in EIT images, with perspectives in, e.g., long-term irradiance analysis.  相似文献   

2060 Chiron back to a minimum of brightness     

Daniela Lazzaro  Marcos A. Florczak  Alberto Betzler  Othon C. Winter  Silvia M. Giuliatti-Winter  Claudia A. Angeli  Dietmar W. Foryta 《Planetary and Space Science》1996,44(12):1547-1550

The results of photometric observations of comet/asteroid 2060 Chiron at the Observatório do Pico dos Dias (Brazil-OPD) and the Observatoire de Haute-Provence (France-OHP) during 1994 and 1995 are presented. The analysis of the data shows a decrease of 2060 Chiron brightness from its peak values of 1988–1991. The absolute magnitude, H_v, varies from a maximum of 6.6 in February 1994 up to a minimum of 6.8 in June 1995. Therefore 2060 Chiron is back to a minimum of activity close to that of 1983–1985. The slope parameter G is found to be G = 0.71 ± 0.15. It is suggested that the H-G magnitude system, generally adopted to present 2060 Chiron brightness, is not the most appropriate due to the cometary activity of this object.  相似文献   

Preface to tropical coastal sedimentary environments     

Chuck Nittrouer  Alberto Figueiredo 《Geo-Marine Letters》1996,16(1):1-2

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Testing the circumstellar disc hypothesis: a search for H₂ outflow signatures from massive young stellar objects with linearly distributed methanol masers     

J. M. De Buizer 《Monthly notices of the Royal Astronomical Society》2003,341(1):277-298

The results of a survey searching for outflows using near-infrared imaging are presented. Targets were chosen from a compiled list of massive young stellar objects associated with methanol masers in linear distributions. Presently, it is a widely held belief that these methanol masers are found in (and delineate) circumstellar accretion discs around massive stars. If this scenario is correct, one way to test the disc hypothesis is to search for outflows perpendicular to the methanol maser distributions. The main objective of the survey was to obtain wide-field near-infrared images of the sites of linearly distributed methanol masers using a narrow-band 2.12-μm filter. This filter is centred on the  H₂ v = 1–0 S(1)  line; a shock diagnostic that has been shown to successfully trace CO outflows from young stellar objects. 28 sources in total were imaged of which 18 sources display H₂ emission. Of these, only two sources showed emission found to be dominantly perpendicular to the methanol maser distribution. Surprisingly, the H₂ emission in these fields is not distributed randomly, but instead the majority of sources are found to have H₂ emission dominantly parallel to their distribution of methanol masers. These results seriously question the hypothesis that methanol masers exist in circumstellar discs. The possibility that linearly distributed methanol masers are instead directly associated with outflows is discussed.  相似文献   

The Auger Observatory in Argentina     

Alberto Etchegoyen 《Astrophysics and Space Science》2004,290(3-4):379-387

The Auger Project studies the highest energies known in nature with an emphasis on energies ≥5 × 10¹⁹ eV, which are cosmic rays coming from the outer space reaching the Earth's surface with a very low flux. The questions to be elucidated are what are the origin, energy, production mechanism, and chemical composition of these cosmic rays. Auger aims at building two observatories in both the hemispheres and in 2000 the construction of the austral observatory started. Auger's two distinctive features are its exceptional size and its hybrid nature. It spans over an area of 3000 km² and is constituted by 24 fluorescence detector telescopes and 1600 surface detectors. As such, it will provide a large number of events with less systematic detection uncertainties. The construction of the Southern Observatory in Argentina is quite advanced and the buildings at the Central Station in Malargüe city are already operational. So are the telescope buildings at Cerros Los Leones and Coihueco (two prototype telescopes were operational at Los Leones, which have now been dismantled), 32 surface detectors, and the telecommunication and data acquisition systems. About 20-hybrid events/months were detected and currently two events/hours are registered with the surface detector array. The detection of hybrid events is the most important issue since it shows that the equipment operates within the design parameters.  相似文献   

Opposition polarimetry and photometry of S- and E-type asteroids     

Irina N Belskaya  Vasilij G Shevchenko  Yurij N Krugly  Yurij S Efimov  Alberto Cellino 《Icarus》2003,166(2):276-284

The first results of the observational program devoted to simultaneous investigation of asteroid polarimetric and photometric opposition phenomena are presented. UBVRI polarimetric and V-band photometric observations of the S-type Asteroid 20 Massalia and the E-type Asteroids 214 Aschera and 620 Drakonia were carried out in 1996-1999 down to phase angles of 0.08°, 0.7°, and 1.2°, correspondingly. The S-type Asteroid 20 Massalia is characterized by the pronounced brightness opposition surge with an amplitude larger than that observed for the E-type asteroids. A sharp peak of negative polarization at small phase angles was not observed for this asteroid. The value of polarization degree at phase angle α<1° is less than 0.5% for both S and E types. The negative polarization branches of S and especially E-asteroids have an asymmetrical shape. The phase angle at which the polarization minimum occurs is close to the angle at which non-linear increase begins in the asteroid magnitude phase curves. A relation of the observed effects to the mechanism of coherent backscattering is discussed.  相似文献   

Dissolution and depletion of ferromagnesian minerals from Holocene tephra layers in an acid bog,New Zealand,and implications for tephra correlation     

A. P. W. Hodder  P. J. De Lange  D. J. Lowe 《第四纪科学杂志》1991,6(3):195-208

This study examines the depletion of ferromagnesian silicate minerals from a sequence of thin, distal, mainly rhyolitic tephra layers of Holocene age preserved in an acid peat bog (Kopouatai), North Island, New Zealand. The rate of such depletion has been fast, as indicated by the complete loss of biotite from one tephra layer (Kaharoa Tephra), in which it is normally dominant, in only ca. 770 yr. Chemical dissolution is advocated as the likely cause for the depletion, with amphiboles and other mineral grains commonly showing etch pits, microcaves, and other characteristic surface solution features. Theoretical thermodynamic and kinetic models show a marked increase in the rate of dissolution of all ferromagnesian minerals under conditions of low pH (< 4), but that where silica concentrations in solution are high the relative proportions of minerals remaining are unaffected. However, where concentrations of dissolved silica are low, as in most bog environments, the relative proportions of ferromagnesian minerals are affected as well as absolute amounts being decreased. Amphiboles are depleted relative to pyroxenes, consistent with kinetic studies. The results show that the identification and correlation of tephras on the basis of relative abundances of ferromagnesian minerals alone may be unreliable, and emphasise the need to use multiple criteria in such studies.  相似文献   

Abundances of [WC] central stars and their planetary nebulaee     

O. De Marco  M. J. Barlow 《Astrophysics and Space Science》2001,275(1-2):53-66

We review elemental abundances derived for planetary nebula (PN) WCcentral stars and for their nebulae. Uncertainties in the abundances of[WC] stars are still too large to enable an abundance sequenceto be constructed. In particular it is not clear why the hotter [WCE]stars have C and O abundances which are systematically lower than those oftheir supposed precursors, the [WCL] stars. This abundance differencecould be real or it may be due to unaccounted-for systematic effects inthe analyses. Hydrogen might not be present in [WC] star winds asoriginallysuggested, since broad pedestals observed at the base of nebular lines canplausibly be attributed to high velocity nebular components. It isrecommended that stellar abundance analyses should be carried out withnon-LTE model codes, although recombination line analyses can provideuseful insights. In particular, C II dielectronic recombinationlines provide a unique means to determine electron temperatures in cool[WC] star winds. We then compare the abundances found for PNe which have [WC] central starswith those that do not. Numerous abundance analyses of PNe have beenpublished, but comparisons based on non-uniform samples and methods arelikely to lack reliability. Nebular C/H ratios, which might be expected todistinguish between PNe around H-poor and H-rich stars, are rather similarfor the two groups, with only a small tendency towards larger values fornebulae around H-deficient stars. Nebular abundances should be obtainedwith photoionization models using the best-fitting non-LTE modelatmosphere for the central star as the input. Heavy-metal line blanketingstill needs to be taken into consideration when modeling the central star,as its omission can significantly affect the ionizing fluxes as well asthe abundance determinations. We discuss the discrepancies between nebularabundances derived from collisionally excited lines and thosederived from optical recombination lines, a phenomenon that may havelinks with the presence of H-deficient central stars.  相似文献   

WIMPs and solar evolution code     

Yannick Giraud-Héraud  Jean Kaplan  François De Volnay Martin  Charling Tao  Sylvaine Turck-Chièze 《Solar physics》1990,128(1):21-33

The Saclay solar evolution code is used to check the effect of WIMPs on solar evolution. In this paper we study the effects of various types of Cosmion-matter interactions, give constraints on the crosssections compatible with the measured neutrino rate of 2 SNU on chlorine, and relate these constraints to ongoing dark matter detection experiments.Unité associée au CNRS UA 280, F-75251 Paris Cedex 05, France.On leave from LPC, Collège de France.  相似文献