Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Misinterpretation of the Kenessey method for the determination of the runoff coefficient: a review     

Lucio D’Alberto  Giorgia Lucianetti 《水文科学杂志》2019,64(3):288-296

The calculation of runoff and infiltration parameters is a fundamental task for water budget estimation and water resources management. The “Kenessey method” allows these values to be calculated and its use is widespread among water scientists and practitioners. Due to language barriers and inefficient translation in past decades, the method has undergone some misinterpretations and is now far from its original usefulness and purpose. The use of the modified method can give unreal results for specific climatic zones. The purpose of this paper is to point out these methodological variations and to return to the original approach, improving it with modern technology.  相似文献   

SlugIn 1.0: A Free Tool for Automated Slug Test Analysis          下载免费PDF全文

Sergio Martos‐Rosillo  Carolina Guardiola‐Albert  Alberto Padilla Benítez  Joaquín Delgado Pastor  Antonio Azcón González  Juan José Durán Valsero 《Ground water》2018,56(3):362-365

The correct characterization of aquifer parameters is essential for water‐supply and water‐quality investigations. Slug tests are widely used for these purposes. While free software is available to interpret slug tests, some codes are not user‐friendly, or do not include a wide range of methods to interpret the results, or do not include automatic, inverse solutions to the test data. The private sector has also generated several good programs to interpret slug test data, but they are not free of charge. The computer program SlugIn 1.0 is available online for free download, and is demonstrated to aid in the analysis of slug tests to estimate hydraulic parameters. The program provides an easy‐to‐use Graphical User Interface. SlugIn 1.0 incorporates automated parameter estimation and facilitates the visualization of several interpretations of the same test. It incorporates solutions for confined and unconfined aquifers, partially penetrating wells, skin effects, shape factor, anisotropy, high hydraulic conductivity formations and the Mace test for large‐diameter wells. It is available in English and Spanish and can be downloaded from the web site of the Geological Survey of Spain. Two field examples are presented to illustrate how the software operates.  相似文献   

Assessment of calanchi and rill–interrill erosion susceptibilities using terrain analysis and geostochastics: A case study in the Oltrepo Pavese,Northern Apennines,Italy     

Alberto Bosino  Paolo Giordani  Geraldine Quénéhervé  Michael Maerker 《地球表面变化过程与地形》2020,45(12):3025-3041

Soil erosion is one of the most important environmental problems distributed worldwide. In the last decades, numerous studies have been published on the assessment of soil erosion and the related processes and forms using empirical, conceptual and physically based models. For the prediction of the spatial distribution, more and more sophisticated stochastic modelling approaches have been proposed – especially on smaller spatial scales such as river basins. In this work, we apply a maximum entropy model (MaxEnt) to evaluate badlands (calanchi) and rill–interrill (sheet erosion) areas in the Oltrepo Pavese (Northern Apennines, Italy). The aim of the work is to assess the important environmental predictors that influence calanchi and rill–interrill erosion at the regional scale. We used 13 topographic parameters derived from a 12 m digital elevation model (TanDEM-X) and data on the lithology and land use. Additional information about the vegetation is introduced through the normalized difference vegetation index based on remotely sensed data (ASTER images). The results are presented in the form of susceptibility maps showing the spatial distribution of the occurrence probability for calanchi and rill–interrill erosion. For the validation of the MaxEnt model results, a support vector machine approach was applied. The models show reliable results and highlight several locations of the study area that are potentially prone to future soil erosion. Thus, coping and mitigation strategies may be developed to prevent or fight the soil erosion phenomenon under consideration. © 2020 John Wiley & Sons, Ltd.  相似文献   

The Cabo Frio upwelling overrides geographical patterns in the population dynamics of the shrimp Artemesia longinaris Spence Bate, 1888 (Decapoda: Penaeidae)     

Abner Carvalho‐Batista  Joo Alberto Farinelli Pantaleo  Antonio Leo Castilho  Rogrio Caetano da Costa 《Marine Ecology》2019,40(2)

Upwelling areas are among the most productive ecosystems on the planet, influencing the biology of marine organisms. This study investigated the population dynamics of the shrimp Artemesia longinaris in two regions in southeastern Brazil, one inside (Macaé—Rio de Janeiro State) and one outside (Ubatuba—State of São Paulo) the Cabo Frio upwelling area. The aim was to verify the influence of the upwelling phenomenon on the abundance, growth, longevity, size of sexual maturity, and reproductive period of the species. In total, 188,902 individuals were captured at Macaé and 3,461 at Ubatuba. Individuals captured at Macaé showed larger maximum size, higher longevity, and slower growth rate, besides reaching sexual maturity at larger sizes than at Ubatuba. Continuous reproduction was observed in both regions, with juvenile recruitment peaks in spring and summer. Local conditions observed at Macaé were influenced by the Cabo Frio upwelling zone, characterized by productive and cooler waters that are around 20°C during most of the year. The upwelling phenomenon is probably the main factor influencing the population parameters studied here, changing the geographic patterns previously observed for the variation of these parameters in A. longinaris.  相似文献   

A depth average SPH model including μ(I) rheology and crushing for rock avalanches     

Alberto Longo  Manuel Pastor  Lorenzo Sanavia  Diego Manzanal  Miguel Martin Stickle  Chuan Lin  Angel Yague  Saeid Moussavi Tayyebi 《国际地质力学数值与分析法杂志》2019,43(5):833-857

Classical depth-integrated smoothed particle hydrodynamics (SPH) models for avalanches are extended in the present work to include a μ(I)− rheological model enriched with a fragmentation law. With this improvement, the basal friction becomes grain distribution dependent. Rock avalanches, where grain distribution tends to change with time while propagating, are the appropriate type of landslide to apply the new numerical proposal. The μ(I)− rheological models considered in the present work are those of Hatano and Gray, combined with two different fragmentation laws, a hyperbolic and a fractal-based law. As an application, Frank avalanche, which took place in Canada in 1903, is analyzed under the scope of the present approach, focusing in the influence of the rheological and fragmentation laws in the evolution of the avalanche.  相似文献   

Contextual factors influencing sustainable fisheries in Mexico     

Alejandro Espinoza-Tenorio  Ileana Espejel  Matthias Wolff  José Alberto Zepeda-Domínguez 《Marine Policy》2011

Sustainable fisheries take into consideration that managed fisheries ecosystems shift over time in response to evolving environmental as well as market and political factors. These contextual forces are especially valuable in understanding developing countries such as Mexico, where the unconsolidated fisheries administration faces productive marine ecosystems but unsustainable fisheries. To recognize the issues that have inhibited the consolidation of a regulatory system for sustainable fisheries, a contextual factor analysis was applied to the co-development of two current policies in the Mexican fishery regime: fisheries and environmental policies. Six historical phases have been identified in which there are few long periods of stability and frequent short periods of radical change that alternate between stable and adverse contextual situations. These short and contrasting contextual situations cause a kind of tug-of-war in Mexican fisheries policy-making. On the one hand, domestic economic, scientific, and technological forces seem to slowly lead toward the consolidation of sustainable fisheries; on the other hand, domestic policies drift from one position to another at other timing than the international fisheries and environmental policies. Although recent crises seem to highlight new periods of radical change in Mexico, they also provide an opportunity to adopt new structural plans to consolidate domestic forces as a basis for long-term strategies.  相似文献   

Structural-stratigraphic control on the Umitaka Spur gas hydrates of Joetsu Basin in the eastern margin of Japan Sea   总被引：1，自引：0，他引：1  

Antonio Fernando Menezes Freire  Ryo Matsumoto  Luiz Alberto Santos 《Marine and Petroleum Geology》2011,28(10):1967-1978

Integrated geological, geochemical, and geophysical exploration since 2004 has identified massive accumulation of gas hydrate associated with active methane seeps on the Umitaka Spur, located in the Joetsu Basin on the eastern margin of Japan Sea. Umitaka Spur is an asymmetric anticline formed along an incipient subduction zone that extends throughout the western side of the Japanese island-arc system. Seismic surveys recognized chimney structures that seem strongly controlled by a complex anticlinal axial fault system, and exhibit high seismic amplitudes with apparent pull-up structures, probably due to massive and dense accumulation of gas hydrate. Bottom simulating reflectors are widely developed, in particular within gas chimneys and in the gently dipping eastern flank of the anticline, where debris can store gas hydrates that may represent a potential natural gas resource. The axial fault system, the shape of the anticline, and the carrier beds induce thermogenic gas migration to the top of the structure, and supply gas to the gas hydrate stability zone. Gas reaching the seafloor produces strong seepages and giant plumes in the sea water column.  相似文献   

The 29 September 2009 Samoa Islands Tsunami: Simulations Based on the First Focal Mechanism Solutions and Implications on Tsunami Early Warning Strategies     

Roberto Tonini  Alberto Armigliato  Stefano Tinti 《Pure and Applied Geophysics》2011,168(6-7):1113-1123

The tsunamigenic earthquake (Mw?=?8.1) that occurred on 29 September 2009 at 17:48 UTC offshore of the Samoa archipelago east of the Tonga trench represents an example of the so-called ??outer-rise?? earthquakes. The areas most affected were the south coasts of Western and American Samoa, where almost 200 people were killed and run-up heights were measured in excess of 5?m at several locations along the coast. Moreover, tide gauge records showed a maximum peak-to-peak height of about 3.5?m near Pago Pago (American Samoa) and of 1.5?m offshore of Apia (Western Samoa). In this work, different fault models based on the focal mechanism solutions proposed by Global CMT and by USGS immediately after the 2009 Samoan earthquake are tested by comparing the near-field recorded signals (three offshore DART buoys and two coastal tide gauges) and the synthetic signals provided by the numerical simulations. The analysis points out that there are lights and shadows, in the sense that none of the computed tsunamis agrees satisfactorily with all the considered signals, although some of them reproduce some of the records quite well. This ??partial agreement?? and ??partial disagreement?? are analysed in the perspective of tsunami forecast and of Tsunami Early Warning System strategy.  相似文献   

SLA–chlorophyll-a variability and covariability in the Algero-Provençal Basin (1997–2007) through combined use of EOF and wavelet analysis of satellite data     

Antonio Olita  Alberto Ribotti  Roberto Sorgente  Leopoldo Fazioli  Angelo Perilli 《Ocean Dynamics》2011,61(1):89-102

Data reduction and signal decomposition techniques have been applied to a large bio-physical remotely sensed dataset covering the decade 1997–2007. The aim was the estimation of the spatial (basin and sub-basin scales) and temporal (seasonal and interannual) variability of sea level anomalies and chlorophyll-a concentration in the Algero-Provençal Basin, as well as the study of their covariability. Empirical orthogonal functions, wavelet analysis, singular value decomposition and correlation maps have been successfully used to individuate the patterns of (co)variability of the investigated fields. The seasonal variability of the phytoplanktonic biomass is divided in two distinct modes, timewise and spacewise separated. Positive interannual events are related to anomalies in 1999 and 2005, while the main (negative) anomaly is that of summer 2003, associated to the European 2003 heatwave. The analysis of the sea level anomalies shows a minimum in the formation of anticyclonic Algerian eddies during that period. The largest anticorrelation between sea level anomalies and phytoplanktonic biomass is found in the central zone of the basin, suggesting a clear biological response to the shoaling/deepening of the isopycnae and so to the nutrient injection into the euphotic layer. The analysis suggests that the driver of the variability of the nutricline depth in this central area is the displacement (seasonal) of the North Balearic Front and the formation/action of the frontal eddies.  相似文献