Ostracode carbonate δ18O- and δ13C-signature of hydrological and climatic changes affecting Lake Neuchâtel,Switzerland, since the latest Pleistocene     

Antje Schwalb  Guy S. Lister  Kerry Kelts 《Journal of Paleolimnology》1994,11(1):3-17

Floating and grounded peat plateaus were studied in fens in the Yukon Territory (Canada). The peat deposit may be over 4 m thick and consists of a lower bed of aquatic peat overlain by humic fen peat, mesic fen peat and woody peat. Permafrost in the grounded peat plateaus is older than the 1200 year old White River Ash, whereas permafrost in the floating peat plateau is younger.Peat accumulation rates since 1200 years B.P. were greater in the fens (85–100 cm) than on the surface of the peat plateaus (25–55 cm). Where the peat plateau is free-floating, it will persist until the climate changes, causing the icy core to thaw. Where the peat plateau is frozen to the mineral substrate, it slowly drowns since the fen peat accumulates faster than the woody peat. This drowning results in degradation of the landform independently of the climate. Only degradation of floating peat plateaus can be used to identify climatic changes.This publication is the first paper in a series of papers presented at the session on Past Climatic Change and the Development of Peatlands at the ASLO and SWS Meetings in Edmonton, Canada, May 30–June 3, 1993. Dr. P. Kuhry and Dr S. C. Zoltai are serving as Guest Editors.  相似文献   

Products and Mechanism of the Gas Phase Reaction of Ozone with β-Pinene     

Richard Winterhalter  Peter Neeb  Dirk Grossmann  Antje Kolloff  Osamu Horie  Geert Moortgat 《Journal of Atmospheric Chemistry》2000,35(2):165-197

Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H₂O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO₂ (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C₉-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH₂OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC₉-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H₂O. The atmospherically important reaction of thestabilised C₉-Criegee intermediate with H₂Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H₂O₂(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C₉-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed.  相似文献   

Methane and sulfide fluxes in permanent anoxia: In situ studies at the Dvurechenskii mud volcano (Sorokin Trough, Black Sea)   总被引：2，自引：0，他引：2  

Anna Lichtschlag  Janine Felden  Florence Schubotz  Antje Boetius  Dirk de Beer 《Geochimica et cosmochimica acta》2010,74(17):5002-5018

The Dvurechenskii mud volcano (DMV) is located in permanently anoxic waters at 2060 m depth (Sorokin Trough, Black Sea). The DMV was studied during the RV Meteor expedition M72/2 as an example of an active mud volcano system, to investigate the significance of submarine mud volcanism for the methane and sulfide budget of the anoxic Black Sea hydrosphere. Our studies included benthic fluxes of methane and sulfide, as well as the factors controlling transport, consumption and production of both compounds within the sediment. The pie-shaped mud volcano showed temperature anomalies as well as solute and gas fluxes indicating high fluid flow at its summit north of the geographical center. The anaerobic oxidation of methane (AOM) coupled to sulfate reduction (SR) was repressed in this zone due to the upward flow of sulfate-depleted fluids through recently deposited subsurface muds, apparently limiting microbial methanotrophic activity. Consequently, the emission of dissolved methane into the water column was high, with an estimated rate of 0.46 mol m⁻² d⁻¹. On the wide plateau and edge of the mud volcano surrounding the summit, fluid flow and total methane flux were lower, allowing higher SR and AOM rates correlated with an increase in sulfate penetration into the sediment. Here, between 50% and 70% of the methane flux (0.07-0.1 mol m⁻² d⁻¹) was consumed within the upper 10 cm of the sediment. The overall amount of dissolved methane released from the entire mud volcano structure into the water column was significant with a discharge of 1.3 × 10⁷ mol yr⁻¹. The DMV maintains also high areal rates of methane-fueled sulfide production and emission of on average 0.05 mol m⁻² d⁻¹. This is a difference to mud volcanoes in oxic waters, which emit similar amounts of methane, but not sulfide. However, based on a comparison of this and other mud volcanoes of the Black Sea, we conclude that sulfide and methane emission into the hydrosphere from deep-water mud volcanoes does not significantly contribute to the sulfide and methane inventory of the Black Sea.  相似文献   

A numerical response of the middle atmosphere to the 11-year solar cycle     

Rolando R. Garcia  Susan Solomon  Raymond G. Roble  David W. Rusch 《Planetary and Space Science》1984,32(4):411-423

A two-dimensional numerical model with coupled photochemistry and dynamics has been used to investigate the response of the middle atmosphere (16–116 km) to changes in solar activity over the 11-year solar cycle. Model inputs that vary with solar cycle include solar radiation, cosmic ray and auroral ionization rates and the flux of NO_x at the model's upper boundary.In this study, the results of model runs for solar cycle minimum and maximum conditions are compared. In the stratosphere, using currently accepted estimates of changes in solar radiation at wavelengths longer than 180 nm, only small responses in ozone, temperature and zonal winds are obtained. On the other hand, changes at shorter wavelengths, and the effects of particle precipitation, lead to large variations in the abundances of trace species in the thermosphere and upper mesosphere. In particular, very large abundances of NO_x are produced above 90 km by auroral particle precipitation. Considerable amounts of NO_x are transported subsequently to the stratosphere by the global mean meridional circulation. It is shown that this excess NO_x can lead to significant decreases in ozone concentrations at high latitudes and that it may explain observations of nitrate deposition in Antarctic snow.  相似文献   

Use of Rhodamine water tracer in the marshland upwelling system   总被引：1，自引：0，他引：1  

Richardson SD  Willson CS  Rusch KA 《Ground water》2004,42(5):678-688

Rhodamine water tracer (RWT) was used to characterize the migration of waste water within the saline subsurface of a marshland upwelling system (MUS), which is an alternative on-site waste water treatment system for coastal areas. Field tracer studies were performed to investigate the fresh waste water plume movement within the saline ground water. Pore velocities were calculated using first detection times and ranged from 0.68 to 10.7 x 10(-4) cm/sec for the loamy sandy soil matrix present at the site. Use of RWT in the field also allowed determination of main and preferential flowpaths. One- and two-dimensional laboratory experiments were performed using silica sand to investigate the interactions of the organically rich waste water with RWT within the zone surrounding the point of injection (one-dimensional) and the impact of background salinity on plume movement (two-dimensional). The results from these studies were used to help explain the field data. One-dimensional breakthrough curves revealed retardation factors for the RWT in the waste water mixture of 1.73 to 1.90. These results were similar to other researchers, indicating little interaction between the waste water and RWT. Variations in pore water salinity (5, 15, 25, and 35 ppt) were found to have a significant effect on pore water velocities of the fresh water plume (two-dimensional), indicating the need to incorporate background salinities into the design process for MUS.  相似文献   

Normal fault growth influenced by basement fabrics: The importance of preferential nucleation from pre‐existing structures     

Luca Collanega  Katherine Siuda  Christopher A.‐L. Jackson  Rebecca E. Bell  Alexander J. Coleman  Antje Lenhart  Craig Magee  Anna Breda 《Basin Research》2019,31(4):659-687

Reactivation of pre‐existing intra‐basement structures can influence the evolution of rift basins, yet the detailed kinematic relationship between these structures and overlying rift‐related faults remains poorly understood. Understanding the kinematic as well as geometric relationship between intra‐basement structures and rift‐related fault networks is important, with the extension direction in many rifted provinces typically thought to lie normal to fault strike. We here investigate this problem using a borehole‐constrained, 3D seismic reflection dataset from the Taranaki Basin, offshore New Zealand. Excellent imaging of intra‐basement structures and a relatively weakly deformed, stratigraphically simple sedimentary cover allow us to: (a) identify a range of interaction styles between intra‐basement structures and overlying, Plio‐Pleistocene rift‐related normal faults; and (b) examine the cover fault kinematics associated with each interaction style. Some of the normal faults parallel and are physically connected to intra‐basement reflections, which are interpreted as mylonitic reverse faults formed during Mesozoic subduction and basement terrane accretion. These geometric relationships indicate pre‐existing intra‐basement structures locally controlled the position and attitude of Plio‐Pleistocene rift‐related normal faults. However, through detailed 3D kinematic analysis of selected normal faults, we show that: (a) normal faults only nucleated above intra‐basement structures that experienced late Miocene compressional reactivation, (b) despite playing an important role during subsequent rifting, intra‐basement structures have not been significantly extensionally reactivated, and (c) preferential nucleation and propagation of normal faults within late Miocene reverse faults and folds appears to be the key genetic relationship between contractionally reactivated intra‐basement structures and rift‐related normal faults. Our analysis shows that km‐scale, intra‐basement structures can control the nucleation and development of newly formed, rift‐related normal faults, most likely due to a local perturbation of the regional stress field. Because of this, simply inverting fault strike for causal extension direction may be incorrect, especially in provinces where pre‐existing, intra‐basement structures occur. We also show that a detailed kinematic analysis is key to deciphering the temporal as well as simply the spatial or geometric relationship between structures developed at multiple structural levels.  相似文献   

Stable isotopes and trace elements in modern ostracod shells: implications for reconstructing past environments on the Tibetan Plateau,China   总被引：1，自引：0，他引：1  

Nicole Börner  Bart De Baere  Lailah Gifty Akita  Roger Francois  Klaus Peter Jochum  Peter Frenzel  Liping Zhu  Antje Schwalb 《Journal of Paleolimnology》2017,58(2):191-211

Stable isotopes and trace elements in ostracod shells have been used widely in paleolimnological investigations of past lake hydrochemistry and climate because they provide insights into past water balance and solute evolution of lakes. Regional differences in lake characteristics and species-specific element fractionation, however, do not permit generalization of results from other regions or ostracod species to the southern Tibetan Plateau, in part because most common taxa from the southern Tibetan Plateau are endemic to the area. This study evaluated relations between present-day environmental conditions and the geochemical composition of modern ostracod shells from the southern Tibetan Plateau, to assess the suitability of using shell chemistry to infer hydrological conditions. We studied nine lakes and their catchments, located along a west–east transect in the south-central part of the Tibetan Plateau. Stable oxygen and carbon isotope values and trace element concentrations in recent shells from the four most abundant ostracod species (Leucocytherella sinensis, ?Leucocythere dorsotuberosa, Limnocythere inopinata, Tonnacypris gyirongensis) were measured, together with hydrochemical properties of host waters at the time of sampling. Results revealed significant between-species differences in stable isotope fractionation and trace element incorporation into shell calcite. Stable oxygen and carbon isotope values of ostracod shells were correlated significantly with the stable isotope composition of the respective water body \( \left( {\updelta^{18} {\text{O}}_{{{\text{H}}_{ 2} {\text{O}}}} \,{\text{and }}\updelta^{13} {\text{C}}_{{{\text{H}}_{ 2} {\text{O}}}} } \right) \), reflecting salinity and productivity, respectively. Offsets between δ¹⁸O_shell and δ¹³C_shell and inorganic calcite, the latter representing isotopic equilibrium, suggest shell formation of T. gyirongensis during spring melt. L. sinensis reproduces throughout the monsoon season until September and shows several consecutive generations, and L. inopinata molts to the adult stage after the monsoon season in August/September. The influence of pore water δ¹³C was displayed by L. inopinata, suggesting shell calcification within the sediment. Mg/Ca_shell is primarily influenced by water Mg/Ca ratios and salinity and confirms the use of this shell ratio as a proxy for precipitation-evaporation balance and lake level. In addition, Sr/Ca and Ba/Ca can be used to infer changes in salinity, at least in closed-basin lakes with calcite saturation. Observed effects of water Sr/Ca and salinity on Sr/Ca incorporation are biased by the presence of aragonite precipitation in the lakes, which removes bioavailable Sr from the host water, resulting in low Sr/Ca_shell values. Changes in carbonate mineralogy affect the bioavailability of trace elements, a process that should be considered in paleoclimate reconstructions. Oxygen isotopes and Mg/Ca_shell ratios were unaffected by water temperature. Positive correlations among Fe/Ca, Mn/Ca and U/Ca in ostracod shells, and their negative correlation with δ¹³C, which reflects organic matter decay, show the potential to infer changes in redox conditions that can be used to reconstruct past oxygen supply to bottom waters and thus past water-circulation changes within lakes. The intensity of microbial activity, associated with organic matter decomposition, can be inferred from U/Ca ratios in ostracod shells. These findings highlight the value of fossil ostracod records in lake deposits for inferring paleoenvironmental conditions on the southern Tibetan Plateau.  相似文献   

Blood metal levels and metal-influenced immune functions of harbour seals in captivity   总被引：2，自引：0，他引：2  

Kakuschke A  Valentine-Thon E  Griesel S  Rosenberger T  Mundry R  Siebert U  Prange A 《Marine pollution bulletin》2008,56(4):764-769

Immunological blood parameters and the effects of environmental pollutants on the immune system are important to assess the health status of seals. Animals living permanently in seal centres are useful for development and validation of diagnostic tools for free-ranging animals. In this study, parameters of cellular immunity as well as metal concentrations in blood and metal influence on cell proliferation of seven seals from a seal centre were investigated repeatedly using multi-element analysis and a lymphocyte proliferation assay. The metal concentrations, except for tin and chromium, were in general comparable to those of free-ranging animals of the North Sea. The unstimulated and mitogen-stimulated lymphocyte proliferation showed strong intra- and inter-individual variability, which reflected variability in activation of the immune status. Furthermore, both immunosuppressive and stimulative influences of metals on lymphocytes were found. Summarising, the methods used in this investigation provided useful information on these animals, and their application to free-ranging animals can be recommended.  相似文献   

8.4 ka以来纳木错湖芯介形类组合的环境变化意义     

谢曼平  朱立平  彭萍  王君波  汪勇  SCHWALB Antje 《地理学报(英文版)》2009,19(4):387-402

A 332-cm long lacustrine core was drilled in the Nam Co in the central-southern part of the Tibetan Plateau. From the core, 15 species of ostracods (Crustacea: Ostracoda), which belong to 6 genera have been identified. According to the variations of the ostracod assem-blages and the ostracods ecological features, which are sensitive to the changing environ-ment, three main stages can be distinguished as follows: Stage I was from 8400 to 6800 a BP, during which the climate was cold-humid, and the lake depth changed from shallow to deep. Stage II was from 6400 to 2500 a BP, during which the climate changed from warm-humid to cold-humid, and then to cold-dry. The lake depth gradually became deep. The shifting of cli-mate, from wet-cold to dry-cold during this period, had constructed the basis of present en-vironment in the Nam Co. Stage III was from 2500 a BP to the present, which showed a trait of lake depth increasing. At the earlier period of this stage, the climate kept as cold-dry as that in the former stage, but the salinity of the lake increased. At the later period of this stage, the degree of cold-dry was enhanced, and the activities of land surface runoff tended to be weakened. Our research also found that the peak values of ostracods with black shell was coherent with the maximum production of the ostracods, and agreed with the increasing sedimentary water dynamics. This indicated that the ostracods with black shell was simulta-neous with the high prolificacy of ostracod, and transported from other places. The abun-dance of Candona juvenile shells reflected the high mortality of that kind of ostracods under an unfavorable condition. This was probably a result of the rapid change of water dynamics of sedimentary environment.  相似文献   

Late Quaternary lake response to climate change and anthropogenic impact: biomarker evidence from Lake Constance sediments     

Sabine Hanisch  Martin Wessels  Frank Niessen  Antje Schwalb 《Journal of Paleolimnology》2009,41(3):393-406

This study used organic matter in oligotrophic Lake Constance (southern Germany) to reconstruct lake environment and to disentangle the multiple factors, such as climate change and human impacts, which influence sedimentation in large lakes. A sediment core from Upper Lake Constance, which represents 16,000 years of Late Glacial and Holocene lake history, was analysed for organic biomarkers, hydrogen index and elements calcium, strontium, and magnesium. Magnetic susceptibility was measured to establish a high-resolution stratigraphic framework for the core and to obtain further information about changes with respect to relative allochthonous versus autochthonous sedimentation. Dinosterol—a biomarker for dinoflagellates—and calcium have low concentrations in Younger Dryas sediments and consistently high concentrations between 10,500 and 7,000 cal. years BP. These variations are attributed to changes in lake productivity, but are not reflected in the proportion of total organic carbon within the sediment. During the Younger Dryas and between 6,000 and 2,800 cal. years BP, concentrations and accumulation rates of land-plant-derived C₂₉-steroids (β-sitosterol, stigmastanol and stigmasterol), in combination with a relatively low HI, indicate periods of enhanced terrigenous input to the lake. For the Younger Dryas, higher runoff can be attributed to a cold climate, leading to decreased vegetation cover and increased erosion. After 6,000 cal. years BP, high terrestrial input may be explained by enhanced precipitation. Biomarker and HI results, in combination with archaeological studies, raise the question as to whether lakeshore settlements affected sedimentation in Upper Lake Constance between 6,000 and 2,800 cal. years BP.  相似文献