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1.
2.
The Apollo orbital geochemistry, photogeologic, and other remote sensing data sets were used to identify and characterize geochemical anomalies on the eastern limb and farside of the Moon and to investigate the processes responsible for their formation. The anomalies are located in the following regions: (1) Balmer basin, (2) terrain northeast of Mare Smythii, (3) near Langemak crater, (4) Pasteur crater, (5) terrain northwest of Milne basin, (6) northeast of Mendeleev basin, (7) north and northeast of Korolev basin, (8) terrain north of Taruntius crater, and (9) terrain north of Orientale basin. The anomalies are commonly associated with Imbrian- or Nectarian-aged light plains units which exhibit dark-haloed impact craters. The results of recent spectral reflectance studies of dark-haloed impact craters plus consideration of the surface chemistry of the anomalies strongly indicate that those geochemical anomalies associated with light plains deposits which display dark-haloed impact craters result from the presence of basaltic units that are either covered by varying thickness of highland debris or have a surface contaminated with significant amounts of highlands material. The burial or contamination of ancient volcanic surfaces by varying amounts of highland material appears to have been an important (though not the dominant) process in the formation of lunar light plains. Basaltic volcanism on the eastern limb and farside of the Moon was more extensive in both space and time than has been accepted. 相似文献
3.
For several years now, an experimental simulation of Titan's atmosphere has been on going at LISA. A cold plasma is established in a gas mixture representative of the atmosphere of the satellite. In these experiments, more than 70 organic compounds have been identified, including the first identification in this type of experimental simulation of C4N2 already detected in its solid form on Titan, which suggests that the setup correctly mimics the chemistry of Titan's atmosphere.We have carried out the first experimental simulation including O-containing compounds in order to study the influence of the presence of CO on the chemical behavior of Titan's atmosphere. With the help of gas chromatography–mass spectrometry (GC–MS) and infrared spectroscopy (IRS) we can thus determine which minor species still undetected in Titan's atmosphere are likely to be present and understand the complex chemistry of the atmosphere of this satellite. Surprisingly we have identified unpredicted O-containing gaseous compounds, mainly ethylene oxide (also named oxirane, C2H4O). This molecule has been observed in the interstellar medium by observation in the millimeter region (Astrophys. J. 489 (1997) 553; Astron. Astrophys. 337 (1998) 275). On the contrary, the predicted O-compounds (formaldehyde and methanol) have not been identified in this experiment. Furthermore, we have identified NH3 in the gaseous products with an initial mixture of N2 (98%) and CH4 (2%).The paper describes the experimental device used in this work, in particular the IRS and GC–MS techniques. We also comment the results related to the detection of the O-containing compounds and NH3 and their implications on our knowledge of the chemistry of Titan's atmosphere and on the retrieval of the future Titan data expected from Cassini-Huygens. 相似文献
4.
5.
An Example of Island-Arc Petrogenesis: Geochemistry and Petrology of the Southern Luzon Arc, Philippines 总被引:7,自引:1,他引:6
DEFANT MARC J.; MAURY REN? C.; RIPLEY EDWARD M.; FEIGENSON MARK D.; JACQUES DARIO 《Journal of Petrology》1991,32(3):455-500
Volcanism throughout the Luzon arc is associated with eastwardsubduction of the South China Sea floor along the Manila Trench.The southern section of the arc, the focus of this study, extendsfrom the Lingayen-Dingalan fault to the small islands just southof Luzon. Two segments appear to exist along this section ofthe arc the northern Bataan and southern Mindoro segments whichare separated by the Macolod Corridor. The volcanic rocks have typical arc phenocryst mineralogies:olivine, clinopyroxene, plagioclase, and titanomagnetite inthe most mafic rocks and clinopyroxene, plagioclase, orthopyroxene,titanomagnetite, ? amphibole in the more felsic samples. Complexzoning, sieve textures, and decoupling of incompatible traceelements suggest that processes such as assimilation have takenplace. The rocks from the study area range from basalts to rhyolitesand show typical calc-alkaline features. The rocks of the MacolodCorridor and Mindoro segment are particularly enriched in largeion lithophile elements (LILE), light rare earth elements (LREE),and radiogenic Sr compared with the Bataan segment. The datafall within the mantle array on Sr-Nd isotopic diagrams andgrade toward higher Sr and lower Nd isotopic values from northto south. A likely source for the volcanics of this study is either amid-ocean ridge basalt (MORB)-type mantle that undergoes higherdegrees of partial melting than regions involved in MORB generationor a previously depleted source. We suggest that the high fieldstrength element (HFSE) anomalies have been derived throughdifferential element partitioning during fluid transport fromthe subducted lithosphere to the mantle wedge. Continental crustal material seems to play a significant roleparticularly in the Macolod Corridor and the Mindoro segment,based on the high LILE, La/Sm ratios, radiogenic Sr isotopes,and 18O values. The Macolod Corridor and the Mindoro segmenthave undergone source contamination by crustal material fromthe North Palawan-Mindoro crustal block either during the collisionof this block with the Manila Trench or by subduction of sedimentsrich in this crustal material. A similar component has alsobeen detected in the Bataan segment but in minor amounts. Thetrace element and isotopic differences between the northernand southern sections of the arc are interpreted in terms ofvariable composition (i. e., variable amounts of a crustal componentintroduced from the Palawan-Mindoro crustal terrain) of themetasomatic fluids released into the source. 相似文献
6.
Marie K. McCabe Zdeněk F. Švestka Russell A. Howard Bernard V. Jackson Neil R. Sheeley Jr. 《Solar physics》1986,103(2):399-408
By using a combination of X-ray (HXIS), H (Haleakala), white-light corona (Solwind), and zodiacal light (Helios) images on 21–22 May, 1980 we demonstrate, and try to explain, the co-existence of a coronal mass ejection with a stationary post-flare coronal arch. The mass ejection was seen, both by Solwind and Helios, in prolongation of the path of a powerful spray, whereas the active region filament did not erupt. A tentative comparison is made with other occurrences of stationary, or quasi-stationary post-flare coronal arches. 相似文献
7.
Daniel Bernard Jamal El Khattabi Emilie Lefevre Hani Serhal Sabine Bastin-Lacherez Isam Shahrour 《Environmental Geology》2008,53(5):1129-1138
In the north of France, high registers of nickel are sometimes recorded within the chalk aquifer. In a confined context, the
presence of pyrite in the covering clays or in the marcasite nodules encrusted in the clay may constitute a natural source
of trace metals. With an objective of sanitary control, the limits of chemical contents regulating the quality of water destined
for human consumption have been lowered by the European Framework Directive in the field of water policy (2000/60/EC). As
a result, nickel limits have been reduced from 50 to 20 μg/l. The analyses, carried out on three water catchment fields in
our area of study, were centred on variable parameters (Eh, O2(d), pH, Conductivity, T°), major elements (SO4, NO3) and metals (Fe, Ni, Mn, Co). The acquired data enabled us to identify from one hand, the conditions which are presented
within the site, special thanks to the evolution of nitrate and iron contents and on the other hand, the natural origin (geological)
of nickel for two of the three sites studied based essentially on the evaluation of the Nickel/Cobalt ratio. Thus, on the
first site, the evolution of nickel content and nitrate content showed the influence of the phenomenon of denitrification
on the re-mobilisation of the nickel. Whereas on the second site, a high variation of total iron content and oxygen dissolved
in solution highlighted a particular phenomenon of oxidation of the pyrite through molecular oxygen. Finally, the correlation
with the sulphates clearly showed behaviour of the nickel, once released, that was entirely dependent on the phenomenon of
adsorption on the iron and manganese hydroxides. 相似文献
8.
Unconsolidated sand, gravel and clay deposits near Beihai and in the Leizhou Peninsula in southern China form an unconfined
aquifer, aquitard and a confined aquifer. Water and soil samples were collected from the two aquifers in the coastal Beihai
area for the determination of chemical compositions, minerals and soluble ions. Hydrogeochemical modeling of three flow paths
through the aquitard are carried out using PHREEQC to determine water–rock interactions along the flow paths. The results
indicate that the dissolution of anorthite, fluorite, halite, rhodochrosite and CO2, and precipitation of potash feldspar and kaolinite may be occurring when groundwater leaks through the aquitard from the
unconfined aquifer to the confined aquifer. Cation exchanges between Na and Ca can also happen along the flow paths. 相似文献
9.
Core formation and the oxidation state of the Earth: Additional constraints from Nb, V and Cr partitioning 总被引:1,自引:0,他引:1
We have combined metal-silicate partitioning data from the literature with new experimental results at 1.5-8 GPa and 1480-2000 °C to parameterize the effects of pressure, temperature and composition on the partitioning of V, Cr and Nb between liquid Fe metal (with low S and C content) and silicate melt.Using information from the steelmaking literature to correct for interactions in the metal phase, we find that, for peridotitic silicate melts, metal-silicate partition coefficients are given by:
10.
Zsuzsanna Balogh-Brunstad C. Kent Keller Forrest Stevens Bernard T. Bormann 《Geochimica et cosmochimica acta》2008,72(11):2601-2618
Ectomycorrhiza-forming fungi (EMF) alter the nutrient-acquisition capabilities of vascular plants, and may play an important role in mineral weathering and the partitioning of products of weathering in soils under nutrient-limited conditions. In this study, we isolated the weathering function of Suillus tomentosus in liquid-cultures with biotite micas incubated at room temperature. We hypothesized that the fungus would accelerate weathering by hyphal attachment to biotite surfaces and transmission of nutrient cations via direct exchange into the fungal biomass. We combined a mass-balance approach with scanning electron microscopy (SEM) and atomic force microscopy (AFM) to estimate weathering rates and study dissolution features on biotite surfaces. Weathering of biotite flakes was about 2-3 orders of magnitude faster in shaken liquid-cultures with fungus compared to shaken controls without fungus, but with added inorganic acids. Adding fungus in nonshaken cultures caused a higher dissolution rate than in inorganic pH controls without fungus, but it was not significantly faster than organic pH controls without fungus. The K+, Mg2+ and Fe2+ from biotite were preferentially partitioned into fungal biomass in the shaken cultures, while in the nonshaken cultures, K+ and Mg2+ was lost from biomass and Fe2+ bioaccumulated much less. Fungal hyphae attached to biotite surfaces, but no significant surface changes were detected by SEM. When cultures were shaken, the AFM images of basal planes appeared to be rougher and had abundant dissolution channels, but such channel development was minor in nonshaken conditions. Even under shaken conditions the channels only accounted for only 1/100 of the total dissolution rate of 2.7 × 10−10 mol of biotite m−2 s−1. The results suggest that fungal weathering predominantly occurred not by attachment and direct transfer of nutrients via hyphae, but because of the acidification of the bulk liquid by organic acids, fungal respiration (CO2), and complexation of cations which accelerated dissolution of biotite. Results further suggest that both carbohydrate source (abundant here) and a host with which nutrients are exchanged (missing here) may be required for EMF to exert an important weathering effect in soils. Unsaturated conditions and physical dispersal of nutrient-rich minerals in soils may also confer a benefit for hyphal growth and attachment, and promote the attachment-mediated weathering which has been observed elsewhere on soil mineral surfaces. 相似文献