The REE distribution in minerals from tin-bearing ore-magmatic systems of the Russian Far East, including the Komsomolsk, Khingan, and Badzhal districts in the Amur region and the Kavalerovo, Lesozavodsk, Voznesenka, Furmanovo, and other districts in Primorsky krai, has been studied. The main attention was focused on tourmaline and chlorite; in addition, associated biotite, feldspar, apatite, fluorite, and carbonates were examined. The major factors affecting the REE distribution in the studied minerals are the temperature, Eh, and pH of the mineral-forming medium; crystal chemistry; partition coefficients of REE between fluid and minerals; and complexation that disturbs the coherent behavior of REE. Fluid evolution at different stages is characterized. 相似文献
Data on fluid inclusions and stable isotope compositions (O, H, C, and S) in minerals have been summarized for large-and middle-scale mesothermal gold deposits (Nezhdaninsk, Berezovsk, Kochkar’, Svetlinsk, Darasun, and Maisk), cassiterite-silicate-sulfide deposits of Sikhote Alin (Solnechnoe, Arsen’evsk, and Vysokogorsk), vein silver-base metal deposits in the Southern Verkhoyansk region (Prognoz and Kupol’noe), and epithermal copper-bismuth-silver-base metal deposits of the Karamazar district in Tajikistan (Kanimansur, Tary Ekan, and Zambarak). It is shown that ores precipitated from fluids with salinity varying from brines (up to 60 wt % NaCl equiv) to dilute fluids (1–3 wt % NaCl equiv). As a rule, fluids of different compositions entered the hydrothermal-magmatic system. A fluid mixture of H2O-CO2-NaCl±CH4±N2 predominated in the orogenic (mesothermal) gold-bearing hydrothermal systems, with deposition of the final-stage gold-bearing sulfosalts from aqueous-salt fluid. Brines played a significant role in the formation of cassiterite-silicate-sulfide and vein silver-base metal deposits. The brines often coexisted with a low-density vapor-rich fluid at the ore deposition site. The obtained data suggest a predominant magmatic component in the hydrothermal-magmatic systems, with a significant contribution of meteoric waters. 相似文献
This paper reports the results of our recent studies and generalizes previously known data on the geology, mineralogy, geochemistry, and genesis of the Russia’s largest Latnenskoe refractory clay deposit. It is shown that conditions of its localization were defined by regional and local factors. The regional factors controlled the distribution of the clay raw material in the region, while the local factors were responsible for the genesis and composition of refractory clays of the Latnenskoe deposit. Our studies showed that the formation of refractory clays is not only related to terrigenous but also to authigenic processes of sedimentation. The terrigenous component of clays was formed by the erosion of kaolin weathering crusts of the Voronezh anteclise crystalline basement and Paleozoic sedimentary hydromica–kaolinite rocks. Authigenic processes were significantly contributed by organic matter, which determined the environmental pH and Eh parameters. It is established that the mineral matter of clays of the deposit is represented by three morphological modifications (crystalline, amorphous, and biomorphic), which were formed subsequently and (or) simultaneously and could be transformed into each other. Application of a complex of modern precision methods allowed us to reveal a previously unknown biomorphic modification of kaolinite, the major rock-forming mineral, as well as mixed-layer kaolinite-smectite in the clays. It is shown that the distribution of major and trace elements and the sulfur isotope composition in different technological types of clay depend mainly on the facies conditions of their formation. Technological properties of clay raw material are considered. 相似文献
New data on local mineral associations and the microheterogeneity of minerals and fluid inclusions in gabbro were obtained for the gabbro–peridotite oceanic core complex with a long-lived detachment fault controlling the hydrothermal activity. It is assumed that the hydrothermal hydrogen-bearing fluid with a NaCl content of >30 wt % is formed in the seawater/harzburgite (~1/5) reaction of serpentinization. The brine residual after serpentinization interacted with gabbro at the final stages of crystallization of an intrusion and assimilated some components (K, REEs, and Ba) from the residual melt. The interaction was resulted in metamorphic transformations of gabbro at decreasing temperature below 500°C. The reaction of the decomposition of magmatic titanomagnetite with the transition of iron reduced to Fe2+ into newly formed chlorinebearing amphibole at 540–450°C and logf(O2) from–20 to–24 is shown.
The mineral assemblages, mode of occurrence, and chemical compositions of coexisting fahlore and sphalerite from the Darasun gold deposit have been described. Three generations of fahlore and three generations of sphalerite have been recognized. The FeS content in sphalerite coexisting with fahlore ranges from 0.8 to 9.4 mol %. The complete solid solution series Fe-tetrahedrite–Zn-tetrahedrite–Fe-tennantite–Zn-tennantite reflected in Sb/(Sb + As) and Fe/(Fe + Zn) ratios ranging from 0 to 0.97 and from 0.07 to 1.00, respectively, with a predominant negative relationship between these ratios has been identified for the first time at the deposit. Stepped, oscillatory, and combined stepped-oscillatory growth zonings within fahlore grains and heterogeneous aggregates of fahlore have been found. Fahlore is enriched in As with respect to Sb, and Zn-tetrahedrite is followed by Fe- and Zn-tennantite from early to late generation; Zn-tetrahedrite is followed by Fe-tennantite in zoned grains and overgrown rims; sphalerite crystallized at decreased temperature and sulfur fugacity. The evolution of the chemical composition of fahlores was caused by the evolving temperature, fluid salinity, and conditions of metal migration. 相似文献
Geology of Ore Deposits - Paragenetic associations of tetrahedrite-(Zn) and sphalerite are distinguished in the Teremki gold-ore deposit. The chemical composition of coexisting minerals of this... 相似文献