Calcium and magnesium‐limited dolomite precipitation at Deep Springs Lake,California     

PATRICK MEISTER  CAROLINA REYES  WILL BEAUMONT  MIGUEL RINCON  LISA COLLINS  WILLIAM BERELSON  LOWELL STOTT  FRANK CORSETTI  KENNETH H. NEALSON 《Sedimentology》2011,58(7):1810-1830

Dolomite [Ca,Mg(CO₃)₂] precipitation from supersaturated ionic solutions at Earth surface temperatures is considered kinetically inhibited because of the difficulties experienced in experimentally reproducing such a process. Nevertheless, recent dolomite is observed to form in hypersaline and alkaline environments. Such recent dolomite precipitation is commonly attributed to microbial mediation because dolomite has been demonstrated to form in vitro in microbial cultures. The mechanism of microbially mediated dolomite precipitation is, however, poorly understood and it remains unclear what role microbial mediation plays in natural environments. In the study presented here, simple geochemical methods were used to assess the limitations and controls of dolomite formation in Deep Springs Lake, a highly alkaline playa lake in eastern California showing ongoing dolomite authigenesis. The sediments of Deep Springs Lake consist of unlithified, clay‐fraction dolomite ooze. Based on δ¹⁸O equilibria and textural observations, dolomite precipitates from oxygenated and agitated surface brine. The Na‐SO₄‐dominated brine contains up to 500 mm dissolved inorganic carbon whereas Mg²⁺ and Ca²⁺ concentrations are ca 1 and 0·3 mm , respectively. Precipitation in the subsurface probably is not significant because of the lack of Ca²⁺ (below 0·01 mm ). Under such highly alkaline conditions, the effect of microbial metabolism on supersaturation by pH and alkalinity increase is negligible. A putative microbial effect could, however, support dolomite nucleation or support crystal growth by overcoming a kinetic barrier. An essential limitation on crystal growth rates imposed by the low Ca²⁺ and Mg²⁺ concentrations could favour the thermodynamically more stable carbonate phase (which is dolomite) to precipitate. This mode of unlithified dolomite ooze formation showing δ¹³C values near to equilibrium with atmospheric CO₂ (ca 3‰) contrasts the formation of isotopically light (organically derived), hard‐lithified dolomite layers in the subsurface of some less alkaline environments. Inferred physicochemical controls on dolomite formation under highly alkaline conditions observed in Deep Springs Lake may shed light on conditions that favoured extensive dolomite formation in alkaline Precambrian oceans, as opposed to modern oceans where dolomites only form diagenetically in organic C‐rich sediments.  相似文献   

Probabilistic simulations of crop yield over western India using the DEMETER seasonal hindcast ensembles     

A. J. CHALLINOR  J. M. SLINGO  T. R. WHEELER  F. J. DOBLAS–REYES 《地球，A辑:动力气象学与海洋学》2005,57(3):498-512

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Identification of last interglacial deposits in eastern Beringia: a cautionary note from the Palisades,interior Alaska     

ALBERTO V. REYES  GRANT D. ZAZULA  SVETLANA KUZMINA  THOMAS A. AGER  DUANE G. FROESE 《第四纪科学杂志》2011,26(3):345-352

Last interglacial sediments in unglaciated Alaska and Yukon (eastern Beringia) are commonly identified by palaeoecological indicators and stratigraphic position ～2–5 m above the regionally prominent Old Crow tephra (124 ± 10 ka). We demonstrate that this approach can yield erroneous age assignments using data from a new exposure at the Palisades, a site in interior Alaska with numerous exposures of last interglacial sediments. Tephrochronology, stratigraphy, plant macrofossils, pollen and fossil insects from a prominent wood‐rich organic silt unit are all consistent with a last interglacial age assignment. However, six ¹⁴C dates on plant and insect macrofossils from the organic silt range from non‐finite to 4.0 ¹⁴C ka BP, indicating that the organic silt instead represents a Holocene deposit with a mixed‐age assemblage of organic material. In contrast, wood samples from presumed last interglacial organic‐rich sediments elsewhere at the Palisades, in a similar stratigraphic position with respect to Old Crow tephra, yield non‐finite ¹⁴C ages. Given that local permafrost thaw since the last interglaciation may facilitate reworking of older sediments into new stratigraphic positions, minimum constraining ages based on ¹⁴C dating or other methods should supplement age assignments for last interglacial sediments in eastern Beringia that are based on palaeoecology and stratigraphic association with Old Crow tephra. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献