Multiple Isotopic Components in Quaternary Volcanic Rocks of the Cascade Arc near Crater Lake, Oregon   总被引：2，自引：1，他引：1  

BACON  CHARLES R.; GUNN  SUSAN H.; LANPHERE  MARVIN A.; WOODEN  JOSEPH L. 《Journal of Petrology》1994,35(6):1521-1556

Quaternary lavas and pyroclastic rocks of Mount Mazama, CraterLake caldera, and the surrounding area have variable Sr, Nd,and Pb isotopic compositions. High-alumina olivine tholeiites(HAOT) have ⁸⁷Sr/⁸⁶Sr ratios of 0.70346–0.70364; basalticandesite, 0–70349–0.70372; shoshonitic basalticandesite, 0.70374–0.70388; and andesite, 0.70324–0.70383.Dacites of Mount Mazama have ⁸⁷Sr/⁸⁶Sr ratios of 0.70348–0.70373.Most rhyodacites converge on 0.7037. However, rhyodacite ofthe caldera-forming, climactic eruption has ⁸⁷Sr/⁸⁶Sr=0.70354because of an admixed low-⁸⁷Sr/⁸⁶Sr component. Andesitic tomafic-cumulate scoriae of the climactic eruption, and enclavesin preclimactic rhyodacites, cluster in two groups but shownearly the entire ⁸⁷Sr/⁸⁶Sr range of the data set, confirmingpreviously suggested introduction of diverse parental magmasinto the growing climactic chamber. Pb and Nd isotope ratiosdisplay less variation (²⁰⁶Pb/²⁰⁴Pb= 18.838–18.967, ²⁰⁷Pb/²⁰⁴Pb=15.556–15.616,²⁰⁸Pb/²⁰⁴Pb=38.405–38.619; _Nd= +3.9 to +6.1) and generallycovary with ⁸⁷Sr/⁸⁶ Sr ratios. Radiogenic isotope data fromCrater Lake plot with published data for other Cascade volcanoeson isotope ratio correlation diagrams. The isotopic data for the Crater Lake area require sources ofprimitive magmas to consist of depleted mantle and a subductioncomponent, introduced in variable quantity to the depleted mantlewedge. Variable degrees of melting of this heterogeneous mantle,possibly at different depths, produced the diversity of isotopiccompositions and large-ion lithophile element (LILE) abundancesin primitive magmas. Trace element ratios do not indicate presenceof an ocean island basalt (OIB) source component that has beenreported in lavas of some other Cascade volcanoes. Crustal contamination may have affected isotope ratios and LILEconcentrations in evolved HAOT, where initial LILE concentrationswere low. Contamination is more difficult to detect in the calcalkalinelavas because of their higher LILE concentrations and the smallisotopic contrast with likely contaminants, such as mid- tolower-crustal rocks thought to be equivalents of igneous rocksof the Klamath Mountains and associated lower crust. Crustalassimilation appears to be required for calcalkaline rocks onlyby ¹⁸O values, which vary from lows of +5.6 to + 6.0% in HAOTand primitive basaltic andesites to a high of +7.0% in dacite,a range that is too high to be explained by plagioclase-dominatedclosed-system fractional crystallization. Elevated ¹⁸O valuesof differentiated lavas may be attributed to interaction withrelatively ¹⁸O-rich, ⁸⁷Sr-poor crustal rocks. Variably fused granitoid blocks ejected in the climactic eruption,and rarely in late Pleistocene eruptive units, have ¹⁸Opl of–3.4 to +6.5% and ¹⁸O_qz of –2.2 to +8.0% but haveSr, Nd, and Pb isotope ratios similar to volcanic rocks (e.g.⁸⁷Sr/⁸⁶Sr0.7037). Rb and Sr data for glass separates from granodioritessuggest that the source pluton is Miocene. Glass from granodioritehas ⁸⁷Sr/⁸⁶Sr ratios as high as 0.70617. Oxygen isotope fractionationbetween quartz, plagioclase, and glass indicates requilibrationof O isotopes at magmatic temperatures, after ¹⁸O/¹⁶O had beenlowered by exchange with meteoric hydrothermal fluids. Unmeltedgranodiorite xenoliths from pre-climactic eruptive units have¹⁸O values that are consistent with onset of hydrothermal exchangeearly during growth of the climactic magma chamber. Assimilationof such upper-crustal granodiorite apparently lowered ¹⁸O valuesof rhyodacites without significantly affecting their magmaticcompositions in other ways.  相似文献   

Out of the Rat Race     

CHARLES WALDEGRAVE  SHANE STUART 《New Zealand geographer》1997,53(1):22-29

After the social policy reforms of 1991 important changes in internal migration in New Zealand occurred. These resulted in changing housing costs and falling incomes which led to the movement of low income households, particularly beneficiaries and state house tenants, from urban to rural areas and small towns. A survey of 404 people who moved to the Southern Wairarapa towns of Carterton, Martinborough and Featherston from New Zealand urban areas since 1985 shows that a proportional increase in beneficiary movement occurred after 1991. Housing costs, relative to income, are important factors in the decision to move for a range of migrants. This pattern of migration has important regional development ramifications.  相似文献   

Sedimentology and origin of deposits from a small ice-dammed lake, Leirbreen, Norway     

ROBERT DONNELLY  CHARLES HARRIS 《Sedimentology》1989,36(4):581-600

This paper describes recent proglacial lacustrine sediments exposed by the drainage of a small (probably never more than 0·03 km²) ice-dammed lake basin at Leirbreen, central Jotunheimen, Norway. The dominant facies include ripple-laminated, massive and horizontally-stratified sands, massive and horizontally-laminated silts, and irregularly-laminated fine sands and silts. The major control on lake circulation and the nature and distribution of these facies was an underflow driven by a subglacial meltwater stream which formed the major lake input. Although much of the sedimentary sequence indicates a pulsatory input, the proximal character of this small lake prevented the development of classic varved silts. Compressional deformation of shoreline sediments was due to winter lake ice push. Other deformational processes included the grounding of icebergs, water escape and syn-sedimentary downslope collapse. Observations from an adjacent small ice-marginal lake at Leirbreen provide support for several of the inferences drawn from the sediments of the former ice-dammed lake.  相似文献   

Calc-alkaline, Shoshonitic, and Primitive Tholeiitic Lavas from Monogenetic Volcanoes near Crater Lake, Oregon   总被引：2，自引：1，他引：2  

BACON  CHARLES. R. 《Journal of Petrology》1990,31(1):135-166

Quaternary monogenetic volcanism in the High Cascades of Oregonis manifested by cinder cones, lava fields, and small shields.Near Crater Lake caldera, monogenetic lava compositions include:low-K (as low as 0?09% K₂O) high-alumina olivine tholeiite (HAOT);medium-K. calc-alkaline basalt, basaltic andesite, and andesite;and shoshonitic basaltic andesite (2?1% K₂O, 1750 ppm Sr at54% SiO₂). Tholeiites have MORB-like trace element abundancesexcept for elevated Sr, Ba, and Th and low high field strengthelements (HFSE), and they represent near-primary liquids. Theyare similar to HAOTs from the Cascades and adjacent Basin andRange, and to many primitive basalts from intraoceanic arcs.Calc-alkaline lavas show a well-developed arc signature of highlarge-ion lithophile elements (LILE) and low HFSE. Their Zrand Hf concentrations are at least partly decoupled from thoseof Nb and Ta; HREE are low relative to HAOT. Incompatible elementabundances and ratios vary widely among basaltic andesites.Some calc-alkaline lavas vented near Mount Mazama contain abundantgabbroic microxcnoliths, and are basaltic andesitic magmas contaminatedwith olivine gabbro. A calc-alkaline basalt and a few basaltic andesites have MgOand compatible trace element contents that suggest only minorfractionation. There appears to be a compositional continuumbetween primitive tholeiitic and calc-alkaline lavas. Compositionalvariation within suites of comagmatic primitive lavas, boththoleiitic and calc-alkaline, mainly results from differentdegrees of partial melting. Sources of calc-alkaline primarymagmas were enriched in LILE and LREE by a subduction componentand contained residual garnet, whereas sources of HAOTs hadlower LILE and LREE concentrations and contained residual clinopyroxene.High and variable LILE and LREE contents of calc-alkaline lavasreflect variations in fluid-transported subduction componentadded to the mantle wedge, degree of partial melting, and possiblyalso interaction with rocks or partial melts in the lower crust. Andesites were derived from calc-alkaline basaltic andesitesby fractionation of plagioclase+augite+magnetite+apatite ? orthopyroxeneor olivine, commonly accompanied by assimilation. Many andesitesare mixtures of andesitic or dacitic magma and a basaltic orbasaltic andesitic component, or are contaminated with gabbroicmaterial. Mingled basalt, andesite, and dacite of Williams Craterformed by multi-component, multi-stage mixing of basaltic andesiticmagma, gabbro, and dacitic magma. The wide range of compositionsvented from monogenetic volcanoes near Crater Lake is a resultof the thick crust coupled with mild tectonic extension superimposedon a subduction-related magmatic arc.  相似文献   

The nature and distribution of fluids during amphibolite facies metamorphism, Naxos (Greece)   总被引：1，自引：0，他引：1  

I. S. BUICK  T. J. B. HOLLAND 《Journal of Metamorphic Geology》1991,9(3):301-314

On the basis of fluid inclusion evidence, pervasive influx of deep-seated CO₂-rich fluids has been invoked to account for mid- to upper amphibolite facies (M2_B) metamorphism on the island of Naxos (Cyclades, Greece). In this paper, mineral devolatilization and melt equilibria are used to constrain the composition of both syn- and post-peak-M2_B fluids in the deepest exposed levels of the metamorphic complex. The results indicate that peak-M2_B fluids were spatially and compositionally heterogeneous throughout the high-grade core of the complex, whereas post-peak-M2_B fluids were generally water-rich. The observed heterogeneities in syn-M2_B fluid composition are inconsistent with pervasive CO₂-flushing models invoked by previous workers on the basis of fluid inclusion evidence. It is likely that few CO₂-rich fluid inclusions on Naxos preserve fluids trapped under peak metamorphic conditions. It is suggested that many of these inclusions have behaved as chemically open systems during the intense deformation that accompanied the uplift of the metamorphic complex. A similar process may explain the occurrence of some CO₂-rich fluid inclusions in granulite facies rocks.  相似文献   

Calculating phase diagrams involving solid solutions via non-linear equations, with examples using THERMOCALC   总被引：33，自引：1，他引：32  

R POWELL  T. HOLLAND  & B. WORLEY 《Journal of Metamorphic Geology》1998,16(4):577-588

Phase diagrams involving solid solutions are calculated by solving sets of non-linear equations. In calculating P–T  projections and compatibility diagrams, the equations used for each equilibrium are the equilibrium relationships for an independent set of reactions between the end-members of the phases in the equilibrium. Invariant points and univariant lines in P–T  projections can be calculated directly, as can coordinates in compatibility diagrams. In calculating P–T  and T–x / P–x pseudosections – diagrams drawn for particular bulk compositions – the equilibrium relationship equations are augmented by mass balance equations. Lines in pseudosections, where the mode of one phase in the lower variance equilibrium is zero, and points, where the modes of two phases are zero, can then be calculated directly. The software, THERMOCALC, allows the calculation of these and a range of other types of phase diagram. Examples of phase diagrams and phase diagram movies, with instructions for their production, along with the THERMOCALC input and output files, and the Mathematica^TM functions for assembling them, are presented in this paper, partly in hard copy and partly on the JMG web sites (http://www.gly.bris.ac.uk/www/jmg/jmg.html, or equivalent Australian or USA sites).
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An enlarged and updated internally consistent thermodynamic dataset with uncertainties and correlations: the system K2O–Na2O–CaO–MgO–MnO–FeO–Fe2O3–Al2O3–TiO2–SiO2–C–H2–O2     

T. J. B. HOLLAND  R. POWELL 《Journal of Metamorphic Geology》1990,8(1):89-124

We present, as a progress report, a revised and much enlarged version of the thermodynamic dataset given earlier (Holland & Powell, 1985). This new set includes data for 123 mineral and fluid end-members made consistent with over 200 P–T–X_CO2–f_O2 phase equilibrium experiments. Several improvements and advances have been made, in addition to the increased coverage of mineral phases: the data are now presented in three groups ranked according to reliability; a large number of iron-bearing phases has been included through experimental and, in some cases, natural Fe:Mg partitioning data; H₂O and CO₂ contents of cordierites are accounted for with the solution model of Kurepin (1985); simple Landau theory is used to model lambda anomalies in heat capacity and the Al/Si order–disorder behaviour in some silicates, and Tschermak-substituted end-members have been derived for iron and magnesium end-members of chlorite, talc, muscovite, biotite, pyroxene and amphibole. For the subset of data which overlap those of Berman (1988), it is encouraging to find both (1) very substantial agreement between the two sets of thermodynamic data and (2) that the two sets reproduce the phase equilibrium experimental brackets to a very similar degree of accuracy. The main differences in the two datasets involve size (123 as compared to 67 end-members), the methods used in data reduction (least squares as compared to linear programming), and the provision for estimation of uncertainties with this dataset. For calculations on mineral assemblages in rocks, we aim to maximize the information available from the dataset, by combining the equilibria from all the reactions which can be written between the end-members in the minerals. For phase diagram calculations, we calculate the compositions of complex solid solutions (together with P and T) involved in invariant, univariant and divariant assemblages. Moreover we strongly believe in attempting to assess the probable uncertainties in calculated equilibria and hence provide a framework for performing simple error propagation in all calculations in thermocalc, the computer program we offer for an effective use of the dataset and the calculation methods we advocate.  相似文献   

The potential of perennial cave ice in isotope palaeoclimatology     

CHARLES J. YONGE  WILLIAM D. MACDONALD 《Boreas: An International Journal of Quaternary Research》1999,28(3):357-362

Perennial ice from caves on and to the east of the Canadian Great Divide yield δ¹⁸O and δD values, which are unusually high measurements when compared with the average precipitation for the region. Furthermore, these ice data fall below and along lines of lower slope than the Global Meteoric Water Line. To explain the observed relationships, we propose the following process. A vapour-ice isotopic fractionation mechanism operates on warm-season vapour when it precipitates as hoar ice on entering the caves. The subsequent fall of hoar to the cave floor through mechanical overloading, along with ice derived from ground-water seepage (with a mean annual isotopic composition), results in massive ice formation of a mixed composition. This mixed composition is what is observed in the characteristic relationships found here. Such findings suggest that a warm versus cold climate interpretation for ancient cave ice may be the opposite of that found in the more familiar polar and glacial ice cores.  相似文献   

Drilling Blake Nose: the search for evidence of extreme Palaeogene–Cretaceous climates and extraterrestrial events     

KROON  NORRIS  KLAUS  IAN T. ALEXANDER  LEON PAUL BARDOT  CHARLES E. BARKER  JEAN-PIERRE BELLIER  CHARLES D. BLOME  LEON J. CLARKE  JOCHEN ERBACHER  KRISTINA L. FAUL  MARY ANNE HOLMES  BRIAN T. HUBER  MIRIAM E. KATZ  KENNETH G. MACLEOD  SANDRA MARCA  FRANCISA C. MARTINEZ-RUIZ  ISAO MITA  MUTSUMI NAKAI  JAMES G. OGG  DOROTHY K. PAK  THOMAS K. PLETSCH  JEAN M. SELF-TRIAL  NICHOLAS J. SHACKLETON  JAN SMIT  WILLIAM USSLERIII  DAVID K. WATKINS  JOEN WIDMARK  & PAUL A. WILSON 《Geology Today》1998,14(6):222-226

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An accurate interpolating scheme for semi-Lagrangian advection on an unstructured mesh for ocean modelling     

DANIEL Y. LE ROUX  CHARLES A. LIN  ANDREW STANIFORTH 《地球，A辑:动力气象学与海洋学》1997,49(1):119-138

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