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1.
Anaerobic diagenesis within Recent, Pleistocene, and Eocene marine carbonate frameworks 总被引:2,自引:0,他引:2
FRANCIS J. SANSONE† GORDON W. TRIBBLE ‡ CHRISTINE C. ANDREWS† JEFFREY P. CHANTON§ 《Sedimentology》1990,37(6):997-1009
Porewaters from a variety of Recent, Pleistocene, and Eocene lithified marine carbonate frameworks displayed similar chemical characteristics: highly depleted concentrations of dissolved oxygen (>20 μM), elevated levels of dissolved methane (25-5000 nM), and near-seawater sulphate levels. These porewaters also had low pH values (7·5-7·9), and contained elevated concentrations of sulphide (4–10 μM), dissolved inorganic carbon (2·05–2·46 mM), and inorganic nutrients. Hydrocarbon composition data indicate that the methane is biogenic, whereas the methane δ13C values (–47·4 ± 2·7%0) suggest that it has been subject to oxidation. The porewater dissolved inorganic carbon δ13C values varied from –0·6 to –39%0, suggesting input of carbon dioxide from organic matter oxidation. We conclude that anaerobic diagenesis involving bacterial degradation of organic matter is a common process in lithified marine carbonates and hypothesize that it may be an important factor controlling their carbonate geochemistry. 相似文献
2.
The Red Hill complex of New Hampshire is unusual for the WhiteMountain Magma Series of northern New England because it consistsof both silica-undersaturated and -saturated to -oversaturatedsyenites. Amphibole, pyroxene, and apatite in two of the saturatedunits, the Outer Coarse Syenite (OCS) and the Garland Peak Syenite(GPS), and in the undersaturated Nepheline Sodalite Syenite(NSS), were analyzed to determine the relationship between coexistingunder-saturated and saturated magmas. Mafic enclaves in theNSS and the GPS were also studied to elucidate their relationshipswith the host syenites. In addition to mafic enclaves, the NSS contains later emplacedcamptonitic dikes and associated pipe-like benmoreites. Thebenmoreites contain amphibole that is compositionally continuouswith amphibole in the NSS. However, REE and other trace elementabundances in apatite from the benmoreites and the NSS are notcompatible with a genetic relationship between the two. Maficenclaves within the NSS contain amphibole and pyroxene thatare compositionally continuous with the NSS. Bulk-rock compositionsof the enclaves plot along trends defined by the NSS. Furthermore,chondrite-normalized REE patterns for apatite in both the enclavesand the NSS are parallel, and REE abundances increase systematicallyfrom the enclaves to the NSS. We therefore suggest that theenclaves represent magmas similar to the NSS parent that intrudedup into its daughter products. These magmas appear to have beentephritic to phonotephritic in composition. Abundances of REE in apatite in the Nepheline Sodalite Syenite(NSS) are distinct from those in apatite in the silica-saturatedOCS. OCS apatites have LREE abundances up to 26 000 times chondritesand La/Yb ratios of 1627. NSS apatites have comparableLREE concentrations, but HREE abundances are considerably lowerthan those of the OCS; La/Yb ratios range from 68 to 104. Theseobserved differences in both the REE and other trace elementabundances between apatite in the two rocks present difficultieswith a common parental magma hypothesis for the NSS and OCS.Hence it is suggested that, although the OCS and NSS are contemporaneousin time and space, they are probably not consanguineous. The silica-saturated GPS is a fine-grained syenite containingstrongly zoned amphiboles with kaersutite to hastingsite coresrimmed by hastingsitic hornblende and ferro-hornblende. Discretegrains of hastingsitic hornblende and ferro-hornblende occurin a feldspar-quartz groundmass. Coarser-grained, quartz-richpatches, containing feldspars and ferro-hornblende and ferroedenite,are also found in the GPS. The kaersutite cores are identicalto the amphibole in the GPS enclaves and the NSS suite. TheseGPS enclaves are silica undersaturated; the kaersutite coresin the GPS host rocks are probably xenocrysts derived from disaggregatedundersaturated magmas similar to that represented by the enclaves. 相似文献
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A collection of papers by Bjorn Kurth, CHRISTINE JANIS
BJORN KURTEN 1924 11 19-1988 1228 相似文献
BJORN KURTEN 1924 11 19-1988 1228 相似文献
5.
KONZETT JURGEN; MILLER CHRISTINE; ARMSTRONG RICHARD; THONI MARTIN 《Journal of Petrology》2005,46(4):717-747
Olivine-rich rocks containing olivine + orthopyroxene + spinel+ Ca-amphibole ± clinopyroxene ± garnet are presentin the central ÖtztalStubai crystalline basementassociated with eclogites of tholeiitic affinity. These rockscontain centimetre-sized garnet layers and lenses with garnet+ clinopyroxene ± corundum. Protoliths of the olivine-richrocks are thought to be olivine + orthopyroxene + spinel dominatedcumulates generated from an already differentiated Fe-rich () tholeiitic magma that was emplaced into shallowcontinental crust. Protoliths of the garnet-rich rocks are interpretedas layers enriched in plagioclase and spinel intercalated ina cumulate rock sequence that is devoid of, or poor in, plagioclase.UPb sensitive high-resolution ion microprobe dating ofzircons from a garnet layer indicates that emplacement of thecumulates took place no later than 517 ± 7 Myr ago. Aftertheir emplacement, the cumulates were subjected to progressivemetamorphism, reaching eclogite-facies conditions around 800°Cand >2 GPa during a Variscan metamorphic event between 350and 360 Ma. Progressive high-P metamorphism induced breakdownof spinel to form garnet in the olivine-rich rocks and of plagioclase+ spinel to form garnet + clinopyroxene ± corundum inthe garnet layers. Retrogressive metamorphism at T 650680°Cled to the formation of Ca-amphibole, chlorite and talc in theolivine-rich rocks. In the garnet layers, högbomite formedfrom corundum + spinel along with Al-rich spinel, Ca-amphibole,chlorite, aspidolitepreiswerkite, magnetite, ilmeniteand apatite at the interface between olivine-rich rocks andgarnet layers at P < 0·8 GPa. Progressive desiccationof retrogade fluids through crystallization of hydrous phasesled to a local formation of saline brines in the garnet layers.The presence of these brines resulted in a late-stage formationof Fe- and K-rich Ca-amphibole and Sr-rich apatite, both characterizedby extremely high Cl contents of up to 3·5 and 6·5wt % Cl, respectively. KEY WORDS: cumulates; Variscan metamorphism; SHRIMP dating; högbomite; saline brines 相似文献
6.
CHRISTINE WINDASS 《地球表面变化过程与地形》1996,21(11):1055-1055
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PHILIP J. ASHWORTH GREGORY H. SAMBROOK SMITH JAMES L. BEST JOHN S. BRIDGE STUART N. LANE IAN. A. LUNT ARNOLD J. H. REESINK CHRISTOPHER J. SIMPSON ROBERT E. THOMAS 《Sedimentology》2011,58(7):1860-1883
The depositional stratigraphy of within‐channel deposits in sandy braided rivers is dominated by a variety of barforms (both singular ‘unit’ bars and complex ‘compound’ bars), as well as the infill of individual channels (herein termed ‘channel fills’). The deposits of bars and channel fills define the key components of facies models for braided rivers and their within‐channel heterogeneity, knowledge of which is important for reservoir characterization. However, few studies have sought to address the question of whether the deposits of bars and channel fills can be readily differentiated from each other. This paper presents the first quantitative study to achieve this aim, using aerial images of an evolving modern sandy braided river and geophysical imaging of its subsurface deposits. Aerial photographs taken between 2000 and 2004 document the abandonment and fill of a 1·3 km long, 80 m wide anabranch channel in the sandy braided South Saskatchewan River, Canada. Upstream river regulation traps the majority of very fine sediment and there is little clay (< 1%) in the bed sediments. Channel abandonment was initiated by a series of unit bars that stalled and progressively blocked the anabranch entrance, together with dune deposition and stacking at the anabranch entrance and exit. Complete channel abandonment and subsequent fill of up to 3 m of sediment took approximately two years. Thirteen kilometres of ground‐penetrating radar surveys, coupled with 18 cores, were obtained over the channel fill and an adjacent 750 m long, 400 m wide, compound bar, enabling a quantitative analysis of the channel and bar deposits. Results show that, in terms of grain‐size trends, facies proportions and scale of deposits, there are only subtle differences between the channel fill and bar deposits which, therefore, renders them indistinguishable. Thus, it may be inappropriate to assign different geometric and sedimentological attributes to channel fill and bar facies in object‐based models of sandy braided river alluvial architecture. 相似文献
8.
Vegetation,fire and climate history of the Lesser Caucasus: a new Holocene record from Zarishat fen (Armenia)
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9.
Michelle E. MINITTI Melissa D. LANE Janice L. BISHOP 《Meteoritics & planetary science》2005,40(1):55-69
Abstract— The origin of hematite detected in Martian surface materials is commonly attributed to weathering processes or aqueous precipitation. Here, we present a new hematite formation mechanism that requires neither water nor weathering. Glass‐rich basalts with Martian meteorite‐like chemistry (high FeO, low Al2O3) oxidized at high (700 and 900 °C) temperatures in air and CO2, respectively, form thin (<1 μm) hematite coatings on their outermost surfaces. Hematite is manifested macroscopically by development of magnetism and a gray, metallic sheen on the glass surface and microscopically by Fe enrichment at the glass surface observed in element maps. Visible and near‐infrared, thermal infrared, and Raman spectroscopy confirm that the Fe enrichment at the oxidized glass surfaces corresponds to hematite mineralization. Hematite formation on basaltic glass is enabled by a mechanism that induces migration of Fe2+ to the surface of an oxidizing glass and subsequent oxidation to form hematite. A natural example of the hematite formation mechanism is provided by a Hawaiian basalt hosting a gray, metallic sheen that corresponds to a thin hematite coating. Hematite coating development on the Hawaiian basalt demonstrates that Martian meteorite‐like FeO contents are not required for hematite coating formation on basalt glass and that such coatings form during initial extrusion of the glassy basalt flows. If gray hematite originating as coatings on glassy basalt flows is an important source of Martian hematite, which is feasible given the predominance of igneous features on Mars, then the requirement of water as an agent of hematite formation is eliminated. 相似文献
10.
Abstract Using a combination of laboratory and field experiments, the performance of a Partech Instruments Ltd IR40-C active head suspended solids sensor has been tested with respect to changing particle size distribution and rapid variation in suspended sediment transport rate. The sensor, which utilizes light attenuation in the infrared waveband, has several advantages both over visible light optical designs and over nuclear or optical back-scatter (OBS) devices. Three sets of laboratory tests are reported: calibration experiments using estuarine, pro-glacial and control media; flume simulations of pulsed sediment supply at a variety of frequencies, concentrations and ambient flow velocities; and simple tests for the effect of air bubbles within the sensor light path. The sensor was also deployed in the field, together with an electromagnetic current meter, to monitor flow and suspended sediment transport fluctuations in the turbulent frequency range. Although the sensor performed well with respect to drift, noise and stability of calibration, significant variation occurred with respect to suspensions of differing particle sizes. A simple correction procedure involving the weighting of sensor output by specific particle surface area may enable comparison of turbidity data from different locations and times, and with standard calibration solutions. At high frequencies, the sensor is capable of resolving fluctuations in the transport rate to c. 0.5 s, which appears to correspond well to field observations of significant velocity fluctuation and transport ‘events’ and is comparable with results obtained using OBS devices. However, the resolution of transport fluctuations is again dependent upon particle characteristics, and the presence of air bubbles in the flow whose size approximates the path width of the sensor may mimic a fluctuating transport process. Further interpretation of high frequency measurement awaits research into the fundamentals of rapidly varying flow and sediment transport characteristics. 相似文献