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Crispin KATONGO Christian KOEBERL Brian J. WITZKE Richard H. HAMMOND Raymond R. ANDERSON 《Meteoritics & planetary science》2004,39(1):31-51
Abstract— The Crow Creek Member is one of several marl units recognized within the Upper Cretaceous Pierre Shale Formation of eastern South Dakota and northeastern Nebraska, but it is the only unit that contains shock‐metamorphosed minerals. The shocked minerals represent impact ejecta from the 74‐Ma Manson impact structure (MIS). This study was aimed at determining the bulk chemical compositions and analysis of planar deformation features (PDFs) of shocked quartz; for the basal and marly units of the Crow Creek Member. We studied samples from the Gregory 84‐21 core, Iroquois core and Wakonda lime quarry. Contents of siderophile elements are generally high, but due to uncertainties in the determination of Ir and uncertainties in compositional sources for Cr, Co, and Ni, we could not confirm an extraterrestrial component in the Crow Creek Member. We recovered several shocked quartz grains from basal‐unit samples, mainly from the Gregory 84‐21 core, and results of PDF measurements indicate shock pressures of at least 15 GPa. All the samples are composed chiefly of SiO2 (29–58 wt%), Al2O3 (6–14 wt%), and CaO (7–30 wt%). When compared to the composition of North American Shale Composite, the samples are significantly enriched in CaO, P2O5, Mn, Sr, Y, U, Cr, and Ni. The contents of rare earth elements (REE), high field strength elements (HFSE), Cr, Co, Sc, and their ratios and chemical weathering trends, reflect both felsic and basic sources for the Crow Creek Member, an inference, which is consistent with the lithological compositions in the environs of the MIS. The high chemical indices of alteration and weathering (CIA' and CIW': 75–99), coupled with the Al2O3‐(CaO*+Na2O)‐K2O (A‐CN'‐K) ratios, indicate that the Crow Creek Member and source rocks had undergone high degrees of chemical weathering. The expected ejecta thicknesses at the sampled locations (409 to 219 km from Manson) were calculated to range from about 1.9 to 12.2 cm (for the present‐day crater radius of Manson), or 0.4 to 2.4 cm (for the estimated transient cavity radius). The trend agrees with the observed thicknesses of the basal unit of the Crow Creek Member, but the actually observed thicknesses are larger than the calculated ones, indicating that not all of the basal unit comprises impact ejecta. 相似文献
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Johnson Simon P.; de Waele Bert; Tembo Francis; Katongo Crispin; Tani Kenichiro; Chang Qing; Iizuka Tsuyoshi; Dunkley Daniel 《Journal of Petrology》2007,48(7):1411-1441
The southern Irumide Belt (SIB) is an ENE–WSW-trending,late Mesoproterozoic orogenic belt located between the Congo–Tanzania–Bangweulu(CTB) and Kalahari cratons in central southern Africa. It isseparated from the late Mesoproterozoic Irumide Belt (IB) tothe north by Permo-Triassic graben, raising the possibilitythat the younger rifts reactivated a suture between the twobelts that has been rendered cryptic as a result of youngerKaroo cover. Both belts are dominated by calc-alkaline gneisses,but in addition the SIB contains abundant metavolcanic and metasedimentaryrocks. In this study we present detailed geochemical, isotopicand geochronological data for volcanic and plutonic lithologiesfrom the southernmost part of the SIB, the Chewore–RufunsaTerrane. This terrane comprises a wide variety of supracrustalto mid-crustal rocks that have major- and trace-element compositionssimilar to magmas formed in present-day subduction zones. Chondrite-normalizedrare earth element (REE) profiles and whole-rock Sm–Ndisotope compositions indicate that the parental supra-subductionmelts interacted with, and were contaminated by sialic continentalcrust, implying a continental-margin-arc setting. Secondaryionization mass spectrometry dating of magmatic zircon has yieldedcrystallization ages between c. 1095 and 1040 Ma, similar toelsewhere in the SIB. U–Pb dating and in situ Lu–Hfisotopic analyses of abundant xenocrystic zircon extracted fromthe late Mesoproterozoic granitoids indicate that the contaminantcontinental basement was principally Palaeoproterozoic in ageand had a juvenile isotopic signature at the time of its formation.These data are in contrast to those for the IB, which is characterizedby younger, c. 1020 Ma, calc-alkaline gneisses that formed bythe direct recycling of Archaean crust without significant additionof any juvenile material. We suggest that the SIB developedby the subduction of oceanic crust under the margin of an unnamedcontinental mass until ocean closure at c. 1040 Ma. Subsequentcollision between the SIB and the CTB margin led to the cessationof magmatism in the SIB and the initiation of compression andcrustal melting in the IB. KEY WORDS: geochemistry; Mesoproterozoic; SHRIMP zircon U–Pb dating; Sm–Nd isotopes; Southern Irumide Belt 相似文献
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Antonie Haas Crispin T.S. Little Heiko Sahling Gerhard Bohrmann Tobias Himmler Jörn Peckmann 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(2):283-293
Vestimentiferan tube worms are prominent members of modern methane seep communities and are totally reliant as adults on symbiotic sulphide-oxidizing bacteria for their nutrition. The sulphide is produced in the sediment by a biochemical reaction called the anaerobic oxidation of methane (AOM). A well-studied species from the Gulf of Mexico shows that seep vestimentiferans ‘mine’ sulphide from the sediment using root-like, thin walled, permeable posterior tube extensions, which can also be used to pump sulphate and possibly hydrogen ions from the soft tissue back into the sediment to increase the local rate of AOM. The ‘root-balls’ of exhumed seep vestimentiferans are intimately associated with carbonate nodules, which are a result of AOM. We have studied vestimentiferan specimens and associated carbonates from seeps at the Kouilou pockmark field on the Congo deep-sea fan and find that some of the posterior ‘root’ tubes of living specimens are enclosed with carbonate indurated sediment and other, empty examples are partially or completely replaced by the carbonate mineral aragonite. This replacement occurs from the outside of the tube wall inwards and leaves fine-scale relict textures of the original organic tube wall. The process of mineralization is unknown, but is likely a result of post-mortem microbial decay of the tube wall proteins by microorganisms or the precipitation from locally high flux of AOM derived carbonate ions. The aragonite-replaced tubes from the Kouilou pockmarks show similar features to carbonate tubes in ancient seep deposits and make it more likely that many of these fossil tubes are those of vestimentiferans. These observations have implications for the supposed origination of this group, based on molecular divergence estimates. 相似文献
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A probabilistic approach to exposure risk assessment 总被引：1，自引：1，他引：0
Crispin M. Mutshinda Imoh Antai Robert B. O’Hara 《Stochastic Environmental Research and Risk Assessment (SERRA)》2008,22(4):441-449
The introduction of hazardous substances into the environment has long been recognized as being a cause of several diseases
in humans, wildlife, and plants. The damaging character of suspected contaminants is usually assessed via a “reject/retain”
design with no explicit link between levels of exposure and intensities of the potential adverse health effects even though
this connection may be important for the development of public health regulations that limit exposure to hazardous substances.
Here, we propose a probabilistic approach to exposure risk assessment as a way around this typical flaw. We develop a Bayesian
model using proximity to the source of an alleged contaminant as a surrogate for exposure. Subsequently, we carry out an experimental
study based on simulated data to illustrate the model implementation with real world data. We also discuss a possible way
of extending the model to accommodate potential heterogeneity in the spatial distribution of the focal disease. 相似文献
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Darren M. Parsons Mark A. Morrison Simon F. Thrush Crispin Middleton Matt Smith Keren T. Spong Dane Buckthought 《Marine Ecology》2013,34(4):492-500
Estuarine and sheltered coastal habitats that contain physical structure are potentially important nurseries for juvenile fish. Many of these structured habitats, however, are potentially vulnerable to stressors such as elevated turbidity. Quantifying the benefits that structured habitats provide to juvenile fish may therefore be an important step in the management process. We investigated the value of structured habitat for juvenile fishes in northeastern New Zealand, using artificial seagrass units (ASUs) with varying blade density. ASUs were predominantly settled by juvenile snapper (Pagrus auratus) and spotty (Notolabrus celidotus). The density of both snapper and spotty was greatest on ASUs with the highest blade density. For snapper, a gradient in abundance was present (with higher abundance closer to the harbour mouth), suggesting either a gradient in the supply of recruits or a potential recruitment shadow effect. The size distribution of juvenile snapper (12–70 mm fork length) was very similar on both sampling trips, despite the 2‐month interim period, suggesting an ontogenetic habitat shift dependent on size. The condition of juvenile snapper from ASUs with the highest blade density was also greater than the other ASU treatments. Overall, these results provide new empirical evidence that habitats with physical structure within shallow estuarine systems are important to early stage juvenile fishes such as snapper, and indicate that the location‐specific context of that habitat is also likely important. 相似文献
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Management of fish populations is often focused on the exploitation of adult fish. Maintaining the habitat requirements of all life stages may also be an important consideration. We investigated the value of structured habitat to juvenile fishes within a northeastern New Zealand harbour using artificial seagrass units (ASUs). Specifically, we deployed ASUs across treatments with high vs. low habitat manipulations. We hypothesised that if the abundance of recruiting juvenile fishes was greater on the high habitat availability treatments this would suggest that the availability of habitat was limiting juvenile fish abundance. Our analyses were focused on the four most abundant fishes that settled on our ASUs: snapper (Pagrus auratus); spotty (Notolabrus celidotus); trevally (Pseudocaranx dentex); and an assemblage of pipefish species. For snapper, spotty and pipefish, abundance was greater on the high habitat availability treatments. This result would be unlikely to occur if the availability of juvenile fishes was limiting, suggesting that juvenile fish abundance is more likely to be limited by habitat. In terms of spatial gradients, spotty abundance and size increased with distance into the harbour. The spatial gradient present for spotty indicates the importance of placing the habitat dependency of juvenile fish into a landscape context. Overall, these results demonstrate that maintaining structured habitats may be an important consideration for some valuable inshore fish populations in northeastern New Zealand. 相似文献
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Crispin Katongo Friedrich Koller Urs Kloetzli Christian Koeberl Francis Tembo Bert De Waele 《Journal of African Earth Sciences》2004,40(5):219
There are several pre-orogenic Neoproterozoic granitoid and metavolcanic rocks in the Lufilian–Zambezi belt in Zambia and Zimbabwe that are interpreted to have been emplaced in a continental-rift setting that is linked to the break-up of the Rodinia supercontinent. However, no geochemical data were previously available for these rocks in the Zambian part of the belt to support this model. We conducted petrographic and whole-rock chemical analyses of the Neoproterozoic Nchanga Granite, Lusaka Granite, Ngoma Gneiss and felsic metavolcanic rocks from the Lufilian–Zambezi belt in Zambian, in order to evaluate their chemical characteristics and tectonic settings. Other magmatic rocks of importance for understanding the evolution of the belt in Zambia, included in this study, are the Mesoproterozoic Munali Hills Granite and associated amphibolites and the Mpande Gneiss. The Neoproterozoic rocks have monzogranitic compositions, aluminum-saturation indices (ASI) < 1.1, and high contents of high field strength elements (HFSE) and rare earth elements (REE). The chondrite-normalised spider diagrams are similar to those of A-type granites from the Lachlan fold belt and show negative Sr, P, and Ti anomalies. On various tectonic discrimination diagrams the Neoproterozoic rocks plot mainly in A-type granite fields. These petrographic and trace element compositions indicate that these rocks are A-type felsic rocks, but they do not have features of granites and rhyolites emplaced in true continental-rift settings, as previously suggested. On the basis of the A-type features and independent regional geological and geochronological data, we suggest that the Neoproterozoic granitoid and felsic metavolcanic rocks were emplaced during the earliest extensional stages of continental rifting in the Lufilian–Zambezi belt. The apparent continental-arc like chemistry of the granitoid and felsic metavolcanic rocks is thus inferred to be inherited from calcalkaline sources. The Mesoproterozoic Munali Hills Granite and Mpande Gneiss have trace element features e.g., Nb–Ta depletions, which indicate that that these gneisses were emplaced in a convergent-margin setting. The MORB-normalised spider diagram of co-magmatic amphibolites exhibit a fractionated LILE/HFSE pattern recognized in subduction zones. This inference is consistent with remnants of ocean crust, juvenile Island arcs and ophiolites elsewhere in the Mesoproterozoic Irumide belt in Zambia and Zimbabwe. In addition, we report the first U–Pb zircon age of 1090.1 ± 1.3 Ma for the Munali Hills Granite. The age for the Munali Hills Granite provides new constraints on correlation and tectono-thermal activity in the Lufilian–Zambezi belt. The age of the Munali Hills Granite indicates that some supracrustal rocks in the Zambezi belt of Zambia, which were previously thought to be Neoproterozoic and correlated with the Katanga Supergroup in the Lufilian belt, are Mesoproterozoic or older. Consequently, previous regional lithostratigraphic correlations in the Lufilian–Zambezi belt would require revision. 相似文献
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Katherine L. Crispin James A. Van Orman 《Physics of the Earth and Planetary Interiors》2010,180(3-4):159-171
Experiments were performed to determine concentration-dependent diffusion coefficients of Cr3+ and Ga3+ in periclase at temperatures of 1563–2273 K. Diffusion profiles measured in the quenched samples are consistent with a theoretical model in which the mobile species is a bound M3+-vacancy pair, and each profile was fitted to determine the binding energy and diffusion coefficient of the pair. Trivalent chromium-vacancy pairs diffuse more slowly than Ga3+-vacancy pairs, and with higher migration energy, 237 kJ/mol vs. 190 kJ/mol. Cation vacancies also bind less tightly to Cr3+ than to Ga3+, with average binding free energies of ?22 and ?83 kJ/mol, respectively. At all concentrations and temperatures, Cr3+ diffuses much more slowly than Ga3+, by up to two orders of magnitude. The differences between Cr3+ and Ga3+ cannot be explained by differences in ionic radius or dipole polarizability, but are consistent with the influence of the crystal field on the partially occupied 3d orbitals of Cr3+. The crystal field splitting stabilizes Cr3+ on the octahedral cation site, increasing the energy required for Cr3+ to exchange positions with an adjacent vacancy. It also makes Cr3+-vacancy pairs less favorable, with the presence of a nearest-neighbor vacancy disrupting the symmetry of the octahedral site, thus diminishing the crystal field stabilization. Trends in the diffusion of first-row divalent transition metals in periclase can also be explained by the crystal field effect. High-spin to low-spin transitions in Fe2+, Co2+ or Mn2+ would significantly enhance their crystal field stabilization in periclase, and if such spin transitions occur in the deep mantle, they would be expected to slow the diffusivity of these ions significantly, perhaps by several orders of magnitude. 相似文献
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Crispin H.V. Cooper 《International journal of geographical information science》2013,27(8):1293-1309
Closeness and betweenness are forms of spatial network analysis grounded in a long-standing tradition of measuring accessibility and flow potential. More recently, these measures have been enhanced by the concept of spatial localization, producing effective models for the prediction of pedestrian and vehicle driver behaviour.A contradiction arises where the distance metric used to define locality does not match the distance metric used to define shortest paths for closeness and betweenness. A typical case is the use of angular shortest paths within a Euclidean buffer as a pedestrian flow model. Such a model assumes that people make a mode choice based on distance, but a route choice based on least angular change – even when this results in an excessively long ‘problem route’, which conflicts with their criterion for mode choice.This study examines the prevalence of problem routes and the magnitude of their effect on some pedestrian and vehicle models. We show that while in a weighted analysis, pathological cases could invalidate an entire model, in the models presented the effect of this contradiction is minor. We do this by comparing model predictions to real flow data, using four strategies for handling problem routes: ignore, discard, reroute and strict locality. Strict locality is justified on the grounds of bounded rationality. We find all strategies to give broadly similar results, although the reroute and strict strategies give marginally better simulation accuracy. We also present a discussion of the characteristics of each strategy, and findings on computational efficiency.We conclude that it is prudent in any computation of localized closeness and betweenness to consider the impact of problem routes; however, they do not necessarily invalidate these forms of analysis, which remain useful. 相似文献
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