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ABSTRACT Carboniferous speleothem calcites in un-metamorphosed limestones from South Wales exhibit crystal diminution (degrading neomorphism) textures. These textures result from processes which have been considered only important under metamorphic conditions. The textures are interpreted as the result of recrystallization associated with dislocation processes. These processes relate to low temperature creep associated with low strain rates extended over long periods of time. The textures described here occur in unusually large crystals but similar textures have been described in limestones from deep boreholes. Dislocation processes, recovery and recrystallization are likely to be important processes operating during deep burial diagenesis. 相似文献
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Volatiles in Basaltic Glasses from Loihi Seamount, Hawaii: Evidence for a Relatively Dry Plume Component 总被引：6，自引：3，他引：6
New H2O, CO2 and S concentration data for basaltic glasses fromLoihi seamount, Hawaii, allow us to model degassing, assimilation,and the distribution of major volatiles within and around theHawaiian plume. Degassing and assimilation have affected CO2and Cl but not H2O concentrations in most Loihi glasses. Waterconcentrations relative to similarly incompatible elements inHawaiian submarine magmas are depleted (Loihi), equivalent (Kilauea,North Arch, Kauai–Oahu), or enriched (South Arch). H2O/Ceratios are uncorrelated with major element composition or extentor depth of melting, but are related to position relative tothe Hawaiian plume and mantle source region composition, consistentwith a zoned plume model. In front of the plume core, overlyingmantle is metasomatized by hydrous partial melts derived fromthe Hawaiian plume. Downstream from the plume core, lavas tapa depleted source region with H2O/Ce similar to enriched Pacificmid-ocean ridge basalt. Within the plume core, mantle components,thought to represent subducted oceanic lithosphere, have waterenrichments equivalent to (KEA) or less than (KOO) that of Ce.Lower H2O/Ce in the KOO component may reflect efficient dehydrationof the subducting oceanic crust and sediments during recyclinginto the deep mantle. KEY WORDS: basalt; Hawaii; mantle; plumes; volatiles 相似文献
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Eleanor T. DIXON Donald D. BOGARD Daniel H. GARRISON 《Meteoritics & planetary science》2003,38(3):341-355
Abstract— This study presents the first determinations of 39Ar‐40Ar ages of R chondrites for the purpose of understanding the thermal history of the R chondrite parent body. The 39Ar‐40Ar ages were determined on whole‐rock samples of four R chondrites: Carlisle Lakes, Rumuruti, Acfer 217, and Pecora Escarpment #91002 (PCA 91002). All samples are breccias except for Carlisle Lakes. The age spectra are complicated by recoil and diffusive loss to various extents. The peak 39Ar‐40Ar ages of the four chondrites are 4.35, ?4.47 ± 0.02, 4.30 ± 0.07 Ga, and 4.37 Ga, respectively. These ages are similar to Ar‐Ar ages of relatively unshocked ordinary chondrites (4.52–4.38 Ga) and are older than Ar‐Ar ages of most shocked ordinary chondrites («4.2 Ga). Because the meteorites with the oldest (Rumuruti, ?4.47 Ga) and the youngest (Acfer 217, ?4.30 Ga) ages are both breccias, these ages probably do not record slow cooling within an undisrupted asteroidal parent body. Instead, the process of breccia formation may have differentially reset the ages of the constituent material, or the differences in their age spectra may arise from mixtures of material that had different ages. Two end‐member type situations may be envisioned to explain the age range observed in the R chondrites. The first is if the impact(s) that reset the ages of Acfer 217 and Rumuruti was very early. In this case, the ?170 Ma maximum age difference between these meteorites may have been produced by much deeper burial of Acfer 217 than Rumuruti within an impact‐induced thick regolith layer, or within a rubble pile type parent body following parent body re‐assembly. The second, preferred scenario is if the impact that reset the age of Acfer 217 was much later than that which reset Rumuruti, then Acfer 217 may have cooled more rapidly within a much thinner regolith layer. In either scenario, the oldest age obtained here, from Rumuruti, provides evidence for relatively early (?4.47 Ga) impact events and breccia formation on the R chondrite parent body. 相似文献
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Two linear optimal control laws and a non-linear control strategy are critically evaluated. They are implemented in a ten-story frame structure. For the linear control laws, both an active bracing system and a hybrid mass damper are considered as control devices, while the non-linear control law can be implemented with either an active or semi-active bracing system. The active and semi-active systems are compared to a passive bracing system with linear viscous dampers and to a hybrid system consisting of a passive bracing and a hybrid mass damper. Dimensionless indices based on the reduction of the maximum story drift and on the maximum control force required are introduced to compare the efficiencies of different control strategies. While the linear optimal control laws exhibit an excellent performance, the non-linear control law, in addition to its simplicity and robustness, appears to be more efficient when the allowable control force is within a certain limit. Furthermore, one attractive feature of the latter is that it can be implemented with semi-active devices to minimize the power requirement. 相似文献
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Abstract There are discrete masses of un-deformed metabasite within the blueschist series of the island of Syros. Greece. Around the margins of these masses are zonal sequences through rocks showing intracrystalline deformation but without a geometric fabric, to rocks with discrete and anastomosing shear zones, and finally to penetratively foliated rocks with isolated relics of the original undeformed texture. Textural relics suggest that this spatial sequence is at least qualitatively also a temporal sequence.
This progressive shear zone deformation took place concurrently with a glaucophane-epidote to eclogite reaction. The reaction pathways in the rocks that underwent the shear zone deformation can be compared with those in rocks of a similar composition that suffered a longer deformation history and show no relics of an undeformed parent. Although the final assemblages are in both cases the same, the pathways are different. These differences are in part related to reactions promoted by the change from local to bulk equilibrium on the onset of deformation in the rocks. They are also related to the crystallization and later breakdown during the sequence of progressive equilibration of a metastable phase, in this case an impure glaucophane. 相似文献
This progressive shear zone deformation took place concurrently with a glaucophane-epidote to eclogite reaction. The reaction pathways in the rocks that underwent the shear zone deformation can be compared with those in rocks of a similar composition that suffered a longer deformation history and show no relics of an undeformed parent. Although the final assemblages are in both cases the same, the pathways are different. These differences are in part related to reactions promoted by the change from local to bulk equilibrium on the onset of deformation in the rocks. They are also related to the crystallization and later breakdown during the sequence of progressive equilibration of a metastable phase, in this case an impure glaucophane. 相似文献
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Donald D. BOGARD Eleanor T. DIXON Daniel H. GARRISON 《Meteoritics & planetary science》2010,45(5):723-742
Abstract– Compared with ordinary chondrites, there is a relative paucity of chronological and other data to define the early thermal histories of enstatite parent bodies. In this study, we report 39Ar‐40Ar dating results for five EL chondrites: Khairpur, Pillistfer, Hvittis, Blithfield, and Forrest; five EH chondrites: Parsa, Saint Marks, Indarch, Bethune, and Reckling Peak 80259; three igneous‐textured enstatite meteorites that represent impact melts on enstatite chondrite parent bodies: Zaklodzie, Queen Alexandra Range 97348, and Queen Alexandra Range 97289; and three aubrites, Norton County, Bishopville, and Cumberland Falls Several Ar‐Ar age spectra show unusual 39Ar recoil effects, possibly the result of some of the K residing in unusual sulfide minerals, such as djerfisherite and rodderite, and other age spectra show 40Ar diffusion loss. Few additional Ar‐Ar ages for enstatite meteorites are available in the literature. When all available Ar‐Ar data on enstatite meteorites are considered, preferred ages of nine chondrites and one aubrite show a range of 4.50–4.54 Ga, whereas five other meteorites show only lower age limits over 4.35–4.46 Ga. Ar‐Ar ages of several enstatite chondrites are as old or older as the oldest Ar‐Ar ages of ordinary chondrites, which suggests that enstatite chondrites may have derived from somewhat smaller parent bodies, or were metamorphosed to lower temperatures compared to other chondrite types. Many enstatite meteorites are brecciated and/or shocked, and some of the younger Ar‐Ar ages may record these impact events. Although impact heating of ordinary chondrites within the last 1 Ga is relatively common for ordinary chondrites, only Bethune gives any significant evidence for such a young event. 相似文献
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The Upper Ludlow Douro Formation contains the first reported Silurian sponge reefs. These relatively small (5–35 m diameter), mound-shaped structures contain, on average, 35% lithistid demosponges. Reefs are surrounded by irregular haloes of crinoid debris; abundance and diversity of all fossil groups decreases away from the reefs. Each reef is underlain by a lens of crinoid wackestone to grainstone rich in crinoid holdfasts; trepostomate bryozoans, solenoporacean algae and rhynchonellid brachiopods are locally common. The bulk of each reef consists of lime mudstone with abundant lithistid sponges. This is capped by a thin layer of wackestone with abundant tabulate and rugose corals and fewer lithistid sponges, calcareous algae, trepostomate bryozoans and stromatoporoids. This zonation, in which a sponge colonization community was replaced by a coral diversification community, is similar to that reported from some Middle Ordovician, Upper Jurassic and Holocene sponge reefs. The Douro sponge reefs were relatively low structures, with about 3 m maximum topographic relief. They grew on a broad carbonate platform, probably in warm, tranquil, turbid waters of normal or near-normal marine salinity. Periodic influxes of terrigenous mud adversely affected reef size, and caused biotic changes. Some of the reef lime mud was derived from non-reef sources, but significant quantities were also produced on the reefs. Reefs underwent synsedimentary lithification, bioerosion and minor storm erosion. Fabrics and compositions of sparry calcite in cavities record three generations of meteoric cementation. Originally siliceous spicules of the lithistid sponges were dissolved and the moulds later filled with sparry calcite. Early dissolution of siliceous spicules is common in reef environments, and may have caused fossil sponges to be under-represented in ancient reefs. 相似文献
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An Experimental Study of Water and Carbon Dioxide Solubilities in Mid-Ocean Ridge Basaltic Liquids. Part I: Calibration and Solubility Models 总被引：14，自引：7，他引：7
DIXON JACQUELINE EABY; STOLPER EDWARD M.; HOLLOWAY JOHN R. 《Journal of Petrology》1995,36(6):1607-1631
Experiments were conducted to determine the solubilities ofH2O and CO2 and the nature of their mixing behavior in basalticliquid at pressures and temperature relevant to seqfloor eruption.Mid-ocean ridge basaltic (MORB) liquid was equilibrated at 1200°Cwith pure H2O at pressures of 176–717 bar and H2O—CO2vapor at pressures up to 980 bar. Concentrations and speciationof H2O and CO2 dissolved in the quenched glasses were measuredusing IR spectroscopy. Molar absorptivities for the 4500 cm–1band of hydroxyl groups and the 5200 and 1630 cm–1 bandsof molecular water are 0•67±0•03, 0•62±0•07,and 25±3 l/mol-cm, respectively. These and previouslydetermined molar absorptivities for a range of silicate meltcompositions correlate positively and linearly with the concentrationof tetrahedral cations (Si+Al). The speciation of water in glass quenched from vapor-saturatedbasaltic melt is similar to that determined by Silver &Stolper (Journal of Petrology 30, 667–709, 1989) in albiticglass and can be fitted by their regular ternary solution modelusing the coefficients for albitic glasses. Concentrations ofmolecular water measured in the quenched basaltic glasses areproportional to f H2O in all samples regardless of the compositionof the vapor, demonstrating that the activity of molecular waterin basaltic melts follows Henry's law at these pressures. Abest fit to our data and existing higher-pressure water solubilitydata (Khitarov et al., Geochemistry 5, 479–492, 1959;Hamilton et al., Journal of Petrology 5, 21–39, 1964),assuming Henrian behavior for molecular water and that the dependenceof molecular water content on total water content can be describedby the regular solution model, gives estimates for the Vo, mH2Oof 12±1 cm3/mol and for the 1-bar water solubility of0•11 wt%. Concentrations of CO2 dissolved as carbonate in the melt forpure CO2-saturated and mixed H2O-CO2-saturated experiments area simple function of fCO2 These results suggest Henrian behaviorfor the activity of carbonate in basaltic melt and do not supportthe widely held view that water significantly enhances the solutionof carbon dioxide in basaltic melts. Using a Vo, mr of 23 cm3/mol(Pan et al., Geochimica et Cosmochimica Acta 55, 1587–1595,1991), the solubility of carbonate in the melt at 1 bar and1200°C is 0•5 p.p.m. Our revised determination of CO2solubility is 20% higher than that reported by Stolper &Holloway (Earth and Planetary Science Letters 87, 397–408,1988). KEY WORDS: mid-ocean ridge basalts; water and carbon dioxide solubility; experimental petrology 相似文献