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The Red Hill complex of New Hampshire is unusual for the WhiteMountain Magma Series of northern New England because it consistsof both silica-undersaturated and -saturated to -oversaturatedsyenites. Amphibole, pyroxene, and apatite in two of the saturatedunits, the Outer Coarse Syenite (OCS) and the Garland Peak Syenite(GPS), and in the undersaturated Nepheline Sodalite Syenite(NSS), were analyzed to determine the relationship between coexistingunder-saturated and saturated magmas. Mafic enclaves in theNSS and the GPS were also studied to elucidate their relationshipswith the host syenites. In addition to mafic enclaves, the NSS contains later emplacedcamptonitic dikes and associated pipe-like benmoreites. Thebenmoreites contain amphibole that is compositionally continuouswith amphibole in the NSS. However, REE and other trace elementabundances in apatite from the benmoreites and the NSS are notcompatible with a genetic relationship between the two. Maficenclaves within the NSS contain amphibole and pyroxene thatare compositionally continuous with the NSS. Bulk-rock compositionsof the enclaves plot along trends defined by the NSS. Furthermore,chondrite-normalized REE patterns for apatite in both the enclavesand the NSS are parallel, and REE abundances increase systematicallyfrom the enclaves to the NSS. We therefore suggest that theenclaves represent magmas similar to the NSS parent that intrudedup into its daughter products. These magmas appear to have beentephritic to phonotephritic in composition. Abundances of REE in apatite in the Nepheline Sodalite Syenite(NSS) are distinct from those in apatite in the silica-saturatedOCS. OCS apatites have LREE abundances up to 26 000 times chondritesand La/Yb ratios of 16–27. NSS apatites have comparableLREE concentrations, but HREE abundances are considerably lowerthan those of the OCS; La/Yb ratios range from 68 to 104. Theseobserved differences in both the REE and other trace elementabundances between apatite in the two rocks present difficultieswith a common parental magma hypothesis for the NSS and OCS.Hence it is suggested that, although the OCS and NSS are contemporaneousin time and space, they are probably not consanguineous. The silica-saturated GPS is a fine-grained syenite containingstrongly zoned amphiboles with kaersutite to hastingsite coresrimmed by hastingsitic hornblende and ferro-hornblende. Discretegrains of hastingsitic hornblende and ferro-hornblende occurin a feldspar-quartz groundmass. Coarser-grained, quartz-richpatches, containing feldspars and ferro-hornblende and ferroedenite,are also found in the GPS. The kaersutite cores are identicalto the amphibole in the GPS enclaves and the NSS suite. TheseGPS enclaves are silica undersaturated; the kaersutite coresin the GPS host rocks are probably xenocrysts derived from disaggregatedundersaturated magmas similar to that represented by the enclaves.  相似文献   
2.
Two types of mafic enclaves occur in the Dinkey Creek pluton:ubiquitous microgranular enclaves, and rare gabbroic enclaves.Common petrographic features of the microgranular enclaves are:(1) fine grain-size, (2) abundant acicular apatite, and (3)plagioclase zoned from bytownitic cores to andesine-labradoriterims, with sharp boundaries between these main zones. Subordinateoscillatory variations are commonly superimposed on both coresand rims. It has been found by secondary ion mass spectrometrythat the rims are identical in major and trace element compositionto plagioclase in the tonalite, which suggests crystallizationfrom the same or similar magmas. The gabbroic enclaves are composedpredominantly of hornblende (50–85%) and appear to bemagmatic segregations. The microgranular enclaves and host rocks display two convergingtrends on silica variation diagrams for Fe2O3, TiO2, Al2O3,Zn, and Zr. The dominant trend is defined by small microgranularenclaves, by samples from a large (20 m?30 m) microgranularenclave, and by the Dinkey Creek tonalites and granodiorites.The subordinate trend covers tholeiltic dikes and tonalitich and converges with the Dinkey Creek host rocks at 61 wt.%SiO2 Alkali and alkaline earth elements exhibit greater variabilitythan the above constituents and appear to be either enrichedor depleted as required for equilibrium with the host rocks.Low CaO and Sr concentrations in small enclaves (<30 cm)apparently reflect a lower modal abundance of calcic plagioclaseand more sericitization of this feldspar as compared with theplagioclase of the large microgranular enclave. The large enclaveis also richer in MgO than the small enclaves. With the exceptionof the alkali elements, the major element compositions of themicrogranular enclaves approach high-Al basaltic to andesiticcom positions. In one analyzed microgranular enclave, low La/Cerelative to chondrites and more abundant HREE than in othermicrogranular samples suggest that it may also contain minorcumulus hornblende. The petrographic and whole-rock geochemical relations, and theplagioclase compositions in the microgranular enclaves and theirhost rocks, indicate that the microgranular enclaves representmixtures of quenched basalts and Dinkey Creek tonalites. Itappears that dikes of high-alumina basalt were intruded intothe lower, tonalitic portions of the Dinkey Creek pluton, wherethey were partially quenched along an interface with overlyingtonalitic magma. Large portions of residual liquid in the partiallyquenched basalts permitted mixing with the overlying magma toform a hybrid zone. This zone was then disaggregated, yieldingthe enclaves, and they were dispersed throughout the upper partof the Dinkey Creek magma chamber. Subsequent crystallizationof tonalitic melt within the enclaves produced the zoned plagioclaseand re-equilibrated hornblende and biotite in the enclaves tothe Dinkey Creek magmatic conditions. Scouring disrupted hornblende-richmagmatic segregations and produced the gabbroic enclaves.  相似文献   
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