Effect of signal contamination in matched-filter detection of the signal on a cluttered background     

Theiler  J. Foy  B.R. 《Geoscience and Remote Sensing Letters, IEEE》2006,3(1):98-102

To derive a matched filter for detecting a weak target signal in a hyperspectral image, an estimate of the band-to-band covariance of the target-free background scene is required. We investigate the effects of including some of the target signal in the background scene. Although the covariance is contaminated by the presence of a target signal (there is increased variance in the direction of the target signature), we find that the matched filter is not necessarily affected. In fact, if the variation in plume strength is strictly uncorrelated with the variation in background spectra, the matched filter and its signal-to-clutter ratio (SCR) performance will not be impaired. While there is little a priori reason to expect significant correlation between the plume and the background, there usually is some residual correlation, and this correlation leads to a suppressing effect that limits the SCR obtainable even for strong plumes. These effects are described and quantified analytically, and the crucial role of this correlation is illustrated with some numerical examples using simulated plumes superimposed on real hyperspectral imagery. In one example, we observe an order-of-magnitude loss in SCR for a matched filter based on the contaminated covariance.  相似文献   

A spectrophotometric measurement of soil cation exchange capacity based on cobaltihexamine chloride absorbance     

Delphine Aran  Armand Maul  Jean-Franois Masfaraud 《Comptes Rendus Geoscience》2008,340(12):865-871

Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH₃)₆³⁺ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation.  相似文献   

Burial of redox-sensitive metals and organic matter in the equatorial Indian Ocean linked to precession     

Delphine PaillerEdouard Bard  Frauke RostekYan Zheng  Richard MortlockAlexander van Geen 《Geochimica et cosmochimica acta》2002,66(5):849-865

Authigenic metals (uranium, cadmium, and molybdenum), organic carbon (OC) and total C₃₇ alkenone (totC₃₇) concentrations were measured for the last 350 kyr in core MD900963, located in the eastern equatorial Arabian Sea. Authigenic metal concentrations on a carbonate-free basis range between 1 and 17 ppm, 0.5 and 6 ppm, and 0.5 and 4 ppm for U, Cd, and Mo, respectively. The profiles are characterized by well-defined 23 kyr cycles between oxic and mildly suboxic conditions. The redox-sensitive metal profiles also follow variations in the concentrations of OC (0.2-0.9%) and alkenones (0.2-6.7 ppm). The coupled variations in inorganic and organic constituents are attributed to a 23-kyr cycle in primary production above site MD900963, as suggested by clear correlations with independent micropaleontologic proxies (primary productivity indices based on foraminifera and coccoliths and fragmentation of foraminiferal shells). The 23-kyr cycles do appear to be primarily driven by productivity rather than changes in bottom water oxygen. Comparison with other records indicates that if this interpretation is correct, productivity variations across much of the Indian Ocean have been dominated by precessional forcing, with high productivity in phase with low summer insolation in the Northern Hemisphere. This interpretation contrasts with the traditional attribution of enhanced productivity in the Indian Ocean with periods of high summer insolation.  相似文献   

Phototransformation of aromatic pollutants in solar light: Photolysis versus photosensitized reactions under natural water conditions   总被引：3，自引：0，他引：3  

Delphine Vialaton  Claire Richard 《Aquatic Sciences - Research Across Boundaries》2002,64(2):207-215

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An Early-Cambrian UPb apatite cooling age for the high-temperature regional metamorphism in the Piancó area,Borborema Province (NE Brazil): initial conclusions     

Bruno Dhuime  Delphine Bosch  Olivier Bruguier  Renaud Caby  Carlos Archanjo 《Comptes Rendus Geoscience》2003,335(15):1081-1089

The Borborema Province (BP) of northeastern Brazil is a complex crustal assemblage, which has undergone a polycyclic evolution during the Proterozoic. In the Piancó-Alto Br??gida belt, a metamorphosed leucosome vein inserted in amphibolites has a trace element pattern suggesting a T-MORB protolith. Apatites yield a REE pattern indicating growth in equilibrium with garnet, thus pointing to its metamorphic origin. UPb analyses yield an age of 540±5 Ma interpreted as a cooling age following amphibolite facies regional metamorphism associated with granitic emplacement at ca. 580 Ma. The resulting slow cooling rates (ranging from ca. 2.5 to 5 °C Ma^?1) are consistent with underplating of mafic magmas, or crustal thickening caused by nappe stacking, as possible processes governing the metamorphic evolution of the BP. To cite this article: B. Dhuime et al., C. R. Geoscience 335 (2003).  相似文献   

An Alternative Protocol for Single Zircon Dissolution with Application to (U‐Th‐Sm)/He Thermochronometry          下载免费PDF全文

Bouchaïb Tibari  Arnaud Vacherat  Martin Stab  Raphaël Pik  Delphine Yeghicheyan  Pascal Hild 《Geostandards and Geoanalytical Research》2016,40(3):365-375

Zircon (U‐Th‐Sm)/He (ZHe) thermochronometry is a powerful tool that has been widely used in geology to constrain the exhumation histories of orogens. In this study, we present an alternative protocol for dissolving zircon grains for determination of parent nuclides. This new alkali fusion procedure developed at the SARM (Service d'Analyse des Roches et des Minéraux) in Nancy, France, is fast (requiring only 2 d, including cleaning steps) and offers several advantages over conventional methods by avoiding: (i) use of HF pressure dissolution and (ii) complete removing of grains from the metal microvials. After dissolution, U, Th and Sm were measured using an ICP‐MS. We tested the new procedure on two different ZHe reference materials, the Fish Canyon Tuff and Buluk Tuff; these provided precision values for ZHe‐age estimations of 9 and 6% (1s), respectively. In addition, using this method, zircons from the Buluk Tuff are shown to be chemically more homogenous and more suitable for assessing the uncertainty of the entire integrated procedure.  相似文献   

Inverse model method for estimating assimilation by aquatic invertebrates     

John T. Lehmann  Robert Foy  Donna A. Lehman 《Aquatic Sciences - Research Across Boundaries》2001,63(2):168-181

Physiological data indicate that a 3-compartment model appropriately represents ingestion, assimilation, and accumulation of somatic and reproductive tissue by an aquatic invertebrate predator. A secondary production model calibrated to growth and respiration data is used to constrain the model equations. Inverse solution methods are used to estimate rate constants for digestion and for net accrual of tissue by growing animals at different temperatures. Predicted time to 50% maximum digestion matches well with the empirical rate of digestion of prey enzymes in the predator gut. Model-derived digestion rates are consistent with the assimilation rate constant obtained by independent radiotracer methods, and with experimental detection time for prey enzymes. The model approach permits parameter estimation within a complex system of equations so that results can be compared with experimental data.  相似文献   

Routine Analyses of Trace Elements in Geological Samples using Flow Injection and Low Pressure On-Line Liquid Chromatography Coupled to ICP-MS: A Study of Geochemical Reference Materials BR, DR-N, UB-N, AN-G and GH   总被引：6，自引：0，他引：6  

Jean Carignan  Pascal Hild  Guy Mevelle  Jacques Morel  Delphine Yeghicheyan 《Geostandards and Geoanalytical Research》2001,25(2-3):187-198

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Geodynamic implications of deep mantle upwelling in the source of Tertiary volcanics from the Veneto region (South-Eastern Alps)     

Patrizia Macera  Daniela Gasperini  Claudia Piromallo  Janne Blichert-Toft  Delphine Bosch  Aldo Del Moro  Silvana Martin 《Journal of Geodynamics》2003,36(5):563

Major and trace element and Sr–Nd–Hf–Pb isotopic data for the most primitive Tertiary lavas from the Veneto region (South-Eastern Alps, Italy) show the typical features of HIMU hotspot volcanism, variably diluted by a depleted asthenospheric mantle component (⁸⁷Sr/⁸⁶Sr_i=0.70306–0.70378; _Ndi=+3.9 to +6.8; _Hfi=+6.4 to +8.1, ²⁰⁶Pb/²⁰⁴Pb_i=18.786–19.574). P-wave seismic tomography of the mantle below the Veneto region shows the presence of low-velocity anomalies at depth, which is consistent with possible upwellings of plume material. Between the depths of 100–250 km the velocity anomalies are approximately 2–2.5% slower than average, implying a temperature excess of about 220–280 K, in agreement with estimates for other mantle plumes in the world. In this context, the Veneto volcanics may represent the shallow expression of a mantle upflow. The presence of a HIMU-DM component in a collision environment has significant geodynamic implications. Slab detachment and ensuing rise of deep mantle material into the lithospheric gap is proposed to be a viable mechanism of hotspot magmatism in a subduction zone setting.  相似文献   

Review komatiites: from Earth’s geological settings to planetary and astrobiological contexts     

Delphine Nna-Mvondo  Jesus Martinez-Frias 《Earth, Moon, and Planets》2007,100(3-4):157-179

Komatiites are fascinating volcanic rocks. They are among the most ancient lavas of the Earth following the 3.8 Ga pillow basalts at Isua and they represent some of the oldest ultramafic magmatic rocks preserved in the Earth’s crust at 3.5 Ga. This fact, linked to their particular features (high magnesium content, high melting temperatures, low dynamic viscosities, etc.), has attracted the community of geoscientists since their discovery in the early sixties, who have tried to determine their origin and understand their meaning in the context of terrestrial mantle evolution. In addition, it has been proposed that komatiites are not restricted to our planet, but they could be found in other extraterrestrial settings in our Solar System (particularly on Mars and Io). It is important to note that komatiites may be extremely significant in the study of the origins and evolution of Life on Earth. They not only preserve essential geochemical clues of the interaction between the pristine Earth rocks and atmosphere, but also may have been potential suitable sites for biological processes to develop. Thus, besides reviewing the main geodynamic, petrological and geochemical characteristics of komatiites, this paper also aims to widen their investigation beyond the classical geological prospect, calling attention to them as attractive rocks for research in Planetology and Astrobiology.  相似文献