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1.
The transition from feldspar amphibolite to eclogite is a very wide P-T field that extends from some-where close to 5 kbar where the garnet-amphibole pair starts to appear, to 10–20 kbar at albite-out reaction, then up to 25–30 kbar where an hydrated phase such as amphibole can be stable with pyroxene and garnet. Thus the assemblage garnet (py)+ amphibole (tr)+epidote (cz)±plagioclase (ab)±clinopyroxene (di)±quartz (qz)±fluid is commonly reported in a large number of metamorphic terrains. These mineral phases are complex solid-solutions which adapt to variations in environmental conditions mainly by means of continuous reactions. The reaction space, introduced by. Thompson in 1982a, provides a very elegant and powerful tool to approach these high-variance assemblages. The reactions:
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2.
In this contribution, we present a virtual voyage through 3D structures generated by chaotic mixing of magmas and numerical simulations with the aim to highlight the power of 3D representations in the understanding of this geological phenomenon. In particular, samples of mixed juveniles from Salina island (Southern Italy) are reconstructed in 3D by serial lapping and digital montage and numerical simulations are performed by using a 3D chaotic dynamical system. Natural and simulated magma mixing structures are visualized by using several multimedia tools including animations and “virtual reality” models. It is shown that magma interaction processes can generate large spatial and temporal compositional heterogeneities in magmatic systems. The same topological structures are observed in both 3D reconstructed rock samples and chaotic numerical simulations, indicating that the mixing of magmas is governed by chaotic dynamics. The use of 3D multimedia models gives the opportunity to penetrate into magma mixing structures and to understand their significance in the context of magma dynamics. Such an approach is very powerful since multimedia tools can strongly capture the attention of the reader bringing him/her into an interactive and memorable geological experience. Electronic supplementary material  enclosed:  相似文献   
3.
Analysis and simulation of magma mixing processes in 3D   总被引:2,自引:0,他引:2  
D. Perugini  G. Poli  G. D. Gatta 《Lithos》2002,65(3-4):313-330
Magma mixing structures from the lava flow of Lesbos (Greece) are analyzed in three dimensions using a technique that, starting from the serial sections of rock cubes, allows the reconstruction of the spatial distribution of magmas inside rocks. Two main kinds of coexisting structures are observed: (i) “active regions” (AR) in which magmas mix intimately generating wide contact surfaces and (ii) “coherent regions” (CR) of more mafic magma that have a globular shape and do not show large deformations. The intensity of mingling is quantified by calculating both the interfacial area (IA) between interacting magmas and the fractal dimension of the reconstructed structures. Results show that the fractal dimension is linearly correlated with the logarithm of interfacial area allowing discrimination among different intensities of mingling.

The process of mingling of magmas is simulated using a three-dimensional chaotic dynamical system consisting of stretching and folding processes. The intensity of mingling is measured by calculating the interfacial area between interacting magmas and the fractal dimension, as for natural magma mixing structures. Results suggest that, as in the natural case, the fractal dimension is linearly correlated with the logarithm of the interfacial area allowing to conclude that magma mixing can be regarded as a chaotic process.

Since chemical exchange and physical dispersion of one magma inside another by stretching and folding are closely related, we performed coupled numerical simulations of chaotic advection and chemical diffusion in three dimensions. Our analysis reveals the occurrence in the same system of “active mixing regions” and “coherent regions” analogous to those observed in nature. We will show that the dynamic processes are able to generate magmas with wide spatial heterogeneity related to the occurrence of magmatic enclaves inside host rocks in both plutonic and volcanic environments.  相似文献   

4.
Active, carbonate‐mineralizing microbial mats flourish in a tropical, highly evaporative, marine‐fed lagoonal network to the south of Cayo Coco Island (Cuba). Hypersaline conditions support the development of a complex sedimentary microbial ecosystem with diverse morphologies, a variable intensity of mineralization and a potential for preservation. In this study, the role of intrinsic (i.e. microbial) and extrinsic (i.e. physicochemical) controls on microbial mat development, mineralization and preservation was investigated. The network consists of lagoons, forming in the interdune depressions of a Pleistocene aeolian substratum; they developed due to a progressive increase in sea‐level since the Holocene. The hydrological budget in the Cayo Coco lagoonal network changes from west to east, increasing the salinity. This change progressively excludes grazers and increases the saturation index of carbonate minerals, favouring the development and mineralization of microbial mats in the easternmost lagoons. Detailed mapping of the easternmost lagoon shows four zones with different flooding regimes. The microbial activity in the mats was recorded using light–dark shifts in conjunction with microelectrode O2 and HS? profiles. High rates of O2 production and consumption, in addition to substantial amounts of exopolymeric substances, are indicative of a potentially strong intrinsic control on mineralization. Seasonal, climate‐driven water fluctuations are key for mat development, mineralization, morphology and distribution. Microbial mats show no mineralization in the permanently submersed zone, and moderate mineralization in zones with alternating immersion and exposure. It is suggested that mineralization is also driven by water‐level fluctuations and evaporation. Mineralized mats are laminated and consist of alternating trapping and binding of grains and microbially induced magnesium calcite and dolomite precipitation. The macrofabrics of the mats evolve from early colonizing Flat mats to complex Cerebroid or Terrace structures. The macrofabrics are influenced by the hydrodynamic regime: wind‐driven waves inducing relief terraces in windward areas and flat morphologies on the leeward side of the lagoon. Other external drivers include: (i) storm events that either promote (for example, by bioclasts covering) or prevent (for example, by causing erosion) microbial mat preservation; and (ii) subsurface degassing, through mangrove roots and desiccation cracks covered by Flat mats (i.e. forming Hemispheroids and Cerebroidal structures). These findings provide in‐depth insights into understanding fossil microbialite morphologies that formed in lagoonal settings.  相似文献   
5.
The late Messinian mixed carbonate‐siliciclastic platforms of the Sorbas Basin, known as the Terminal Carbonate Complex, record significant changes in carbonate production and geometry. Their facies and stratigraphic architecture result from complex interactions between base‐level fluctuations, evaporite deformation/dissolution and detrital inputs. A 3D quantitative approach (with DIONISOS software) is used to explore the basin‐scale platform architecture and to quantify the carbonate production of the Terminal Carbonate Complex. The modelling strategy consists in integrating detailed 2D field‐based transects and modern carbonate system parameters (e.g. carbonate production rates, bathymetric and hydrodynamic ranges of production). This approach limits user impact and so provides more objective output results. Tests are carried out on carbonate production rates, subsidence and evaporite deformation/dissolution. Numerical modelling provides accurate predictions of geometries, facies distributions and depositional sequence thicknesses, validated by field data. Comparative statistical testing of the field transects and of the various model outputs are used to discern the relative contribution of the parameters tested to the evolution of basin filling. The 3D visualization and quantification of the main carbonate producers (ooids and microbialites) are discussed in terms of changes in base‐level and detrital supply. This study demonstrates that base‐level fluctuations have the greatest impact on the carbonate budget. Evaporite deformation/dissolution affects the type and amount of carbonate production, inducing a transition from an ooid‐ to microbialite‐dominated system and also has a major effect on stratigraphic architecture by inducing the migration of depocentres. The numerical modelling results obtained using modern carbonate system parameters could also be applied to subsurface ooid‐microbialite reservoirs, and the Terminal Carbonate Complex is a good analogue for such systems.  相似文献   
6.
A discussion is made on the general significance of an Early Miocene (22–23 Ma, K/Ar dating) basaltic dike swarm that outcrops within large areas of the central and western Betic Zone of the Betic Cordilleras (Southern Spain). This dike swarm is thought to represent the remains of one of the earliest magmatic episodes within the the Neogene volcanic province that is associated with the late orogenic evolution of the Alboran region, and undoubtedly offers the best preserved igneous material related to this early stage that is known at present. The dike rocks (hypabyssal equivalents of andesitic basalts and basaltic andésites) have both major and trace-element abundance patterns that are akin to those of arc-tholeiitic suites. The field relationships and areal distribution of the dike swarm suggest, on the other hand, that a major E-W-trending rifting belt could have been developing within the Alboran Block in oligo-miocene times, previous to its collision with adjacent continental borderlands in the Early-Middle Miocene.Because of their magmatic character and wide distribution, it is proposed that these dike rocks may be regarded as an indication of the existence of roughly contemporaneous (Oligo-Miocene) Benioff-Wadati zone activity under the Alboran Area, which also points towards the previous existence of subductable lithosphere in its surroundings. The main dilatational vector during dike emplacement was already normal to the present E-W stretching of the Alboran Basin proper, which also adds to the possibility that the latter had already started to individualize tectonically in Oligo-Miocene times, and that some of its present crustal features, especially a prominent E-W-trending pattern of magnetic anomalies, had been generated in relation with the dike event. Continued postcollisional Middle Miocene to Pliocene calc-alkaline to ultrapotassic volcanism in the same area could hence have resulted from decompression partial melting of an already contaminated, and still thermally anomalous, mantle wedge, connected with the occurrence of traverse strike-slip and extensional deep faulting within a crustal segment that stretches from southeastern Spain to Morocco.
Zusammenfassung Über die generelle Bedeutung einer Vielzahl von Gängen (22–23 Ma, K/Ar-Datierung) wird diskutiert, die in einem weiten Gebiet der Betischen Zone aufgeschlossen sind. Diese Vielzahl von Gängen repräsentiert wahrscheinlich eine der ersten magmatischen Episoden innerhalb der vulkanischen neogenen Provinz, welche mit der späten tektonischen Entwicklung der Region des Alboranischen Meeres verbunden ist. Diese Gänge bieten in jedem Fall das besterhaltene magmatische Material, verglichen mit denen, die man bis jetzt kennt. Die Gesteine, die diese Gänge bilden (hypoabyssiche Aequivalente andesitischer Basalte und basaltischer Andesite), besitzen ebenso Hauptelemente wie auch Spurenelemente, die den Tholeiit-Serien der Inselbögen ähnlich sind. Ihre Flächenverteilung und Feldbeziehungen geben auch an, daß ein ausgedehnter Gürtel in der Zone von Alboran in oligo-miozänen Zeiten in Entwicklung war, bevor sich der Zusammenstoß des sogenannten Alboranblocks mit der naheliegenden Kontinentalzone im unteren-mittleren Miozän produzierte.Diese Gesteine geben das gleichzeitige Vorhandensein einer Benioff-Wadati-Zone aktiv unter der Region von Alboran an, sowohl auf Grund ihres magmatischen Aussehens wie auch auf Grund ihrer weiten Flächenverteilung, und deshalb zeigen sie auch die vorige Existenz subduktionsfähiger Lithosphäre in ihrer Nähe. Der Hauptdilatationsvektor war schon während der Intrusion der Gänge normal zur jetzigen Elongation des Alboran-Beckens gerichtet, was auch vermuten läßt, daß jenes Becken schon während des Oligozäns oder des unteren Miozäns begonnen hatte, sich tektonisch zu individualisieren. In diesem Fall könnte die durch die Gänge repräsentierte vulkanische Episode einige der Charakteristika der dem Becken unterliegenden Kruste erklären und speziell das Vorhandensein eines wichtigen Netzes von magnetischen Anomalien, das Ost-West verläuft. Die spätere Entwicklung des Vulkanismus in dieser Provinz konnte sich aus der Partialschmelzung einer vorher kontaminierten und sogar thermisch anomalen Zone des Mantels ergeben haben, verbunden mit dem Wirken von Verwerfungen und zerrenden Brüchen in einem lithosphärischen Gürtel, der sich vom Südosten der Iberischen Halbinsel bis Marokko ausbreitet.

Resumen Se hace una discusión sobre la significación general de un enjambre de diques (22–23 M.a., datación K/Ar) que aflora en una amplia extensión de la Zona Bética (Cordilleras Béticas, España Meridional). Este enjambre de diques représenta probablemente uno de los primeras episodios magmáticos dentro de la provincia volcánica neógena asociada a la evolución orogénica tardia de la región del Mar de Alborán, y ofrece en todo caso el material igneo mejor preservado en relación con este estadio de los conocidos hasta el presente. Las rocas que constituyen los diques (equivalentes hipoabisales de basaltos andesiticos y andesitas basálticas) poseen caracteres geoquímicos tanto de elementos mayores como de trazas que son afines a los de las series toleáticas de arcos insulares. Su distribución areal y relaciones de campo indican, por otra parte, que una banda dilatacional podría haberse estado desarrollando en el área de Alborán en tiempos oligo-miocenos, con anterioridad a la colisión del Bloque de Alborán con las áreas continentales adyacentes en el Mioceno Inferior-Medio.A causa tanto de su afinidad magmática como de su amplia distribución areal, estas rocas vienen a indicar la existencia, contemporánea, de una zona de Benioff-Wadati activa bajo la región de Alborán y, por ende, la presencia previa de litosfera subducible en sus inmediaciones. El principal vector dilatacional durante la intrusión de los diques era ya normal a la actual elongación de la cuenca de Alborán, lo cual también sugiere la posibilidad de que aquella hubiese comenzado a individualizarse tectónicamente durante el Oligoceno ó Mioceno Inferior. En tal caso el episodio volcico representado por los diques podría explicar algunas de las características de la corteza subyacente a esta cuenca, y en especial la existencia de una prominente red de anomalias magnéticas de dirección E-W, paralela a la red de dikes. El desarrollo posterior del volcanismo en esta provincia podria haber resultado de la fusión partial de una zona del manto previamente contaminada, y aún térmicamente anómala, en conexión con la actuación de desgarres y fracturación distensiva en una banda litosférica que se extiende desde el sureste de la peninsula ibérica hasta Marruecos.

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7.
Sixteen selected samples from the Upper Cretaceous volcanic belt of the Eastern Pontids have been analysed for major elements, Rb, Sr and Zr. On the basis of the K2O versus SiO2 distribution, two groups of rocks have been distinguished, one with calc-alkaline affinity and a second group with shoshonitic character. The calc-alkaline rocks have porphyritic texture with clinopyroxene, plagioclase and orthopyroxene as phenocryst and in the groundmass. The orthopyroxene is lacking in the shoshonites where plagioclase, clinopyroxene and, in the more evolved terms, amphibole and biotite are the main phenocryst minerals. The shoshonitic rocks have higher K2ONa2O ratio, K2O, P2O5 and Rb, contents with respect to the calc-alkaline samples. The TiO2 content is invariably low, never exceeding approximately 1%. The occurrence of volcanic rocks ranging in composition from calc-alkaline to shoshonitic in the Upper Cretaceous volcanic belt of the Eastern Pontids suggests that the Upper Cretaceous volcanic cycle reached its mature stage before the onset of the Eocene calc-alkaline volcanism which is believed to be neither genetically nor tectonically related with the Upper Cretaceous volcanism.  相似文献   
8.
The Moselle river flows in the north-east of France, from Vosges Mountains to neighboring countries Luxembourg and Germany. One of its tributaries, the Fensch river, drains a highly industrialized watershed, strongly impacted by mining, smelting and surfacing activities. The objective of this work, part of a general research program on Moselle watershed (Zone Atelier Moselle) was to assess the impact of the polluted Fensch river on the global quality of the Moselle river. For that purpose, water, sediments and suspended particulate matter were sampled in both rivers, upstream and downstream the junction. Four main sampling campaigns were carried out, in winter during a flood event and in spring at low water level. On a first step, mineralogical analyses (XRD and FTIR) and chemical analyses (ICP-MS, ICP-AES), were performed on sediments, suspended particulate matters and filtered waters. Major and trace elements concentrations were obtained on two different granulometric fractions (0–2 mm and 0–50 μm) revealing the enrichment in heavy metals of fine particles. From one collecting campaign to another, seasonal variations could be evidenced on suspended matter composition even though major minerals (calcite, quartz and kaolinite) were always present. Furthermore, spatial variations were evidenced for Fensch and Moselle downstream sediments. Thus, very fine-grained sediments, poorly crystallized, displaying at the same time higher metal concentrations and higher organic matter content than in Fensch river material, were collected downstream, in a low hydrodynamic conditions zone, assumed as a preferential sedimentary zone or even as a placer. Strong correlations could be revealed between iron content and contaminant concentrations, confirming the origin of polluted material.  相似文献   
9.
Cadmium (Cd) is among the major contaminants in the Seine estuary. In the biota, the RNO (Réseau National d’Observation, the French Mussel-Watch) has shown that Cd concentrations in mussels living at the mouth of the estuary are related to changes in inputs to this area of phosphogypsum, a calcium sulphate that is a by-product of the phosphoric acid naturally enriched with Cd. In the water column, Cd concentrations at several key estuary sites show a very marked trend toward decreased contamination in the particles as well as in the dissolved phase. The behavior of Cd in the estuary has been studied between 1991 and 1998 in the framework of the scientific program Seine-Aval. This program has highlighted punctual Cd inputs in the estuarine water column. The partition of Cd between the dissolved and the particulate phase, previously described in various estuaries, is characterized by an intense phenomenon of solubilization in the mixing zone freshwater-seawater, but the colloidal Cd fraction remains low along the whole salinity gradient, about 5% to 10% of the apparent dissolved fraction. Although the decrease of inputs induced a fall of Cd concentrations in the water column, laboratory experiments show that the estuarine particles are far from being exhausted in Cd. Despite continuous efforts to reduce the urban and industrial inputs into the estuarine and coastal waters, the Seine estuary still remains very contaminated by Cd.  相似文献   
10.
The Nile deep-sea fan (NDSF), turbiditic system reaching a size of about 90,000 km2, has been investigated since 1998 by several geophysical methods (multibeam bathymetry, backscatter imagery, seismic data, 3–5 kHz echo-sounding). The analysis of this important data set evidenced that the NDSF is the locus of numerous multi-scale slope instabilities. Three main types of instabilities have been defined, mainly on the basis of their size or origin. (1) First type of instabilities related to the generalized gravity spreading of the Plio-Quaternary deep-sea fan on Messinian salt layers. This global spreading is accommodated by numerous localized slides. (2) Second type of instabilities correspond to giant mass movements probably triggered either by earthquakes, fluids, or climate and eustatic oscillations. Finally, (3) third type of instabilities correspond either to localized levee liquefactions or to thin-skinned slides on the steep slopes of the Eratosthenes seamount. The deposits generated by these slope movements greatly participate in the building of the NDSF. The characterization of these different instabilities, in a petroleum province as the NDSF, has important implications in terms of risk assessments when considering drilling operations.  相似文献   
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