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In this paper, the influence of anthropogenic activity on surface water chemistry is investigated. Base flow samples from dominant land use streams in the Muskegon River Watershed, Michigan, USA, were analyzed for nutrients, major ions, and trace elements. Principal component and hierarchical cluster analysis were used to investigate the processes controlling the effects of land use on the biogeochemistry of streams in this Watershed. Biogeochemical fingerprints of land use were developed based on the results of the cluster analysis. Spider diagrams which referenced the natural environment aided the identification of the individual contributions of urban and agricultural land uses to surface water chemistry. The biogeochemical fingerprints quantified support previous findings (Urb: Na, K, Cl/Ag: Ca, Mg) and produced new insights into the effects of land use on the behavior of nutrients (Ag: N and Urb: N, P) and trace elements (Urb: V, Cr, Co, Cu, Se, Rb, Mo, Sr, Cd, Pb and Ba/Ag: U and As). The higher correlations of urban than agricultural land uses with nutrients, specifically P, were not expected and may reflect the effects of fertilization and wastewater or the season the samples were taken. More study in different geologic and urban settings is needed to help refine these fingerprints, but it is becoming apparent that despite obscuring factors, land use produces consistent, quantifiable associations between biogeochemical analytes. 相似文献
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Eugene A. Fitzpatrick 《Theoretical and Applied Climatology》1964,13(2):270-286
Summary A harmonic or Fourier analysis of mean monthly rainfall data is found useful in objectively describing and mapping the seasonality of rainfall within Australia. Over large areas the seasonal component is well described by the first and second harmonic terms, leaving as a residual variance only a small proportion of the observed total variance. Care must be taken in the interpretation of second harmonic contributions within those areas of tropical Australia under strong monsoonal influences. This is because pecularities in the form of the annual rainfall regime make the first harmonic term inadequate in itself to fully describe the annual trend. The technique is found particularly useful in defining the boundaries of areas of similar seasonality, and maps based upon the first and second harmonic amplitudes are shown to bear a close relationship with known physical controls.
With 9 Figures 相似文献
Zusammenfassung Zur objektiven Beschreibung der jahreszeitlichen Schwankung der Regenfälle in Australien und ihrer kartenmäßigen Darstellung wird mit Erfolg die harmonische Analyse der mittleren Monatsmengen des Niederschlags angewendet. Über weiten Gebieten wird die jahreszeitliche Schwankung durch die ersten beiden harmonischen Schwingungen gut dargestellt; die Reststreuung macht nur einen kleinen Bruchteil der beobachteten Gesamtstreuung aus. Vorsicht erscheint jedoch geboten bei der Interpretation des Anteils der zweiten Harmonischen in den Gebieten des tropischen Australien, die unter starkem Monsuneinfluß stehen. Hier machen Besonderheiten im Niederschlagsregime selbst die erste Harmonische ungenügend zur Beschreibung des Jahresganges. Die angewandte Methode ist besonders geeignet, die Grenzen zwischen Gebieten mit gleichartigem Jahreszeiteneinfluß festzulegen. Karten, die auf der ersten und zweiten harmonischen Schwingung beruhen, zeigen einen engen Zusammenhang mit bekannten physikalischen Faktoren.
Résumé Afin de décrire objectivement les variations saisonnières des précipitations en Australie, on se sert avantageusement de l'analyse harmonique des sommes mensuelles moyennes. Cette méthode est également utilisée pour la représentation cartographique des dites variations. Les amplitudes saisonnières sont bien rendues par les deux premières harmoniques et cela pour de grandes étendues. L'amplitude qui reste ne représente qu'une faible fraction de l'amplitude totale observée. Il faut cependant procéder avec prudence lors de l'interprétation de la part revenant à la seconde harmonique dans les contrées tropicales de l'Australie, contrées qui subissent fortement l'influence de la mousson. Dans ce cas précis, les particularités du régime des précipitations ne permettent même pas d'utiliser la première harmonique pour décrire l'évolution des pluies au cours de l'année. La méthode proposée est surtout intéressante pour délimiter les régions soumises aux mêmes régimes. Des cartes basées sur la première et la seconde harmonique montrent un rapport étroit entre les précipitations et certains facteurs physiques connus.
With 9 Figures 相似文献
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W. H. Jefferys M. J. Fitzpatrick B. E. McArthur 《Celestial Mechanics and Dynamical Astronomy》1987,41(1-4):39-49
GaussFit is a new computer program for solving least squares and robust estimation problems. It has a number of unique features, including a complete programming language designed especially to formulate estimation problems, a built-in compiler and interpreter to support the programming language, and a built-in algebraic manipulator for calculating the required partial derivatives analytically. These features make GaussFit very easy to use, so that even complex problems can be set up and solved with minimal effort. GaussFit can correctly handle many cases of practical interest: nonlinear models, exact constraints, correlated observations, and models where the equations of condition contain more than one observed quantity. An experimental robust estimation capability is built into GaussFit so that data sets contaminated by outliers can be handled simply and efficiently.Invited Talk at the 18th meeting of the Division on Dynamical Astronomy of the American Astronomical Society held in Braintree, Massachussetts, May 7–9, 1987. 相似文献
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J. Elizabeth Jackson Michael G. Yost Catherine Karr Cole Fitzpatrick Brian K. Lamb Serena H. Chung Jack Chen Jeremy Avise Roger A. Rosenblatt Richard A. Fenske 《Climatic change》2010,102(1-2):159-186
Illness and mortality related to heat and worsening air quality are core public health concerns associated with climate change projections. We examined the historical relationship between age- and cause-specific mortality rates from 1980 through 2006 and heat events at the 99th percentile of humidex values in the historic period from January 1, 1970 to December 31, 2006 in the greater Seattle area (King, Pierce and Snohomish counties), Spokane County, the Tri-Cities (Benton and Franklin counties) and Yakima County; the relative risks of mortality during heat events were applied to population and climate projections for Washington State to calculate number of deaths above the baseline (1980–2006) expected during projected heat events in 2025, 2045 and 2085. Three different warming scenarios were used in the analysis. Relative risks for the greater Seattle area showed a significant dose-response relationship between heat event duration and daily mortality rates for non-traumatic deaths for persons ages 45 and above, typically peaking at four days of exposure to humidex values above the 99th percentile. The largest number of projected excess deaths in all years and scenarios for the Seattle region was found for age 65 and above. Under the middle warming scenario, this age group is expected to have 96, 148 and 266 excess deaths from all non-traumatic causes in 2025, 2045 and 2085, respectively. We also examined projected excess deaths due to ground-level ozone concentrations at mid century (2045–2054) in King and Spokane counties. Current (1997–2006) ozone measurements and mid-twenty-first century ozone projections were coupled with dose-response data from the scientific literature to produce estimates overall and cardiopulmonary mortality. Daily maximum 8-h ozone concentrations are forecasted to be 16–28% higher in the mid twenty-first century compared to the recent decade of 1997–2006. By mid-century in King County the non-traumatic mortality rate related to ozone was projected to increase from baseline (0.026 per 100,000; 95% confidence interval 0.013–0.038) to 0.033 (95% CI 0.017–0.049). For the same health outcome in Spokane County, the baseline period rate of 0.058 (95% CI 0.030–0.085) was estimated increase to 0.068 (95% CI 0.035–0.100) by mid-century. The cardiopulmonary death rate per 100,000 due to ozone was estimated to increase from 0.011 (95% CI 0.005–0.017) to 0.015 (0.007–0.022) in King County, and from 0.027 (95% CI 0.013–0.042) to 0.032 (95% CI 0.015–0.049) in Spokane County. Public health interventions aimed at protecting Washington’s population from excessive heat and increased ozone concentrations will become increasingly important for preventing deaths, especially among older adults. Furthermore, heat and air quality related illnesses that do not result in death, but are serious nevertheless, may be reduced by the same measures. 相似文献
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M. A. Wells R. W. Fitzpatrick R. J. Gilkes & J. Dobson 《Geophysical Journal International》1999,138(2):571-580
Mineral and isothermal magnetic properties of Al-, Mn- and Ni-substituted haematites were characterized and their relationships evaluated in order to interpret better the results of magnetic analyses of soils and recent sediments. Aluminium, manganese and nickel haematites generally behaved as single-domain (SD) particles. The influence of incorporated Al on the magnetic behaviour of haematite was consistent with Al acting as a paramagnetic dilutent. Mass magnetic susceptibility ( χ ) and SIRM800 decreased as the level of Al substitution increased. Incorporation of Mn and Ni increased χ , which could be associated with enhancement of the spin canting effect of haematite. The stability of SIRM800 to demagnetization for Al-haematite appears to be related to a defect mechanism associated with the development of smaller crystallites arising from Al substitution. Magnetic domain rotation or flipping was probably inhibited, being blocked by structural defects during magnetization and demagnetization, and resulted in a low but stable partial SIRM (SIRM800 ). %IRM/SIRM800 demagnetization curves and estimated ( B o )CR values of ≤100 mT for Mn-haematite indicate pseudo-single-domain/multidomain-like behaviour despite Mn-haematite having particle and crystallite dimensions similar to Ni-haematite, which did not show this behaviour. Data indicate that parameters involving unsaturated, partial SIRM should be used with caution in magnetic studies of soils and sediments. 相似文献
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Contributions of groundwater conditions to soil and water salinization 总被引：23，自引：2，他引：21
Salinization is the process whereby the concentration of dissolved salts in water and soil is increased due to natural or
human-induced processes. Water is lost through one or any combination of four main mechanisms: evaporation, evapotranspiration,
hydrolysis, and leakage between aquifers. Salinity increases from catchment divides to the valley floors and in the direction
of groundwater flow. Salinization is explained by two main chemical models developed by the authors: weathering and deposition.
These models are in agreement with the weathering and depositional geological processes that have formed soils and overburden
in the catchments. Five soil-change processes in arid and semi-arid climates are associated with waterlogging and water. In
all represented cases, groundwater is the main geological agent for transmitting, accumulating, and discharging salt. At a
small catchment scale in South and Western Australia, water is lost through evapotranspiration and hydrolysis. Saline groundwater
flows along the beds of the streams and is accumulated in paleochannels, which act as a salt repository, and finally discharges
in lakes, where most of the saline groundwater is concentrated. In the hummocky terrains of the Northern Great Plains Region,
Canada and USA, the localized recharge and discharge scenarios cause salinization to occur mainly in depressions, in conjunction
with the formation of saline soils and seepages. On a regional scale within closed basins, this process can create playas
or saline lakes. In the continental aquifers of the rift basins of Sudan, salinity increases along the groundwater flow path
and forms a saline zone at the distal end. The saline zone in each rift forms a closed ridge, which coincides with the closed
trough of the groundwater-level map. The saline body or bodies were formed by evaporation coupled with alkaline-earth carbonate
precipitation and dissolution of capillary salts.
Received, May 1998 · Revised, July 1998 · Accepted, September 1998 相似文献
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