Acute toxicity of bromochlorinated seawater to selected estuarine species with a comparison to chlorinated seawater toxicity     

Morris H. Roberts  Jr.  Richard A. Gleeson 《Marine environmental research》1978,1(1):19-30

The acute toxicity of bromochlorinated estuarine water (ca. 20%) was determined for several estuarine organisms. The most sensitive species were oysters (Crassostrea virginica, larvae and juveniles) and copepods (Acartia tonsa) with 48-h LC₅₀'s of 0·10 to 0·21 mg BrCl/litre. Palaemonetes pugio was most tolerant with a 96-h LC₅₀ of 0·70 mg BrCl/litre. The fish species tested (Menidia menidia, Brevoortia tyrannus and Leiostomus xanthurus) all had a 96-h LC₅₀ of 0·21–0·23 mg BrCl/litre.The BrCl toxicity data are compared with Cl₂ toxicity data for the same species. When the LC₅₀'s are expressed as equivalents per litre, BrCl is found to be two to four times less toxic than Cl₂. The ranking of species in terms of sensitivity is the same for both disinfectants.Some data are provided concerning the decay rates of BrCl and Cl₂ in estuarine water. BrCl was found to decay more rapidly than Cl₂ at higher ammonia levels (0·25 mg NH₄-N/litre). The question of chemical speciation is discussed with particular reference to the differential toxicities.  相似文献   

Green's theorem and Green's functions for the steady-state cosmic-ray equation of transport     

G. M. Webb  L. J. Gleeson 《Astrophysics and Space Science》1977,50(1):205-223

Green's Theorem is developed for the spherically-symmetric steady-state cosmic-ray equation of transport in interplanetary space. By means of it the momentum distribution functionF _o(r,p), (r=heliocentric distance,p=momentum) can be determined in a regionr _arr_bwhen a source is specified throughout the region and the momentum spectrum is specified on the boundaries atr _a andr _b . Evaluation requires a knowledge of the Green's function which corresponds to the solution for monoenergetic particles released at heliocentric radiusr _o , Examples of Green's functions are given for the caser _a =0,r _b = and derived for the cases of finiter _a andr _b . The diffusion coefficient is assumed of the form = _o(p)r ^b . The treatment systematizes the development of all analytic solutions for steady-state solar and galactic cosmic-ray propagation and previous solutions form a subset of the present solutions.  相似文献   

Robin Marian Law     

Brendan Gleeson 《New Zealand geographer》2003,59(1):5-6

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Geochemical zoning around the McClean uranium deposits, Saskatchewan, Canada     

J.P. Golightly  C.F. Gleeson  J.J. Brummer  Saracoglu 《Journal of Geochemical Exploration》1983,19(1-3)

Some 3400 drill core samples of the Athabasca Group and underlying regolith have been obtained by sampling 8-m sections from 55 diamond drill holes in the McClean Lake Area, Saskatchewan. Forty eight holes are from sections over six areas known to contain uranium mineralization and 7 are from unmineralized areas. The uranium zones are covered by 30 to 180 m of Athabasca sandstones and conglomerates.The uranium mineralization of the McClean deposits can be described as belonging to two different facies; a more reduced sulphide-arsenide facies and a more oxidized hematite-“bleached” facies, superimposed on any one of three host rocks.The sulphide-arsenide facies is probably older and, except in one deposit, it forms a patchy distribution of relicts. The principal pattern is an upwards increase in sulphur/arsenic ratio. The hematite-“bleached” facies appears to be younger and may represent a reworking of the earlier sulphide-arsenide facies mineralization under more oxidizing conditions.The trace metals can be grouped according to their redox behaviour. Vanadium, Mo and U, occurring as oxides, form one group while Ni, Co, Zn, Cu and As, occurring as sulphides and/or arsenides, form intermediate and most reduced groups, respectively. Iron is concentrated in the most oxidized facies as hematite or goethite and in the most reduced facies as pyritebravoite, siderite and chlorite. Manganese follows the distribution of siderite.The ratio of oxidized to reduced minerals can be represented by the ratio of U/Ni. This ratio can be used to estimate the variation of redox potential in the deposit at the time of deposition or alteration. The principal pattern is one of systematic increase in U/Ni ratio or oxidation potential both upward and to the northeast in each of the hematite and bleached facies.A generalized Eh-pH diagram is used to qualitatively describe the significance of each mineral facies.The U/Ni ratio of the transition between the hematite and “bleached” facies increases upwards. The phase diagram suggests that a possible cause is an upward decrease in pH and increase in Eh.The overall distribution is compatible with the origin of the deposits due to reduction at the interface between a plume of reductant emanating from fractures in the sub-Athabasca basement and an oxidizing aquifer moving southwestward in the sandstone. This model does not accurately predict the distribution of elements among the seven McClean Lake pods. However, it explains the overall pattern. Local variations in metal ratios in solution either in time or reflecting local provenance could be adduced to explain local deviations from the overall pattern.Clay alteration, apparently largely contemporaneous with the earliest mineralization, is largely illitic but with sporadic occurrences of xenotime and goyazite. Thus K and to some extent P, Y and light REE's are also enriched to some degree in the deposits.Uranium analysis of the drill core shows that there is little movement of U into the overlying sandstones from basement rocks and regolith that contain no uranium deposits. Uranium in the Athabasca sandstone from these areas averages less than 1 ppm. However, where uranium zones have been found in the basement rocks, regolith and lower Athabasca sandstone, U values greater than 2–3 ppm consistently occur in the overlying sandstones at or near surface.There appear to be two types of U anomalies, those that flank the deposits and those that directly overlie them. Both types exhibit vertical and lateral continuity. They are associated with vertical to steeply dipping fracture systems that traverse the Athabasca sandstone from basement to surface. The fractures are thought to be related to diagenetic processes from compaction of the sedimentary rocks over basement irregularities as well as tectonic processes (i.e. re-adjustment along old basement structures).These results suggest that target areas containing deeply buried uranium deposits could be defined by U analyses of the Athabasca sandstone from quite widely spaced holes of limited depth. This conclusion can be compared to XRD and chemical studies of clay mineral distribution within the Athabasca sandstone about the deposits.  相似文献   

Editors’ Message: The 2013 Editors’ Choice articles,a new editor,and the 2013 ‘Coolest Paper’ award     

Clifford Voss  Matthew Currell  Tom Gleeson 《Hydrogeology Journal》2014,22(2):293-294

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The geology of the carbonate-hosted Blende Ag–Pb–Zn deposit,Wernecke Mountains,Yukon, Canada     

Micheal Moroskat  Sarah A. Gleeson  R. J. Sharp  A. Simonetti  C. J. Gallagher 《Mineralium Deposita》2015,50(1):83-104

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1973 supplement to exploration geochemistry bibliography     

H.E. Hawkes  F.C. Canney  P.R. Donovan  G.H. Friedrich  C.F. Gleeson  M.B. Mehrtens  P. Lowenstein 《Journal of Geochemical Exploration》1974,3(1):89-128

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The compton-getting effect     

L. J. Gleeson  W. I. Axford 《Astrophysics and Space Science》1968,2(4):431-437

The differential current density and anisotropy seen by an observer moving relative to the frame of reference in which a flux of cosmic ray particles or photons is isotropic, is derived assuming that the observer's speed is small. The results are applied to examples relevant to the theory of cosmic ray modulation and the expected anisotropies of photons originating outside our galaxy.This research was supported by the Advanced Research Projects Agency (Project DEFENDER) and was monitored by the U.S. Army Research Office-Durham under Contract DA-31-124-ARO-D-257, and by NASA under contract #NGR-05-009-081.  相似文献   

Tracing groundwater discharge in a High Arctic lake using radon-222   总被引：1，自引：1，他引：0  

Hilary A. Dugan  Tom Gleeson  Scott F. Lamoureux  Kent Novakowski 《Environmental Earth Sciences》2012,66(5):1385-1392

In the High Arctic, groundwater fluxes are limited by the presence of continuous permafrost, although it has been hypothesized that there may be localized groundwater flow and hydraulic connectivity beneath large lakes, due to the presence of taliks, or large regions of unfrozen ground. However, due to the logistical difficulty of employing seepage meters and piezometers in deep, ice-covered lakes, relatively little is known about groundwater discharge to polar lakes. One method of assessing groundwater discharge is through the use of geochemical tracers. We conducted a pilot study to quantify groundwater discharge into a High Arctic lake using dissolved radon gas as a geochemical tracer. Lake water was collected in 15 L polyvinyl chloride (PVC) bags with minimal atmospheric interaction from a 25-m deep lake near Shellabear Point, Melville Island, Northwest Territories, Canada. Sample bags were aerated through a closed water loop for 60 min to allow sufficient radon to equilibrate in a coupled air circuit. Radon in air concentrations were measured on a Durridge RAD7 portable alpha spectrometer. The field trial in a remote setting and separate tests with groundwater samples collected from a temperate site demonstrate the utility of the methodology. The limited results suggest that radon levels in the lower water column are elevated above background levels following nival melt in the surrounding watershed. Although these results are insufficient to quantify groundwater discharge, the results suggest subsurface flow may exist, and further study is warranted.  相似文献   

Cosmic-ray flow lines and energy changes     

G. M. Webb  L. J. Gleeson 《Astrophysics and Space Science》1980,70(1):3-31

In this paper we discuss the particle flow or streaming and energy changes of cosmic rays in the interplanetary region via flow lines in momentum-position space. We consider the steady-state case where particles are released monoenergetically from the Sun or from infinity and study the cosmic-ray traffic pattern in momentum and position arising from monoenergetic sources. The analysis makes extensive use of the result (wherep is the particle momentum,V the solar wind velocity andG the cosmic-ray density gradient) for the mean time rate of change of momentum of cosmic rays reckoned for a fixed volume in a reference frame fixed in the solar system, developed by us in several recent papers.Deceased.  相似文献