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The electrochemical transfer characteristics of nickel sulphides from six West Australian localities are examined by the nonlinear complex resistivity (nlcr ) method. Ores are classified on the basis of their state of oxidation (supergene, transition zone and primary ores) in an equivalent mine water electrolyte; evidence is found for a systematic change of electrical response with oxidation that is symptomatic of electrochemical reactions varying from diffusion to charge-transfer controlled processes. The analysis is based on the assumption that the Randies’ circuit is an effective model of a rock's electrical response in its natural electrolyte. Both complex impedance plane graphs and computer inversion are used to study the model. Harmonic distortion is a useful aid in this interpretation. 相似文献
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Abstract Quartz-hosted, synthetic CO2 -H2 O fluid inclusions behave as open systems with respect to diffusional transfer of hydrogen during laboratory-simulated metamorphic re-equilibration at 650, 750 and 825°C and 1.5 kbar total pressure with fO2 defined by the C-CH4 buffer. Microthermometry and Raman spectroscopy show that the initial CO2 -H2 O inclusions become CO2 -CH4 -H2 -H2O
inclusions after diffusive influx of hydrogen from the reducing confining medium. Measurable changes are observed in inclusion compositions after only 15 days of re-equilibration, implying significant hydrogen mobility at still lower temperatures over geological time spans. Results of synthetic inclusion re-equilibrium experiments have profound implications for the interpretation of natural fluid-inclusion data; failure to account for potential hydrogen migration in inclusions from high-temperature geological environments may lead to erroneous estimates of P-T, and/or the compositions of metamorphic fluids. 相似文献
inclusions after diffusive influx of hydrogen from the reducing confining medium. Measurable changes are observed in inclusion compositions after only 15 days of re-equilibration, implying significant hydrogen mobility at still lower temperatures over geological time spans. Results of synthetic inclusion re-equilibrium experiments have profound implications for the interpretation of natural fluid-inclusion data; failure to account for potential hydrogen migration in inclusions from high-temperature geological environments may lead to erroneous estimates of P-T, and/or the compositions of metamorphic fluids. 相似文献
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Geochemical Constraints on the Origin of Volcanic Rocks from the Andean Northern Volcanic Zone, Ecuador 总被引：2，自引：0，他引：2
BRYANT J. A.; YOGODZINSKI G. M.; HALL M. L.; LEWICKI J. L.; BAILEY D. G. 《Journal of Petrology》2006,47(6):1147-1175
Whole-rock geochemical data on basaltic to rhyolitic samplesfrom 12 volcanic centers are used to constrain the role of continentalcrust in the genesis of magmas formed beneath the anomalouslywide subduction-related volcanic arc in Ecuador. Relativelyhomogeneous, mantle-like, isotopic compositions across the arcimply that the parental magmas in Ecuador were produced largelywithin the mantle wedge above the subduction zone and not byextensive melting of crustal rocks similar to those upon whichthe volcanoes were built. Cross-arc changes in 143Nd/144Nd and7/4Pb are interpreted to result from assimilation of geochemicallymature continental crust, especially in the main arc area, 330–360km from the trench. Mixing calculations limit the quantity ofassimilated crust to less than 10%. Most andesites and dacitesin Ecuador have adakite-like trace element characteristics (e.g.Y <18 ppm, Yb <2 ppm, La/Yb >20, Sr/Y >40). Availablewhole-rock data do not provide a clear basis for distinguishingbetween slab-melting and deep crustal fractionation models forthe genesis of Ecuador adakites; published data highlightinggeochemical evolution within individual volcanoes, and in magmaticrocks produced throughout Ecuador since the Eocene, appear tosupport the deep fractionation model for the genesis of mostevolved Ecuadoran lavas. A subset of andesites, which displaya combination of high Sr (>900 ppm), Nd >4·1 and7/4Pb <6·0, appear to be the best candidates amongEcuador lavas for slab-melts associated with the subductionof the relatively young, over-thickened, oceanic crust of theCarnegie Ridge. KEY WORDS: andesite; Ecuador; trace elements; isotopes; adakite 相似文献
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Brad R. HALL 《国际泥沙研究》1999,(2)
ILOWERGUADALUPERIVER,SANJOSECALIFORNIATheLowerGuadalupeRiverProjectAreadoesnothavetheabilitytoconveytheflowofthe100-yearfloodevent.LocatedbetweentheSanrranciscoBayandDowntownSanJose,theLowerGuadalupeRiverProjectareaissubjecttomanynaturalandman-inducedagentsandnaturalphysicalprocessesthataffectthehydraulicandsedimenttransportcharacteristicsoftheRiver.Themostsignificantagentsandprocessesincludethelocalgeology,regionalseismicity,tidalprocesses,pastsubsidenceintheregion,risings… 相似文献
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FANGJU WANG G. BRENT HALL SUBARYONO 《International journal of geographical information science》2013,27(3):261-283
Currently used methods for representing geographical information are inadequate because they do not tolerate imprecision. This leads to information loss and inaccuracy in analysis. Such expressive inadequacy is largely due to the underlying membership concept of classical set theory. To improve information processing in GIS research and application, an alternative membership concept is required. In this paper, we explore the inadequacy imposed upon geographical information representation by classical set theory and address the problems of information loss. A fuzzy relational data model is defined which is more representative for geographical information. A GIS database for agricultural land resource management is created by using the data model and a new technique for assessing land suitability is developed. The fuzzy representation largely facilitates data analysis in this GIS. The methods are tested with data from North Java, Indonesia using a vector-based GIS software package, Arc Info, and the analysis results are presented. 相似文献
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Results are presented of the determination of Zr, Nb, Hf and Ta in 74 standard reference materials by inductively coupled plasma mass spectrometry (ICP-MS). Samples are decomposed by fusion with lithium metaborate and the analytes are separated prior to analysis by precipitation of their cupferrates. Calibration is made using synthetic solutions and internal standardization with Ru (for Zr and Nb) and Re (for Hf and Ta). Accuracy is assessed by comparison with recommended values and precision is evaluated by replicate analyses of five SRMs. 相似文献
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The outputs and neutral of a three phase generator are converted to six amplitude variable phases in a 3.5 kW 400 Hz transmitter. These outputs are applied to six groundimplanted electrodes, producing a horizontally rotating current dipole in the subsurface. An investigation of the radiation pattern in the vertical magnetic field indicates, in symmetry and closure control, considerable advantages in this form of galvanic energization. These include optimization of inductive anomalies and the ability to interpret phase observations on a spatial basis in depth sounding and orebody location. 相似文献