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Toshihiko Ohnuki Takuo Ozaki Fuminori Sakamoto Eiichi Wakai Haruyuki Iefuji 《Geochimica et cosmochimica acta》2005,69(22):5307-5316
We determined the association of uranium in yeast cells S. cerevisiae grown in medium containing high (1 g · L-1) or low (0.2 g · L-1) concentrations of phosphate after exposure for 96 h to a 4 × 10-4 mol · L-1 U(VI) solution at pH 3.2 or 4.7. The analysis was made using a field emission scanning electron microscope equipped with energy dispersive spectroscopy (FESEM-EDS), transmission electron microscopy (TEM), and visible diffuse reflectance spectrometry. Cells grown in the high-phosphate medium rapidly accumulated U(VI) from solution at pH 3.2 over the first 24 h, followed by a slow uptake until 96 h, whereas in cells grown in low-phosphate medium, U(VI) accumulation reached a steady state within 24 h. FESEM-EDS analyses revealed the formation of a U(VI)-bearing precipitate on the yeast cells grown in high-phosphate medium after only 48 h exposure; no precipitate was detected on cells grown in low-phosphate medium up to 96 h. These results suggest that sorption onto the cell surfaces was the dominant process initially. Analysis of the U(VI)-bearing precipitates by all three methods demonstrated the presence of H-autunite, HUO2PO4 · 4H2O. Thermodynamic calculations suggest that the chemical compositions of the solutions containing yeast grown in high-phosphate medium were undersaturated with respect to H-autunite, but were supersaturated with ten times more U(VI) and P than were actually observed. Apparently, the sorbed U(VI) on the cell surfaces reacts with P released from the yeast to form H-autunite by local saturation. The U(VI) uptake by yeast cells grown in high phosphate medium at pH 4.7, along with the thermodynamic calculation, indicated that more H-autunite is precipitated in neutral pH solution than in acid solution. Thus, U(VI)-phosphate mineralization on the cells of microorganisms should be taken into account for predicting U(VI) mobility in the environment. 相似文献
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Concentration of polychlorinated biphenyls (PCBs) in beached resin pellets: variability among individual particles and regional differences 总被引：1，自引：0，他引：1
Endo S Takizawa R Okuda K Takada H Chiba K Kanehiro H Ogi H Yamashita R Date T 《Marine pollution bulletin》2005,50(10):1103-1114
Concentrations of polychlorinated biphenyls (PCBs) in beached resin pellets were examined to reveal variability between individual particles and differences among beaches. Fifty-five resin pellets from a beach in Tokyo were individually analyzed for PCBs, and showed concentrations ranging from <28 to 2,300 ng/g. This indicates that concentrations are highly variable between particles. Among several characters, discoloration (e.g., yellowing) had a positive relationship with PCB concentration: discolored pellets contained more PCBs than others on most of the beaches sampled. Given the color-selective ingestion of food by some organisms, this may be ecotoxicologically important. Measurements of samples from 47 beaches in Japan showed regional differences in PCB concentrations in resin pellets consistent with those in mussels. Sporadic high concentrations of PCBs were also found in pellets from remote islands, suggesting that resin pellets could be the dominant route of exposure to the contaminants at remote sites. The similarity of PCB concentrations between resin pellets and mussels suggests a potential use of resin pellets to monitor pollution in seawater. 相似文献
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This paper presents a finite element model for analysing the behaviour of granular material wrapped with polyethylene bags under vertical compression and cyclic shearing. The simple Mohr–Coulomb model is used to represent the soil behaviour. The polyethylene bag is represented by a linear-elastic–perfect-plastic model. The soil-bag interface is modelled with contact constraints. The main purpose of the numerical analysis is to validate the anticipated performance of soilbags under various loading conditions and hence the effectiveness of soilbags as a method of ground improvement. 相似文献
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The examination of fracturing process subjected to triaxial compression test in Inada granite 总被引：1，自引：0，他引：1
Takashi Nishiyama Youqing Chen Hiromu Kusuda Toshihide Ito Katsuhiko Kaneko Haruyuki Kita Toshinori Sato 《Engineering Geology》2002,66(3-4):257-269
The behavior of a granite subject to a triaxial compression test ranging from the prefailure stage to the postfailure stage was studied using a fluorescent technique from the geological point of view. Microscopic observations of the specimens at different stages showed changes in the failure process. The start of formation of new microcracks paralleled the compression direction through their propagation until the onset of faulting and ended with the failure of shear zones after the strength failure point. Pores chiefly identified in the feldspar increased in length and width in the early stages, but not in number. It seems that the effect of pore spaces did not have any effect of failure. The microcracks generated on angular edges of quartz or feldspar grains and around biotite grains with increasing compression force. The phenomenon appearing on the crystal boundaries among biotite and quartz or feldspar agrees with the result calculated based on the theory on stress fields with ellipsoidal inhomogeneity suggested by Eshelby. 相似文献
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