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Horizontal and vertical distribution of PCBs and chlorinated pesticides in sediments from Masan Bay,Korea 总被引：1，自引：0，他引：1
Horizontal and vertical distributions of organochlorine compounds (OCs) were determined in sediments from Masan Bay. The concentrations of polychlorinated biphenyls (PCBs), dichlorodiphenyltrichloroethanes (DDTs), HCB, hexachlorocyclohexanes (HCHs) and chlordane related compounds (CHLs) in sediments were in the range of 1.24-41.4, 0.28-89.2, 0.02-0.59, nd-1.03, and nd-2.56 ng/g, respectively. The spatial distribution of OCs showed a negative gradient from the inner of the bay to outer part of the bay, indicating that the source of OCs was probably located inside the bay. Compositional pattern of PCB congeners showed a relatively high concentration of high-chlorinated congeners in the inner part of the bay and a relatively low concentration of low-chlorinated congeners in the outer part. In sediment core from Masan Bay maximum concentrations of PCBs and DDTs are observed in the subsurface samples and correspond to an age of early 1980s and late 1960s. The concentration profiles of PCBs and DDTs in sediments of Masan Bay appear to correspond to use of PCBs and DDTs in Korea. 相似文献
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Up to now,there were no systematic studies of geochemistry and isotopic age for the Yixian(义县) fluorite deposit,western Liaoning(辽宁) Province,China.Based on the analysis of metallogenic geological setting,we studied the REE,Rb-Sr and Sm-Nd isotopes.The chondrite-normalized REE patterns of fluorite are characterized by moderate LREE depletion(LREE/HREE=0.95-3.57,(La/Yb)N=0.08-2.84) and enrichment of Sr(146×10-6-596×10-6) and moderately positive Eu anomalies(δEu=1.10-1.34),which are similar to those of the ho... 相似文献
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An earthquake with a magnitude of 5.7 $(\text{ M}_{\mathrm{L}})$ has struck Simav, Kutahya located in the western part of Turkey on May 19, 2011. The ground motion caused observable damage within 25 km radius from the epicenter. Although the earthquake is moderate, its effects on the structures are serious. This paper presents the observations on seismic damages of reinforced concrete (RC) and masonry structures. Common reasons of damage in RC buildings are: low quality of concrete, detailing mistakes of reinforcement, short column, pounding, overhangs and misconstructed gable and outer infill wall parts. Interesting cases related to these deficiencies are reported. Damages in the masonry buildings are due to lack of connection between orthogonal walls and unsuitable location and dimension of openings. The damages at structures are more noticeable at regions with unfavorable soil conditions like plain regions or foothills. However, on stiffer soils at hilly sides, the damages seem to be more limited and masonry structures are observed to be less affected compared to the RC ones. The damages in RC buildings found to be increasing with story number for light damage states. However, for heavier damage states, 4–5 story buildings are observed to be the most damaged. 相似文献
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Muhammad Raza Mohamad Pauzi Zakaria Nor Rasidah Hashim Un Hyuk Yim Narayanan Kannan Sung Yong Ha 《Environmental Earth Sciences》2013,70(6):2425-2436
This is a comprehensive study of the composition, origin and sources of specific polycyclic aromatic hydrocarbons (PAHs) in sediments of mangrove estuary in the western part of Peninsular Malaysia. Mangrove sediments were analyzed for 17 PAHs by gas chromatography–mass spectrometry. Total PAH concentrations in the sediments ranged from 20 to 112 ng/g on a dry-weight basis. High molecular weight PAHs were abundant in the sediments. Parent PAH ratios revealed that pyrogenic input has important contribution to the sedimentary PAHs. Ratios of alkylated PAHs indicate that the sedimentary PAHs were influenced by petrogenic PAHs, which implies that petrogenic input has contribution to the sedimentary PAHs but that it is not a major factor in distribution of PAHs within the estuary. Combustion-derived PAHs show a positive and very strong correlation with total PAHs (R 2 = 0.926, p < 0.05). Total methylphenanthrenes show very weak correlation with total PAHs (R 2 = 0.0928, p < 0.05). The PAH concentrations were found to increase with distance from the upstream of the estuary to the coastal area of the Straits of Malacca. For the assessment of sediment contamination using biological thresholds, none of the individual studied PAH compounds exceeded the values of the effect range low–effect range median guideline and the threshold effects level–probable effects level guideline. This study demonstrates that the sediments of the mangrove ecosystem facing the Straits of Malacca and Sumatra are influenced by anthropogenic PAH inputs as a result of human activities such as biomass burning, vehicle emissions and boating activities. 相似文献
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Kongtae Ra Joung-Keun Kim Sang Hee Hong Un Hyuk Yim Won Joon Shim Seung-Yong Lee Young-Ok Kim Jaesoo Lim Eun-Soo Kim Kyung-Tae Kim 《Ocean Science Journal》2014,49(3):279-289
Heavy metal concentrations in the surface sediments of specially managed Ulsan Bay were investigated to determine metal distribution, pollution status and its ecological risk using pollution indices (enrichment factor and geo-accumulation index), potential ecological risk index and sediment quality guidelines (SQGs). The order of mean concentration (mg/kg) of metals was Zn (361.9) > Cu (95.6) > Pb (90.7) > Cr (64.7) > Ni (32.2) > Co (16.6) > As (15.8) > Cd (0.40) > Hg (0.16) in sediments of Ulsan Bay. Spatial distribution of metals in sediments showed a significantly higher concentration near industrial complexes, indicating that metal pollution is caused by anthropogenic sources. The results of enrichment factor (EF) and geo-accumulation index (Igeo) showed that sediments were significantly accumulated with Cu, Zn, As, Cd, Pb and Hg, indicating moderate to very severe enrichment (pollution) by these metals. Based on the potential ecological risk index, Hg and Cd posed a very high and a considerable potential ecological risk. Cu and As posed a moderate potential ecological risk, while, other metals (Cr, Co, Ni, Zn and Pb) rarely posed any potential ecological risk to the coastal environments. The sediments in Ulsan Bay showed a very high level of ecological risk, dominated by Hg and Cd. Metal concentrations in sediments were 80% for Cu, 96.7% for Zn, 50% for As, 70% for Pb and 50% for Hg above the threshold effects level (TEL), respectively. 相似文献
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Biomarker responses in pelagic and benthic fish over 1 year following the Hebei Spirit oil spill (Taean, Korea) 总被引：1，自引：0，他引：1
Jung JH Kim M Yim UH Ha SY An JG Won JH Han GM Kim NS Addison RF Shim WJ 《Marine pollution bulletin》2011,62(8):1859-1866
After the Hebei Spirit oil spill incident (7th December, 2007) in the west coast of Korea, contamination of biliary PAH metabolite and hepatic biomarkers in a pelagic and a benthic fish was monitored for 1 year. Concentrations of 16 PAHs and alkylated PAHs in fish muscle were highest (22.0 ng/g d.w. for 16 PAHs and 284 ng/g d.w. for alkylated PAHs) at 5 days after the spill and then decreased rapidly to background levels at 11 months after the spill. Fish from the oiled site had elevated biliary PAH metabolite concentrations immediately after the spill; these declined steadily in both species, but were still above reference site concentrations 2 months after the spill. Oiled-site fish showed hepatic CYP 1A induction whose trend closely followed those of biliary PAH metabolite concentrations, implying continuous exposure to PAHs. Brain acetylcholinesterase activity was not related to oil exposure. 相似文献
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Benthic ecosystem in Gwangyang Bay, a fast developing industrial area with steel production, port container handling, petroleum and other chemical processing in South Korea was studied. The average levels of polychlorinated biphenyls (ΣPCB) in the benthic components were: seawater 2.99 ± 0.13 (ng/L); sediment 294 ± 118 (ng/g TOC); [biota=ng/g lipid] starfish 92; prawn 131 ± 2; mussels 127 ± 22; crab 182 ± 114; clam 187; polychaeta 215; sea cucumber 497 ± 90; squill 603 ± 38; fish 396 ± 159. Levels in the inner bay samples were higher than the outer bay samples suggesting land based pollution. Good correlation (r(2)=0.79; p<0.05) existed between PCB concentration and lipid content indicating partitioning processes in action. PCB signature in the abiotic and biotic components shows enrichment of lower chlorinated congeners emitted by a unique source nearby, viz. steel manufacturing plant. 相似文献