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1.
The appearance of multiplets arising from the 42P state of CaII (the H and K lines and an infrared triplet), the 1st positive band of N2 and possibly certain multiplets of FeII in meteor wake spectra is explained semi-quantitatively in terms of the two-step sequence: collisional ionization of major atmospheric species O2 and N2 followed by resonant charge exchange with ablated meteoric atoms. Many other features which could arise through this mechanism (multiplets of MgII, SiII and FeII, and bands of O2 and N2) are likely to be weak or to have escaped detection owing to observational selection.  相似文献   
2.
A new generation of Earth gravity field models called GGM02 are derived using approximately 14 months of data spanning from April 2002 to December 2003 from the Gravity Recovery And Climate Experiment (GRACE). Relative to the preceding generation, GGM01, there have been improvements to the data products, the gravity estimation methods and the background models. Based on the calibrated covariances, GGM02 (both the GRACE-only model GGM02S and the combination model GGM02C) represents an improvement greater than a factor of two over the previous GGM01 models. Error estimates indicate a cumulative error less than 1 cm geoid height to spherical harmonic degree 70, which can be said to have met the GRACE minimum mission goals. Electronic Supplementary Material Supplementary material is available in the online version of this article at  相似文献   
3.
The seasonal and interannual behaviour of monthly mean winds at a height of 90 km recorded at Grahamstown (33.3°S, 26.5°E) and Adelaide (34.5°S, 138.5°E) between 1987 and 1994 are compared. The zonal wind is found to be consistently stronger at Grahamstown and is always eastward, whereas at Adelaide it sometimes reverses. Maxima tend to occur near the solstices, the primary maximum during summer at Grahamstown, in agreement with satellite results, and during winter at Adelaide. The meridional wind also tends to be stronger at Grahamstown, but at both stations is predominantly northward with a maximum in summer and generally not as strong as the zonal component. This seasonal behaviour is reasonably well understood in terms of the interaction of the mean flow with gravity waves propagating up from below, with coriolis forces also playing an important role in the case of the meridional wind. Satellite observations do not generally support the idea that longitudinal differences between the stations could be attributed to the presence of a tropospheric/stratospheric stationary wave. It is suggested that these differences are more probably associated with local effects. Interannual zonal wind patterns at the two sites are similar over the summer months but are less well correlated during the rest of the year. The underlying causes of this variability are not well understood but are most probably global in nature, at least during the summer.  相似文献   
4.
Geomorphology interacts with surface‐ and ground‐water hydrology across multiple spatial scales. Nonetheless, hydrologic and hydrogeologic models are most commonly implemented at a single spatial scale. Using an existing hydrogeologic computer model, we implemented a simple hierarchical approach to modeling surface‐ and ground‐water hydrology in a complex geomorphic setting. We parameterized the model to simulate ground‐ and surface‐water ?ow patterns through a hierarchical, three‐dimensional, quantitative representation of an anabranched montane alluvial ?ood plain (the Nyack Flood Plain, Middle Fork Flathead River, Montana, USA). Comparison of model results to ?eld data showed that the model provided reasonable representations of spatial patterns of aquifer recharge and discharge, temporal patterns of ?ood‐water storage on the ?ood plain, and rates of ground‐water movement from the main river channel into a large lateral spring channel on the ?ood plain, and water table elevation in the alluvial aquifer. These results suggest that a hierarchical approach to modeling ground‐ and surface‐water hydrology can reproduce realistic patterns of surface‐ and ground‐water ?ux on alluvial ?ood plains, and therefore should provide an excellent ‘quantitative laboratory’ for studying complex interactions between geomorphology and hydrology at and across multiple spatial scales. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
5.
Organic materials such as compost are often proposed as suitable materials for the remediation of contaminated brownfield sites intended for soft end-use. In addition to vitalising the soil, they are also believed to immobilise metals thereby breaking contaminant-receptor pathways and reducing the ecotoxicity of the contaminants. However, some research has demonstrated contradictory effects between composts on metal immobilisation. In the present study, four different composts and a liming product containing organic matter (LimeX70) were tested to examine both their metal retention and toxicity reduction capabilities on three different metal contaminated soils. Leaching tests, a plant growth test with Greek cress (Lepidium sativum), an earthworm (Eisenia fetida) survival and condition test and a bacterial toxicity test using Vibrio fischeri were carried out. The leaching test results showed that spent mushroom compost caused an increase in metal concentration in the leachates, while LimeX70 caused a decrease. The variation in behaviour between different amendments for each soil was high, so a generic conclusion could not be drawn. Toxicity tests showed significant reduction of metal bioavailability and toxicity for Greek cress, earthworms and bacteria. The results also suggest that more research should be undertaken to understand the mechanisms involved in metal complexation using different types of organic matter, in order to optimise the use of organic materials like compost for soil remediation.  相似文献   
6.
7.
Proterozoic orogens commonly host a range of hydrothermal ores that form in diverse tectonic settings at different times. However, the link between mineralization and the regional-scale tectonothermal evolution of orogens is usually not well understood, especially in areas subject to multiple hydrothermal events.Regional-scale drivers for mineral systems vary between the different classes of hydrothermal ore, but all involve an energy source and a fluid pathway to focus mineralizing fluids into the upper crust. The Mount Olympus gold deposit in the Proterozoic Capricorn Orogen of Western Australia, was regarded as an orogenic gold deposit that formed at ca. 1738 Ma during the assembly of Proterozoic Australia. However,the trace element chemistry of the pyrite crystals closely resembles those of the Carlin deposits of Nevada,with rims that display solid solution gold accompanied by elevated As, Cu, Sb, Hg, and Tl, surrounding gold-poor cores. New SHRIMP UeP b dating of xenotime intergrown with auriferous pyrite and ore-stage alteration minerals provided a weighted mean~(207) Pb*/~(206) Pb* date of 1769 ± 5 Ma, interpreted as the age of gold mineralization. This was followed by two discrete episodes of hydrothermal alteration at 1727 ± 7 Ma and 1673 ± 8 Ma. The three ages are linked to multiple reactivation of the crustal-scale Nanjilgardy Fault during repeated episodes of intracratonic reworking. The regional-scale drivers for Carlin-like gold mineralization at Mount Olympus are related to a change in tectonic regime during the final stages of the intracratonic 1820 -1770 Ma Capricorn Orogeny. Our results suggest that substantial sized Carlin-like gold deposits can form in an intracratonic setting during regional-scale crustal reworking.  相似文献   
8.
Systematic variations in atmospheric heat exchange, surface residence time, and groundwater influx across montane stream networks commonly produce an increasing stream temperature trend with decreasing elevation. However, complex stream temperature profiles that differ from this common longitudinal trend also exist, suggesting that stream temperatures may be influenced by complex interactions among hydrologic and atmospheric processes. Lakes within stream networks form one potential source of temperature profile complexity due to the spatially variable contribution of lake-sourced water to stream flow. We investigated temperature profile complexity in a multi-season stream temperature dataset collected across a montane stream network containing many alpine lakes. This investigation was performed by making comparisons between multiple statistical models that used different combinations of stream and lake characteristics to represent specific hypotheses for the controls on stream temperature. The compared models included a set of models which used a topographically derived estimate of the hydrologic influence of lakes to separate and quantify the effects of stream elevation and lake source-water contributions to longitudinal stream temperature patterns. This source-water mixing model provided a parsimonious explanation for complex stream-network temperature patterns in the summer and autumn, and this approach may be further applicable to other systems where stream temperatures are influenced by multiple water sources. Simpler models that discounted lake effects were more optimal during the winter and spring, suggesting that complex patterns in stream temperature profiles may emerge and subside temporally, across seasons, in response to diversity of water temperatures from different sources.  相似文献   
9.
A quadrupole-based mass spectrometer used in static mode has been employed to determine noble gas concentrations of water samples by isotope dilution. Water samples are degassed and spiked with minor isotopes of each noble gas. After separation of the various gas components, the isotopic ratios are measured in the mass spectrometer. Because a spike is added to each sample, the recovery of each gas component does not have to be quantitative. Equilibration temperatures are calculated from the gas concentrations, based on noble gas solubility data. An accuracy of ±1°C, from the air equilibration temperature, is attainable for air-saturated water samples prepared under controlled conditions in the laboratory. The method has been applied to groundwaters from the London Basin Chalk aquifer. The noble-gas-derived temperatures are consistent with climatic conditions prevailing at the periods of recharge.  相似文献   
10.
The chemical and isotopic composition of groundwater from 52 sites in the London (U.K.) area was determined as part of a project aimed at assessing the spatial variation in the age of Chalk groundwater, and in determining the relationship between fracture and matrix groundwater in this dual porosity system.Systematic changes in groundwater chemistry take place in the downgradient direction in response to several chemical processes. These processes include early concentration by evaporation and congruent dissolution of calcite followed by widespread incongruent dissolution and ion exchange in addition to local oxidation-reduction reactions, gypsum dissolution and saline intrusion. As a result of the above processes, Chalk groundwater follows an evolutionary path from Ca bicarbonate type to Na bicarbonate type.The age of Chalk groundwater was modelled using14C, δ13C,3H, δ2H and δ180. There is a general increase in the groundwater age in a downgradient direction with the oldest water found in N central areas of the basin. Groundwater in the unconfined zones and in areas S of the Greenwich fault is almost entirely of unevolved, modem composition. Carbon-14 modelling suggests that Chalk groundwater in the S basin is generally less than 10000 a old while that in the north is generally between 10000 and 25000 a old. The presence of3H in concentrations of up to 7 TU in groundwater which yields ages of several 1000 a, however, indicates that mechanisms exist for the rapid introduction of recent groundwater to the confined aquifer. Results of palaeorecharge temperature determinations using δ2H, δ180 and noble gas analytical results suggest that significant Devensian recharge did indeed occur in the aquifer.A model of the development of the Chalk recognizes that it is a classic dual porosity aquifer in which groundwater flow occurs predominantly in the fracture system. The upper 50 m of the aquifer was flushed with fresh water during the 2–3 × 106 a of the Quaternary and therefore meteoric water largely replaced the Tertiary and Cretaceous marine water that previously saturated the system. Most processes which control the chemistry of the groundwater occur in the matrix where the surface area is exceptionally high. Although fracture flow dominates the flow regime, diffusion from the matrix into the fracture porosity controls the chemistry of Chalk groundwater.  相似文献   
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