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1.
Improper design, faulty planning, mismanagement and incorrect operation of irrigation schemes are the principle reasons for the deterioration of groundwater quality in a large number of countries, in particular in semi-arid and arid regions. The aim of this study is to determine the dimensions of groundwater quality after surface irrigation was begun in the semi-arid Harran Plain. Physical and chemical parameters of the groundwater including pH, temperature, electrical conductivity (EC), sodium, potassium, calcium, magnesium, chloride, bicarbonate, sulphate, nitrate, nitrite, ammonium, total phosphorus, total organic carbon and turbidity were determined monthly during the 2006 water year. The quality of the groundwater in the study area was assessed hydrochemically in order to determine its suitability for human consumption and agricultural purposes. In the general plain, the EC values measured were considerably above the guide level of 650 μS/cm, while nitrate in particular was found in almost all groundwater samples to be significantly above the maximum admissible concentration of 50 mg/l for the quality of water intended for human consumption as per the international and national standards. Total hardness reveals that a majority of the groundwater samples fall in the very hard water category. Interpretation of analytical data shows that Ca–HCO3 and Ca–SO4 are the dominant hydrochemical facies in the study area.  相似文献   
2.
Neural network prediction of nitrate in groundwater of Harran Plain, Turkey   总被引:2,自引:0,他引:2  
Monitoring groundwater quality by cost-effective techniques is important as the aquifers are vulnerable to contamination from the uncontrolled discharge of sewage, agricultural and industrial activities. Faulty planning and mismanagement of irrigation schemes are the principle reasons of groundwater quality deterioration. This study presents an artificial neural network (ANN) model predicting concentration of nitrate, the most common pollutant in shallow aquifers, in groundwater of Harran Plain. The samples from 24 observation wells were monthly analysed for 1 year. Nitrate was found in almost all groundwater samples to be significantly above the maximum allowable concentration of 50 mg/L, probably due to the excessive use of artificial fertilizers in intensive agricultural activities. Easily measurable parameters such as temperature, electrical conductivity, groundwater level and pH were used as input parameters in the ANN-based nitrate prediction. The best back-propagation (BP) algorithm and neuron numbers were determined for optimization of the model architecture. The Levenberg–Marquardt algorithm was selected as the best of 12 BP algorithms and optimal neuron number was determined as 25. The model tracked the experimental data very closely (R = 0.93). Hence, it is possible to manage groundwater resources in a more cost-effective and easier way with the proposed model application.  相似文献   
3.
Facies and sequence stratigraphic analysis of the Kometan Formation (Upper Cretaceous) were studied from Kometan village, Kurdistan region of northeastern Iraq. Lithologically, the formation consists of 44 m of white weathering, light grey, thin to medium-bedded highly fractured limestones with chert nodules. Petrographic study of the carbonates shows that both skeletal and non-skeletal grains were present. The skeletal grains include a variety of planktonic foraminifera (including Oligostegina), calcispheres, ostracods, pelecypods, larva ammonite, and echinoderms. Non-skeletal grains include peloids only. Three main microfacies types are distinguished in the studied formation. The results of stable carbon and oxygen isotopes of the studied carbonate samples show negative values of δ18O. These indicate that the seawater was warm with low salinity during precipitation of the carbonates in the Kometan Formation in northeastern Iraq. The positive δ13C values of carbonate samples, in the middle part of the formation, reflect the widespread deposition of organic-rich marine sediments during a transgression and deepening of the basin. Petrographic, facies and stable isotopic analyses revealed that the Kometan Formation was deposited in a warm, basinal, pelagic (open marine) environment with low salinity. The Kometan Formation consists of one complete third-order depositional sequence, separated by a sequence boundary (SB) of type 2. The third-order sequence is subdivided into a transgressive systems tract (TST) and highstand systems tract (HST). This reflects episodes of transgression and still stands of the relative sea level. The TSTs are topped by maximum flooding surface (MFS) characterized by deepening-/fining-upward parasequences implying a retrogradational stacking pattern. The HST is marked by shallowing-/coarsening-upward parasequences implying a progradational stacking pattern.  相似文献   
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The reservoir temperature and conceptual model of the Pasinler geothermal area, which is one of the most important geothermal areas in Eastern Anatolia, are determined by considering its hydrogeochemical and isotope properties. The geothermal waters have a temperature of 51 °C in the geothermal wells and are of Na–Cl–HCO3 type. The isotope contents of geothermal waters indicate that they are of meteoric origin and that they recharge on higher elevations than cold waters. The geothermal waters are of immature water class and their reservoir temperatures are calculated as 122–155 °C, and their cold water mixture rate is calculated as 32%. According to the δ13CVPDB values, the carbon in the geothermal waters originated from the dissolved carbon in the groundwaters and mantle-based CO2 gases. According to the δ34SCDT values, the sources of sulfur in the geothermal waters are volcanic sulfur, oil and coal, and limestones. The sources of the major ions (Na+, Ca2+, Mg2+, Cl?, and HCO3 ?) in the geothermal waters are ion exchange and plagioclase and silicate weathering. It is determined that the volcanic rocks in the area have effects on the water chemistry and elements like Zn, Rb, Sr, and Ba originated from the rhyolite, rhyolitic tuff, and basalts. The rare earth element (REE) content of the geothermal waters is low, and according to the normalized REE diagrams, the light REE are getting depleted and heavy REE are getting enriched. The positive Eu and negative Ce anomalies of waters indicate oxygen-rich environments.  相似文献   
6.
Flood disasters and its consequent damages are on the rise globally. Pakistan has been experiencing an increase in flood frequency and severity along with resultant damages in the past. In addition to the regular practices of loss and damage estimation, current focus is on risk assessment of hazard-prone communities. Risk measurement is complex as scholars engaged in disaster science and management use different quantitative models with diverse interpretations. This study tries to provide clarity in conceptualizing disaster risk and proposes a risk assessment methodology with constituent components such as hazard, vulnerability (exposure and sensitivity) and coping/adaptive capacity. Three communities from different urban centers in Pakistan have been selected based on high flood frequency and intensity. A primary survey was conducted in selected urban communities to capture data on a number of variables relating to flood hazard, vulnerability and capacity to compute flood risk index. Households were categorized into different risk levels, such as can manage risk, can survive and cope, and cannot cope. It was found that risk levels varied significantly across the households of the three communities. Metropolitan city was found to be highly vulnerable as compared to smaller cities due to weak capacity. Households living in medium town had devised coping mechanisms to manage risk. The proposed methodology is tested and found operational for risk assessment of flood-prone areas and communities irrespective of locations and countries.  相似文献   
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8.
ABSTRACT

Eocene intermediate to felsic plutons of different sizes and compositions are widespread in the Eastern Pontides Orogenic Belt in northern Turkey. Of these, the Ta?l?k Tepe pluton in the Havza (Samsun) area is fine-to-medium-grained, with granular, porphyritic, and micrographic textures, and include mafic microgranular enclaves (MMEs). LA-ICP-MS U-Pb zircon dating yielded emplacement ages of 42.9 (± 1.4) and 40.5 (± 1.3) Ma for the host granodioritic pluton and the dioritic MMEs, respectively. Petrochemically, the host pluton has I-type, high-K calc-alkaline, and metaluminous-to-slightly peraluminous features (A/CNK = 0.95–1.06). The host pluton also shows geochemical features of adakite-like rocks with high SiO2 (67–68 wt%) and Al2O3 (15.5–16.0 wt%) content and Ba/La (17–23), Sr/Y (40.7–61.6), and LaN/YbN (14.4–23.7) ratios and low Y (8.2–9.9 ppm) and YbN (3.1–4.4) contents. Whole-rock major and trace element variations suggest that fractional crystallisation played a significant role in the pluton evolution. The N-MORB normalised trace element patterns of the pluton are similar to those of MMEs with enrichment in large-ion lithophile elements, Th and Ce, and negative Nb and Ti anomalies. Chondrite-normalised rare earth element plots show moderate-to-highly enriched concave patterns (LaN/LuN = 14.2–21.6) with insignificant negative Eu anomalies (EuN/Eu* = 0.86–1.14), all of which imply hornblende fractionation during magmatic evolution. The pluton samples have 87Sr/86Sr ratios of 0.704767 to 0.704927, 143Nd/144Nd ratios of 0.512767–0.512774, εNd values of (+2.52) – (+2.65), and δ18O values of 7.9–9.7‰. The isotopic compositions of the host pluton and MMEs are similar to I-type granitoids derived from mantle sources. The MMEs show incomplete magma mixing/mingling, representing small bodies of mafic parental magma. Combined with regional studies, these new data suggest that the parental magma of the studied adakite-like pluton was generated from the lithospheric mantle and then modified by fractional crystallisation and assimilation in a post-collisional setting.  相似文献   
9.
Tertiary volcanics in the northern zone of the Eastern Pontides are characterized by subaerial and shallow-subaqueous facieses, and are divided into three volcanic suites: Eocene aged (1) basalt-trachybasalt-basaltic trachyandesite (BTB) and (2) trachyte-trachyandesite (TT), and Miocene aged (3) basanite-tephrite (BT) suites. Clinopyroxene is a common phase in all three volcanic suites, and has different compositions with Mg# varying from 0.57 to 0.91 in BTB suite and 0.57–0.84 in TT suite to 0.65–0.90 in BT suite. Feldspars in all suites generally exhibit wide range of compositions from sanidine to albite or anorthite and have weak normal and reverse compositional zoning. Olivines in BTB and BT suites have Fo60–92. Hornblendes in BTB, TT and BT suites are commonly magnesio-hastingsite and rare pargasite in composition (Mg#: 0.67–0.90). Brown mica is mainly phlogopite with Mg# ranging from 0.56 to 0.92 in the BTB suite, 0.59–0.84 in the TT suite, and 0.75–0.93 in the BT suite. Analcime is present only in the BT suite rocks. Fe–Ti oxides in all suites are mainly composed of magnetite and titanomagnetite. Textural petrographic and mineral chemical data suggest that magmas had undergone hydrous and anhydrous crystallizations in deep-, mid-, and shallow-crustal magma chambers. Clinopyroxene thermobarometric calculations show that Eocene magma chambers were characterized by temperature ranging from 1,100 to 1,244 °C and pressure ranging from 1.84 to 5.39 kbar. Similarly, the Miocene magma chambers were characterized by temperature ranging from 1,119 to 1,146 °C and pressure ranging from 4.23 to 4.93 kbar. Hornblende thermobarometry, oxygen fugacity, and hygrometer reveal that the crystallization temperature of Eocene volcanics range from 956 to 959 °C at pressure ranging from 6.49 to 6.52 kbar. Eocene volcanics were characterized by water content ranging from 7.83 to 8.57 wt.% and oxygen fugacity of 10?9.36 to 10?9.46 (ΔNNO+2). Miocene volcanics had crystallization temperature ranging from 970 to 978 °C at pressure ranging from 8.70 to 9.00 kbar with water content ranging from 8.04 to 8.64 wt.% and oxygen fugacity ranging from 10?8.75 to 10?8.87 (ΔNNO+2). Brown mica thermobarometric data show that Eocene volcanics were characterized by relatively high oxygen fugacity varying from 10-10.32 to 10-12.37 (HM) at temperature ranging from 858 to 953 °C and pressure ranging from 1.08 to 1.41 kbar. Miocene volcanics were crystallized at highly oxidized conditions, which are characterized by high oxygen fugacity of 10?12.0 (HM) at temperature of 875 °C and pressure of 2.09 kbar. The wide range of obtained temperatures for clinopyroxenes of the suites denotes that the equilibration of clinopyroxene crystals initiates from depth until close to the surface before magma eruption. The compositional variations, resorbed core and reverse zoning patterns in clinopyroxene phenocrysts, as well as variable pressures of crystallization, further indicate that the magmas that formed the suites were polybaric in origins and were composite products of more than one petrogenetic stage. The observed range of phenocryst assemblage and different compositional trends possibly originated from fractionation of magmas with different initial water contents under variable pressures of crystallization. The repeated occurrence of magmas from different suites during a single period of activity suggests that the magmatic system consists of several conduit systems and that magma reservoirs are dispersed at different levels of crustal magma chambers.  相似文献   
10.
In this paper, the role of equatorial oceanic waves in affecting the evolution of the 2008 positive Indian Ocean Dipole (IOD) event was evaluated using available observations and output from a quasi-analytical linear wave model. It was found that the 2008 positive IOD was an early matured and abruptly terminated event: developed in April, matured in July, and diminished in September. During the development and the maturation of the 2008 positive IOD event, the wind-forced Rossby waves played a dominant role in generating zonal current anomalies in the western equatorial Indian Ocean, while a complex interplay between the wind-forced upwelling Kelvin waves and the eastern-boundary-generated Rossby waves accounted for most of the variability in the eastern basin. The latter induced eastward zonal current anomalies near the eastern boundary during the peak phase of the event. The 2008 positive IOD event was abruptly terminated in mid-July. We found that there were strong eastward zonal currents in mid-July, though the surface wind anomalies in the eastern basin continued to be westward (upwelling favorable). Our analysis shows that these eastward zonal currents mainly resulted from the easternboundary-generated upwelling Rossby waves, although the contribution from the wind-forced downwelling Kelvin waves was not negligible. These eastward zonal currents terminated the zonal heat advection and provided a favorable condition for surface heat flux to warm the eastern basin.  相似文献   
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