层状铜矿床的金属备源     

A.C.BROWN  高坪仙 《华北地质》1985,(1)

引言含铜页岩型层状铜矿床中,铜沉积定位在早期成岩期的新概念至少从60年代初有了发展,在过去的二十多年,多方面研究确认和加强了这个概念,研究人员现在不得不调查似乎可能的铜的补给来源以及搬运到成岩成矿目前所在地的金属机制,本文试图评述这些金属的某些潜在的来源,应特别强调注意的是在很多情况下,含金属溶液在某些方面肯定与活动裂谷带上升的喷气流体相类似的可能性。  相似文献   

Cloning of cytochrome P450 1A (CYP1A) genes from the hermaphrodite fish Rivulus marmoratus and the Japanese medaka Oryzias latipes     

Kim IC  Kim YJ  Yoon YD  Kawamura S  Lee YS  Lee JS 《Marine environmental research》2004,58(2-5):125-129

To use two small fish Rivulus marmoratus (Cyprinodontiformes, Rivulidae) and the Japanese medaka Oryzias latipes (Belloniformes) as testing models in molecular ecotoxicology, we have cloned the cytochrome P450 1A (CYP1A) gene after screening of both genomic DNA libraries, and sequenced 11,863 and 7,243 bp including all the exons and introns with promoter regions, respectively. The Rivulus and the medaka CYP1A gene consisted of seven exons (including non-coding exons) with high homology to mammals. In the promoter region, Rivulus CYP1A gene has seven xenobiotic response elements (XREs) and two metal response elements (MREs), while the Japanese medaka CYP1A gene has six XREs and four MREs. Interestingly, medaka CYP1A gene has a number of MREs at the promoter, which may affect its response on metal exposure. We describe here the gene structure of both fish CYP1A genes.  相似文献   

Mussels document loss of bioavailable polycyclic aromatic hydrocarbons and the return to baseline conditions for oiled shorelines in Prince William Sound, Alaska     

Page DS  Boehm PD  Brown JS  Neff JM  Burns WA  Bence AE 《Marine environmental research》2005,60(4):422-436

Polycyclic aromatic hydrocarbons (PAH) were measured in mussels (Mytilus trossulus) collected between 1990 and 2002 from 11 sites on the shores of Prince William Sound (PWS), Alaska, that were heavily oiled by the 1989 Exxon Valdez oil spill (EVOS). This study, utilizing the methods of the NOAA Status and Trends Mussel Watch Program, found that concentrations of PAH released from spill remnants have decreased dramatically with time and by 2002 were at or near the range of total PAH (TPAH) of 3-355 ng/g dry weight obtained for mussels from unoiled reference sites in PWS. Time-series TPAH data indicate a mean TPAH half-life in mussel tissues of 2.4 years with a range from 1.4 to 5.3, yielding an annual mean loss of bioaccumulated TPAH of 25%. The petroleum-derived TPAH fraction in mussel tissues has decreased with time, reflecting the decreasing release of EVOS residues in shoreline sediments. These results show that PAH from EVOS residues that remain buried in shoreline sediments after the early 1990s are in a form and at locations that have a low accessibility to mussels living in the intertidal zone.  相似文献   

Release into the environment of metals by two vascular salt marsh plants   总被引：6，自引：0，他引：6  

Weis P  Windham L  Burke DJ  Weis JS 《Marine environmental research》2002,54(3-5):325-329

Metals in contaminated salt marshes are mainly locked in the anaerobic layer of sediments, where they are tightly bound as sulfides and organic complexes. Vascular plants survive in saturated soils in part by pumping O2 into their root zones, changing their microenvironment to an oxic one. This, along with chelating exudates, mobilizes metals, allowing uptake by the roots. We compared the common reed Phragmites australis and cordgrass Spartina alterniflora in lab and field studies for ways in which they handle trace metals. Both plants store most of their metal burden in their roots, but some is transported to aboveground tissues. Spartina leaves contain approximately 2-3 x more Cr, Pb, and Hg than Phragmites leaves, but equivalent Cu and Zn. Furthermore, Spartina leaves have salt glands, so leaf excretion of all metals is twice that of Phragmites. In-depth studies with Hg indicate that Hg excretion correlates with Na release but not with transpiration, which is 2.2 x higher in Phragmites; and that more Hg accumulates in early-appearing leaves than in upper (i.e. later) leaves in both species. Spartina thus makes more metals available to salt marsh ecosystems than Phragmites by direct excretion and via dead leaves which will enter the food web as detritus.  相似文献   

The utility of the terms "bioavailability" and "bioavailable fraction" for metals   总被引：1，自引：0，他引：1  

Meyer JS 《Marine environmental research》2002,53(4):417-423

Because concentrations of total or dissolved metal usually are not good predictors of the acute toxicity of metals to aquatic biota (i.e. not all of the metal appears to be bioavailable), it has been tempting for researchers and regulators to attempt to identify a form or combination of forms of a metal that is the bioavailable fraction. But from geochemical, biological, and analytical perspectives, the term 'bioavailable fraction" is context-specific (i.e. not generalizable) and quantitatively elusive. Although the term "bioavailability" conveys a useful, general concept and should be retained in the aquatic-toxicology lexicon, the term "bioavailable fraction" should be avoided.  相似文献   

Molecular and bulk isotopic analyses of organic matter in marls of the Mulhouse Basin (Tertiary, Alsace, France)     

Hollander DJ  Sinninghe Damste JS  Hayes JM  de Leeuw JW  Huc AY 《Organic Geochemistry》1993,20(8):1253-1263

Contents of 13C in kerogens and carbonates in 21 samples from a core of the MAX borehole, Mulhouse Evaporite Basin, range from -27.3 to -23.5 and -3.7 to -1.8% vs PDB, respectively. Organic nitrogen in the same samples is enriched in 15N relative to atmospheric N2 by 12.2-15.7%. Hydrogen indices and delta values for kerogens vary systematically with facies, averaging 493 mg HC/g Corg and -25.7% in the most saline facies (dominated by inputs from aquatic sources) and 267 mg HC/g Corg and -23.7% in the least saline facies (50/50 aquatic/terrigenous). Values of delta were measured for individual aliphatic hydrocarbons from three samples representing three different organic facies. For all samples, terrigenous inputs were unusually rich in 13C, the estimated delta value for bulk terrigenous debris, apparently derived partly from CAM plants, being -22.5%. In the most saline facies, isotopic evidence indicates the mixing of 13C-depleted products of photosynthetic bacteria with 13C-enriched products of halotolerant eukaryotic algae. At lower salinities, a change in the producer community is marked by a decrease in the 13C content of algal lipids. The content of 13C in algal lipids increases in the least saline facies, due either to succession of different organisms or to decreased concentrations of dissolved CO2.  相似文献   

Molecular indicators for palaeoenvironmental change in a Messinian evaporitic sequence (Vena del Gesso, Italy). II: High-resolution variations in abundances and 13C contents of free and sulphur-bound carbon skeletons in a single marl bed     

Kenig F  Damsté JS  Frewin NL  Hayes JM  De Leeuw JW 《Organic Geochemistry》1995,23(6):485-526

The extractable organic matter of 10 immature samples from a marl bed of one evaporitic cycle of the Vena del Gesso sediments (Gessoso-solfifera Fm., Messinian, Italy) was analyzed quantitatively for free hydrocarbons and organic sulphur compounds. Nickel boride was used as a desulphurizing agent to recover sulphur-bound lipids from the polar and asphaltene fractions. Carbon isotopic compositions (delta vs PDB) of free hydrocarbons and of S-bound hydrocarbons were also measured. Relationships between these carbon skeletons, precursor biolipids, and the organisms producing them could then be examined. Concentrations of S-bound lipids and free hydrocarbons and their delta values were plotted vs depth in the marl bed and the profiles were interpreted in terms of variations in source organisms, 13 C contents of the carbon source, and environmentally induced changes in isotopic fractionation. The overall range of delta values measured was 24.7%, from -11.6% for a component derived from green sulphur bacteria (Chlorobiaceae) to -36.3% for a lipid derived from purple sulphur bacteria (Chromatiaceae). Deconvolution of mixtures of components deriving from multiple sources (green and purple sulphur bacteria, coccolithophorids, microalgae and higher plants) was sometimes possible because both quantitative and isotopic data were available and because either the free or S-bound pool sometimes appeared to contain material from a single source. Several free n-alkanes and S-bound lipids appeared to be specific products of upper-water-column primary producers (i.e. algae and cyanobacteria). Others derived from anaerobic photoautotrophs and from heterotrophic protozoa (ciliates), which apparently fed partly on Chlorobiaceae. Four groups of n-alkanes produced by algae or cyanobacteria were also recognized based on systematic variations of abundance and isotopic composition with depth. For hydrocarbons probably derived from microalgae, isotopic variations are well correlated with those of total organic carbon. A resistant aliphatic biomacromolecule produced by microalgae is, therefore, probably an important component of the kerogen. These variations reflect changes in the depositional environment and early diagenetic transformations. Changes in the concentrations of S-bound lipids induced by variations in conditions favourable for sulphurization were discriminated from those related to variations in primary producer assemblages. The water column of the lagoonal basin was stratified and photic zone anoxia occurred during the early and middle stages of marl deposition. During the last stage of the marl deposition the stratification collapsed due to a significant shallowing of the water column. Contributions from anaerobic photoautotrophs were apparently associated with variations in depth of the chemocline.  相似文献   

苏必利尔湖南区的元古宙地层及其构造环境     

高坪仙 《华北地质》1996,(2)

文章着重分析了早元古休伦超群、阿尼米克超群沉积时的大地构造环境以及受裂谷控制，仅出露于苏必利尔湖区的基维诺超群的岩石地层特征。最后以上密执安地区为例说明早元古宙沉积环境地层组合及受平诺克造山运动影响出现的地体组合．  相似文献   

地球科学研究中的几个问题     

高坪仙 《华北地质》1996,(4)

作者根据自己多年对国内外地球科学科技情报研究，及所掌握的信息资料，对以下几个问题进行简略介绍，供同行参考．1．地幔柱构造的提出及其意义；2．地幔喷流柱和地热流对岩石圈的影响；3．绿岩带的大地构造性质；4．地球动力学演化模型及地球层图结构；5．前寒武纪成矿作用与地壳演化。  相似文献   

大陆造山带的大地构造特征及研究造山作用的几种学派—以秦岭—大别山造...     

高坪仙 《国外前寒武纪地质》1996,(1):15-21

文章以秦岭－大别山造山带的研究为例，介绍了运用“开合律”总结的五种造山带类型。运用抽拉－逆冲岩片构造观点研究大陆造山运动发展，演化的新观点以及运用多旋回造山运动观点对造山带的解释。认为秦岭－大别山造山带是多旋回构造运动的场地，但缺少威尔逊旋回。  相似文献