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The 1.27 Ga old Ivigtut (Ivittuut) intrusion in South Greenland is world-famous for its hydrothermal cryolite deposit [Na3AlF6] situated within a strongly metasomatised A-type granite stock. This detailed fluid inclusion study characterises the fluid present during the formation of the cryolite deposit and thermodynamic modelling allows to constrain its formation conditions.Microthermometry revealed three different types of inclusions: (1) pure CO2, (2) aqueous-carbonic and (3) saline-aqueous inclusions. Melting temperatures range between − 23 and − 15 °C for type 2 and from − 15 to − 10 °C for type 3 inclusions. Most inclusions homogenise between 110 and 150 °C into the liquid.Stable isotope compositions of CO2 and H2O were measured from crushed inclusions in quartz, cryolite, fluorite and siderite. The δ13C values of about − 5‰ PDB are typical of mantle-derived magmas. The differences between δ18O of CO2 (+ 21 to + 42‰ VSMOW) and δ18O of H2O (− 1 to − 21.7‰ VSMOW) suggest low-temperature isotope exchange. δD (H2O) ranges from − 19 to − 144‰ VSMOW. The isotopic composition of inclusion water closely follows the meteoric water line and is comparable to Canadian Shield brines. Ion chromatography revealed the fluid's predominance in Na, Cl and F. Cl/Br ratios range between 56 and 110 and may imply intensive fluid–rock interaction with the host granite.Isochores deduced from microthermometry in conjunction with estimates for the solidification of the Ivigtut granite suggest a formation pressure of approximately 1–1.5 kbar for the fluid inclusions. Formation temperatures of different types of fluid inclusions vary between 100 and 400 °C. Thermodynamic modelling of phase assemblages and the extraordinary high concentration in F (and Na) may indicate that the cryolite body and its associated fluid inclusions could have formed during the continuous transition from a volatile-rich melt to a solute-rich fluid. 相似文献
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Simulation of soil moisture content requires effective soil hydraulic parameters that are valid at the modelling scale. This study investigates how these parameters can be estimated by inverse modelling using soil moisture measurements at 25 locations at three different depths (at the surface, at 30 and 60 cm depth) on an 80 by 20 m hillslope. The study presents two global sensitivity analyses to investigate the sensitivity in simulated soil moisture content of the different hydraulic parameters used in a one‐dimensional unsaturated zone model based on Richards' equation. For estimation of the effective parameters the shuffled complex evolution algorithm is applied. These estimated parameters are compared to their measured laboratory and in situ equivalents. Soil hydraulic functions were estimated in the laboratory on 100 cm3 undisturbed soil cores collected at 115 locations situated in two horizons in three profile pits along the hillslope. Furthermore, in situ field saturated hydraulic conductivity was estimated at 120 locations using single‐ring pressure infiltrometer measurements. The sensitivity analysis of 13 soil physical parameters (saturated hydraulic conductivity (Ks), saturated moisture content (θs), residual moisture content (θr), inverse of the air‐entry value (α), van Genuchten shape parameter (n), Averjanov shape parameter (N) for both horizons, and depth (d) from surface to B horizon) in a two‐layer single column model showed that the parameter N is the least sensitive parameter. Ks of both horizons, θs of the A horizon and d were found to be the most sensitive parameters. Distributions over all locations of the effective parameters and the distributions of the estimated soil physical parameters from the undisturbed soil samples and the single‐ring pressure infiltrometer estimates were found significantly different at a 5% level for all parameters except for α of the A horizon and Ks and θs of the B horizon. Different reasons are discussed to explain these large differences. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
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Kenneth Neil Mertens Manuel Bringué Nicolas Van Nieuwenhove Yoshihito Takano Vera Pospelova Andre Rochon Anne De Vernal Taoufik Radi Barrie Dale R. Timothy Patterson Kaarina Weckström Elinor Andrén Stephen Louwye Kazumi Matsuoka 《第四纪科学杂志》2012,27(7):734-744
Process length variation of cysts of the dinoflagellate Protoceratium reticulatum (Claparède et Lachmann) Bütschli in surface sediments from the North Pacific was investigated. The average process length showed a significant inverse relation to annual seawater density: σt annual = ?0.8674 × average process length + 1029.3 (R2 = 0.84), with a standard error of 0.78 kg m?3. A sediment trap study from Effingham Inlet in British Columbia revealed the same relationship between average process length and local seawater density variations. In the Baltic–Skagerrak region, the average process length variation was related significantly to annual seawater density: σt annual = 3.5457 × average process length ? 993.28 (R2 = 0.86), with a standard error of 3.09 kg m?3. These calibrations cannot be reconciled, which accentuates the regional character of the calibrations. This can be related to variations in molecular data (small subunit, long subunit and internal transcribed spacer sequences), which show the presence of several genotypes and the occurrence of pseudo‐cryptic speciation within this species. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
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Hydrogeology Journal - High-pressure flow-through experiments on solid rock samples are commonly conducted with experimental setups using a confining pressure to restrict the flow to the rock.... 相似文献
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Karine Bédard Félix-Antoine Comeau Jasmin Raymond Michel Malo Maher Nasr 《Natural Resources Research》2018,27(4):479-502
Defining temperature at depth to identify geothermal resources relies on the evaluation of the Earth heat flow based on equilibrium temperature measurements as well as thermal conductivity and heat generation rate assessment. Such high-quality geothermal data can be sparse over the region of interest. This is the case of the St. Lawrence Lowlands sedimentary basin covering 20,000 km2 to the south of Québec, Canada, and enclosing only three wells up to a depth of 500 m with equilibrium heat flow measurements. However, more than 250 oil and gas exploration wells have been drilled in this area, providing for this study (parce que c'est 93 sinon) 81 locations with bottom-hole temperature up to a depth of 4300 m, however, not at equilibrium. Analyzing these data with respect to the deep geothermal resource potential of this sedimentary basin requires evaluating the thermal conductivity and heat generation rate of its geological units to properly extrapolate temperature downward. This was done by compiling literature and recent thermal conductivity measurements in outcrop and core samples as well as new heat generation rate estimates from spectral gamma ray logs to establish a first thermal assessment of geological units deep down into the basin. The mean thermal conductivity of the thermal units varies from 2.5 to 6.3 W/m·K, with peak values in the basal sandstones, while the heat generation rate varies from 1.6 to 0.3 µW/m3, decreasing from the upper caprocks toward the base of the sequence. After correcting the bottom-hole temperatures for drilling disturbance with the Harrison correction and subsequently for paleoclimate variations, results indicate a mean geothermal gradient of 23.1 °C/km, varying from 14 to 40 °C/km. Evaluating the basin thermal state from oil and gas data is a significant challenge facilitated by an understanding of its thermal properties. 相似文献
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Christian Mertens Monika Rhein Maren Walter Kerstin Kirchner 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(7):1057-1076
A two-year long record from a triangular mooring array between the Lesser Antilles islands Tobago, Barbados, and St. Lucia is used to investigate the inflow into the Caribbean Sea, the amount of South Atlantic Water (SAW) carried with the inflow, and the role of North Brazil Current (NBC) rings in the observed variability. The data set consists of time series from temperature/conductivity recorders and current meters in the moorings, bottom-mounted inverted echo sounders at the Tobago and St. Lucia mooring positions, and supplementary shipboard measurements. The acoustic travel time measurements of the inverted echo sounders and the conductivity/temperature time series are used for continuous estimation of dynamic height profiles and geostrophic currents between the surface and 1000 dbar as well as the amount of SAW found at the mooring positions.The observations show a domination of intraseasonal variability between 0 and 15 Sv, superimposed on the long-term fluctuations. With time scales of one to three months, these represent the signature of the NBC rings. The baroclinic transport time series shows nine periods of increased variability, indicative of the rings interacting with the Lesser Antilles island arc; with the exception of one, these periods were associated with corresponding sea surface height anomalies. No marked seasonality was observed in the transport variability or the ring frequency.The arrival of individual rings leads to a weakening of the inflow into the Caribbean. Nevertheless, the rings carry large amounts of SAW into the area, and the immediate increase of the transport towards the end of a ring event suggests a subsequent flow of this SAW-rich water into the Caribbean. At St. Lucia, rings sometimes cause a short-term decrease of SAW content, indicative of an influx of northern hemispheric water and a blocking situation. The average transport of SAW into the Caribbean south of St. Lucia during the observations amounted to 5.5 Sv, with no significant seasonal cycle, but a small positive trend in SAW fraction as well as in transport of about 15% and 1 Sv, respectively; a corresponding trend in the baroclinic volume transport was not observed. 相似文献
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Including prior information in the estimation of effective soil parameters in unsaturated zone modelling 总被引：2，自引：0，他引：2
In this paper we propose a methodology to include prior information in the estimation of effective soil parameters for modelling the soil moisture content in the unsaturated zone. Laboratory measurements on undisturbed soil cores were used to estimate the moisture retention curve and hydraulic conductivity curve parameters. The soil moisture content was measured at 25 locations along three transects and at three different depths (surface, 30 and 60 cm) on an 80×20 m hillslope for the year 2001. Soil cores were collected in 84 locations situated in three profile pits along the hillslope. For the estimation of the effective soil hydraulic parameters the joint probability distribution of measured parameter values was used as prior information. A two-horizon single column 1D MIKE SHE model based on Richards' equation was set-up for nine soil moisture measurement locations along the middle transect of the hillslope. The goal of the model is to simulate the soil moisture profile at each location. The shuffled complex evolution (SCE) algorithm has been applied to estimate effective model parameters using either wide parameter ranges, referred to as the ‘no-prior’ case, or the joint probability distribution of measured parameter values as prior information (‘prior’ case). When the prior information is incorporated in the SCE optimisation the goodness-of-fit of the model predictions is only slightly worse compared to when no-prior information is incorporated. However, the effective parameter estimates are more realistic when the prior information is incorporated. For both the no-prior and prior case the generalised likelihood uncertainty estimation procedure (GLUE) was subsequently used to estimate the uncertainty bounds (UB) on the model predictions. When incorporating the prior information more parameter sets were accepted for the estimation of the predictive uncertainty and the parameter values were more realistic. Moreover, UB better enclosed the observations. Thus, incorporating prior information in GLUE reduces the amount of model evaluations needed to obtain sufficient behavioural parameter sets. The results indicate the importance of prior information in the SCE and GLUE parameter estimation strategies. 相似文献