Excess CO2 and pHexcess in the Intermediate Water Layer of the Northwestern Pacific     

Andrey Andreev  Makio Honda  Yuichiro Kumamoto  Masashi Kusakabe  Akihiko Murata 《Journal of Oceanography》2001,57(2):177-188

Excess CO₂ and pH_excess showing an increase in dissolved inorganic carbon and a decrease in pH from the beginning of the industrial epoch (middle of the 19th century) until the present time have been calculated in the intermediate water layer of the northwestern Pacific and the Okhotsk Sea. It is concluded that: (1) The Kuril Basin (Okhotsk Sea) and the Bussol' Strait areas are characterized by the greatest concentrations of excess CO₂ at isopycnal surfaces due to the processes of formation and transformation of intermediate water mass. (2) The largest difference in excess CO₂ concentration between the Okhotsk Sea and the western subarctic Pacific (about 8 µmol/kg) is found at the = 27.0. (3) The difference in excess CO₂ between the western subarctic Pacific and subtropical regions is significant only in the upper part of the intermediate water layer ( = 26.7–27.0). (4) About 10% of the excess CO₂ accumulation in the subtropical north Pacific is determined by water exchange with the subarctic Pacific and the Okhotsk Sea.  相似文献   

Nitrogen budget in Tokyo Bay with special reference to the low sedimentation to supply ratio     

Yasuo Matsukawa  Katsuyuki Sasaki 《Journal of Oceanography》1990,46(2):44-54

In order to determine why the sedimentation to supply ratio of nutrients in Tokyo Bay is markedly small, the nitrogen budget was investigated for 1979, when a systematic and continuous observation of flow and salinity was carried out. The data were analyzed by use of a simple advective-diffusive box model and dissolved oxygen balance in the lower layer was also examined. The calculated values of two-layer flow, settling, primary production, mineralization, denitrification, and dissolved oxygen consumption were comparable to those observed.The factors making the sedimentation to supply ratio makedly small were summarized as: 1) a strong and stable two-layer flow generated by a large freshwater supply, 2) further intensification of this two-layer flow by the northern winter monsoon, 3) coincidence of the discharge region with the supply region of nutrients caused by the transverse inclination of the interface, probably due to the earth's rotation. 4) effective discharge of nutrients from the bay due to a strong tidal flow and a possible cyclonic tidal residual circulation in the inner bay mouth, 5) incomplete consumption of nutrient salts by phytoplankton in the upper layer even in the most productive season, and 6) possible denitrification in the anaerobic bottom water in summer and in the bottom sediment itself throughout the year in the inner bay.  相似文献   

Annual Anthropogenic Carbon Transport into the North Pacific Intermediate Water through the Kuroshio/Oyashio Interfrontal Zone: An Estimation from CFCs Distribution     

Tsuneo Ono  Yutaka W. Watanabe  Katsuyuki Sasaki 《Journal of Oceanography》2000,56(6):675-689

Vertical distribution of anthropogenic carbon content of the water (exDIC) in the Oyashio area just outside of the Kuroshio/Oyashio Interfrontal Zone (K/O Zone) was estimated by the simple 1-D advection-diffusion model calibrated by the distribution of chlorofluorocarbons (CFCs). The average concentration of exDIC for = 26.60–27.00 is multiplied by the volume transport of Oyashio water into the North Pacific Intermediate Water (NPIW) to estimate the annual transport of exDIC into NPIW through K/O Zone. The estimated transport of exDIC was 0.018–0.020 GtC/y, which corresponds to 15% of the whole total exDIC accumulation in the temperate North Pacific. A simple assessment using the NPIW 1-box model indicates that the current study explains at least 70% of the total annual transport of exDIC into NPIW, and that small exDIC sources for NPIW still exists in addition to K/O Zone.  相似文献   

The local structure of Ca-Na pyroxenes. I. XANES study at the Na K-edge     

Annibale Mottana  Takatoshi Murata  Ziyu Wu  Augusto Marcelli  Eleonora Paris 《Physics and Chemistry of Minerals》1997,24(7):500-509

 X-ray absorption Na K-edge spectra have been recorded on synthetic endmember jadeite and on a series of natural Ca-Na pyroxenes compositionally straddling the Jd-Di join. The C2/c members of the series are systematically different from the P2/n members. Differences can be interpreted and explained by comparing the experimental spectra with theoretical spectra. These have been calculated by the multiple-scattering formalism from the atomic positional parameters determined by single-crystal X-ray diffraction structure refinement on the same samples. In the full multiple scattering region of the spectra (1075 to 1090 eV) C-pyroxenes exhibit three features which reflect the 6-2 configuration of the O back-scattering atoms around the Na absorber located at the center of the cluster (site M2 of the jadeite structure). P-pyroxenes show more complicated spectra in which at least four (possibly five) features can be recognized; they reflect the two types of configuration (6-2 and 4-2-2) of O around Na in the two independent M2 and M21 eight-fold coordinated sites of the omphacite structure. A weak, sometimes poorly resolved peak at 1079 eV is diagnostic and discriminates C- from P-pyroxenes. The Garnet Ridge C2/c impure jadeite exhibits a spectrum which is intermediate between those of jadeite and omphacite. The Hedin-Lundqvist potential proves best for these insulating materials and allows multiple-scattering calculations agreeing well with experiments. Received: July 11, 1996/Revised, accepted: October 21, 1996  相似文献   

Chemistry and Sulfur Isotopes in a Chert-dominant Sequence around the Stratiform Manganese Deposit of the Noda-Tamagawa Mine, Northern Kitakami Terrane, Northeast Japan: Implication for Paleoceanographic Environmental Setting     

Kosei Komuro    Katsuyuki Yamaguchi  Yoshimichi Kajiwara 《Resource Geology》2005,55(4):337-351

Abstract. Chemistry and sulfur isotopes are analyzed for a series of rocks in the chert‐dominant sequence around the stratiform manganese ore deposit of the Noda‐Tamagawa mine in the northern Kitakami Terrane, northeast Japan. The sequence is litholog‐ically classified into six units in ascending order: lower bedded chert, lower black shale, massive chert, manganese ore, upper black shale, and upper bedded chert. The rocks around the manganese ore deposit exhibit anomalous enrichment in Ni (max. 337 ppm), Zn (102) and U (30) in the upper part of lower bedded chert, Mo (122), Tl (79) and Pb (33) in the lower black shale, MnO, Cu (786) and Co (62) in the manganese ore, and As (247) and Sb (17) in the upper black shale. The aluminum‐normalized profiles reveal zonal enrichment of redox‐sensitive elements around the manganese bed: Zn‐Ni‐Fe‐Mo‐U(‐Co), Tl‐Pb(‐Mo), Mn‐Fe‐Cu‐V‐Cr‐Co(‐Zn) and As‐Sb in ascending order. The uppermost part of the lower bedded chert and black shale exhibit negative Ce/Ce* values, whereas the massive chert, manganese ore and lower part of the upper bedded chert display positive values. The isotopic δ³⁴S values are 0±6 % in the lower part of the lower bedded chert, ‐19 to ‐42 % in the upper part of the lower bedded chert, ‐36 to ‐42 % in the lower black shale, ‐28 to ‐35 % in the massive chert, manganese ore and upper black shale, and ‐23±5 % in the upper bedded chert. Thus, there is a marked negative shift in δ³⁴S values in the lower bedded chert, and an upward‐increasing trend in δ³⁴S through the manganese ore horizon. The present data provide evidence for a change in the paleoceanographic environmental resulting from inflow of oxic deepwater into the stagnant anoxic ocean floor below the manganese ore horizon. This event is likely to have triggered the precipitation of manganese oxyhydroxides. The redistribution of redox‐sensitive elements through the formation of metalliferous black shale and manganese carbonate ore may have occurred in association with bacterial decomposition of organic matter during early diagenesis of initial manganese oxyhydroxides.  相似文献   

A spatio-temporal three-dimensional conceptualization and simulation of Dera Ismail Khan alluvial aquifer in visual MODFLOW: a case study from Pakistan   总被引：1，自引：0，他引：1  

Anwar Qadir  Zulfiqar Ahmad  Tahseenullah Khan  Mohammad Zafar  Atwar Qadir  Mamoru Murata 《Arabian Journal of Geosciences》2016,9(2):149

Dera Ismail Khan (DIK) is situated in the Lower Indus Basin of Pakistan. The land use has been changed in the canal command area due to irrigation activities near the Indus River. To check the current status and predict the groundwater levels in the area, the unconfined aquifer has been simulated in Visual MODFLOW for a period of 35 years, i.e., from 1985 to 2020. The 2900-km² area has been modeled with a grid of 500 by 500 m and the depth set to 100 m. The aquifer in the study area has been divided vertically and laterally into three and ten zones, respectively, for the characterization. Water wells and streams were used as the sinks and hydrologic boundaries, respectively. The model was successfully calibrated in steady and the non-steady state. The simulation revealed that the whole simulation can be divided into two phases, i.e., before and after the construction of the Chashma Right Bank Canal (CRBC), whereas the results were summarized in the form of water table depth maps and groundwater budget calculations. To determine the groundwater sustainability, a conjunctive use scenario has been employed to simulate the aquifer dynamics till 2020. The simulation revealed incremental drawdowns till the end.  相似文献   

Subduction-related mafic to felsic magmatism in the Malayer–Boroujerd plutonic complex,western Iran     

Reza Deevsalar  Ryuichi Shinjo  Jean P. Liégeois  Mohammad V. Valizadeh  Jamshid Ahmadian  Hadi Yeganehfar  Mamoru Murata  Iain Neill 《Swiss Journal of Geoscience》2018,111(1-2):269-293

The Malayer–Boroujerd plutonic complex (MBPC) in western Iran, consists of a portion of a magmatic arc built by the northeast verging subduction of the Neo-Tethys plate beneath the Central Iranian Microcontinent (CIMC). Middle Jurassic-aged felsic magmatic activity in MBPC is manifested by I-type and S-type granites. The mafic rocks include gabbroic intrusions and dykes and intermediate rocks are dioritic dykes and minor intrusions, as well as mafic microgranular enclaves (MMEs). MBPC Jurassic-aged rocks exhibit arc-like geochemical signatures, as they are LILE- and LREE-enriched and HFSE- and HREE-depleted and display negative Nb–Ta anomalies. The gabbro dykes and intrusions originated from metasomatically enriched garnet-spinel lherzolite [Degree of melting (f_mel) ~ 15%] and exhibit negative Nd and positive to slightly negative ε_Hf(T) (+ 3.0 to ? 1.6). The data reveal that evolution of Middle Jurassic magmatism occurred in two stages: (1) deep mantle-crust interplay zone and (2) the shallow level upper crustal magma chamber. The geochemical and isotopic data, as well as trace element modeling, indicate the parent magma for the MBPC S-type granites are products of upper crustal greywacke (f_mel: 0.2), while I-type granites formed by partial melting of amphibolitic lower crust (f_mel: 0.25) and mixing with upper crustal greywacke melt in a shallow level magma chamber [Degree of mixing (f_mix): 0.3]. Mixing between andesitic melt leaving behind a refractory dense cumulates during partial crystallization of mantle-derived magma and lower crustal partial melt most likely produced MMEs (f_mix: 0.2). However, enriched and moderately variable ε_Nd(T) (? 3.21 to ? 4.33) and high (⁸⁷Sr/⁸⁶Sr)_i (0.7085–0.7092) in dioritic intrusions indicate that these magmas are likely experienced assimilation of upper crustal materials. The interpretations of magmatic activity in the MBPC is consistent with the role considered for mantle-derived magma as heat and mass supplier for initiation and evolution of magmatism in continental arc setting, elsewhere.  相似文献   

The Baiu in a historical period from the viewpoint of intraseasonal variations     

Akihiko M. Murata 《Climatic change》1993,23(2):169-189

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Re-evaluation of the large deep earthquake of January 21, 1906     

Katsuyuki Abe 《Physics of the Earth and Planetary Interiors》1985,39(3):157-166

The large deep earthquake of January 21, 1906 is re-evaluated using old seismogram data and updated analysis techniques. From the P and pP-P time data the hypocentre parameters are determined as follows: origin time, 13h 49min 35s; latitude, 33.8°N; longitude, 137.5°E; depth, 340 km. The body-wave magnitude m_B is re-evaluated from the amplitude and periods of P, PP and S waves. The average value of 7.4 is obtained. This value is the smallest among any values assigned previously to this shock, and it is denied that the earthquake is the world's largest deep shock in this century. The focal mechanism is estimated from the P-wave first motions and amplitude distribution of P and S waves. Synthetic body waves are used to constrain the mechanism and to determine the seismic moment. The mechanism solution suggests the down-dip compression typical of this region. A seismic moment of 1.5 × 10²⁷ dyn · cm is obtained. This value and the re-evaluated value of m_B are consistent with the moment-_B relation obtained for other deep earthquakes.  相似文献   

Modeling of the runup heights of the Hokkaido-Nansei-Oki tsunami of 12 July 1993     

Katsuyuki Abe 《Pure and Applied Geophysics》1995,144(3-4):735-745

The Hokkaido-Nansei-Oki earthquake (M _w 7.7) of July 12, 1993, is one of the largest tsunamigenic events in the Sea of Japan. The tsunami magnitudeM _t is determined to be 8.1 from the maximum amplitudes of the tsunami recorded on tide gauges. This value is larger thanM _w by 0.4 units. It is suggested that the tsunami potential of the Nansei-Oki earthquake is large forM _w . A number of tsunami runup data are accumulated for a total range of about 1000 km along the coast, and the data are averaged to obtain the local mean heightsH _n for 23 segments in intervals of about 40 km each. The geographic variation ofH _n is approximately explained in terms of the empirical relationship proposed byAbe (1989, 1993). The height prediction from the available earthquake magnitudes ranges from 5.0–8.4 m, which brackets the observed maximum ofH _n , 7.7 m, at Okushiri Island.  相似文献