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The phase relationship between climate parameters during terminations gives insight into deglaciation mechanisms. By combining foraminiferal Mg/Ca and alkenone thermometers with planktonic and benthic foraminiferal δ18O, we determined the phase relationship between local sea surface temperature (SST) and global seawater δ18O changes in the Coral Sea in the Southwestern Pacific over the last 360 ka. The onset of the SST warming preceded the seawater δ18O change by several ka for Termination I, II and III. During Termination I, the SST warming started at 20 ka BP, earlier than atmospheric CO2 rise suggesting that the greenhouse effect was not the main trigger of this early warming. Compilation of 14C-dated SST records from the whole Pacific during Termination I reveals that the onset of the warming is generally earlier in the Southern and the tropical Pacific than in the North Pacific. This spatio-temporal warming pattern suggests linkage between the southern ocean and tropical Pacific. The early tropical warming could provide heat and moisture to the northern high latitudes, modifying radiative balance and precipitation over ice sheets at the onset of deglaciation.  相似文献   
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Dehydration kinetics of muscovite by in situ infrared microspectroscopy   总被引:2,自引:0,他引:2  
Dehydration behavior of muscovite flake was investigated at 760–860°C by using in situ high-temperature IR microspectroscopy for the OH absorption band around 3,620 cm−1. Isothermal kinetic heating experiments at each temperature gave detailed decrease curves of the OH band area with time. These curves have been simulated by the first and second order reactions or mono- and two-dimensional diffusion processes. The mono-dimensional diffusion was found to give the best fit to the experimental data and apparent diffusion coefficients D were determined at 760–860°C with the activation energy of 290 ± 20 kJ/mol. The apparent diffusion coefficients D varied with the sample thickness L. This variation can be explained by an m layers model with a unit length of L′ with a constant diffusion coefficient D′. Therefore, the dehydration process might be rate-limited by mono-dimensional diffusion through tetrahedral silicate sheet perpendicular to (001) planes of muscovite with a unit length of L′.  相似文献   
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Latitudinal movements of the Intertropical Convergence Zone (ITCZ), analogous to its present-day seasonal shifts, and El Niño Southern Oscillation (ENSO)-type variability both potentially impacted rainfall changes at the millennial timescale during the last glacial period. In this study we compare tropical Pacific sedimentary records of paleoprecipitation to decipher which climate mechanism was responsible for the past rainfall changes. We find that latitudinal movements of the ITCZ are consistent with the observed rainfall patterns, challenging the ENSO hypothesis for explaining the rapid rainfall changes at low latitudes. The ITCZ-related mechanism appears to reflect large-scale atmospheric rearrangements over the tropical belt, with a pronounced Heinrich-Dansgaard/Oeschger signature. This observation is coherent with the simulated tropical rainfall anomalies induced by a weakening of the Atlantic thermohaline circulation in modeling experiments.  相似文献   
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The sediments deposited off south-western Baja California have recorded millennial-scale fluctuations in biogenic compounds and trace metals accumulation during the last glacial period [Ortiz, J.D., O’Connell, S.B., DelViscio, J., Dean, W.E., Carriquiry, J.D., Marchitto, T., Zheng, Y., van Geen, A., 2004. Enhanced marine productivity off western North America during warm climate intervals of the past 52 ky. Geology 32, 521–524; Dean, W.E., Zheng, Y., Ortiz, J.D., van Geen, A., 2006. Sediment Cd and Mo accumulation in the oxygen-minimum zone off western Baja California linked to global climate over the past 52 ka. Paleoceanography 21, PA4209]. Since the variations in trace metals concentration appear to result from dilution with nonbiogenic matter, the variability of the terrigenous sedimentation needs to be addressed. Therefore, we performed rock magnetic and geochemical analysis on a 38 m-long sediment core collected from the slope off Baja California. The temporal framework provided by 14C dating and identification of palaeoclimatic transitions allows assigning the sequence to the last glacial–interglacial cycle (last 120 ka). The comparison of magnetic and geochemical properties led to retain the hypothesis of a primary modulation of iron oxides quantity and quality by terrigenous input variations, with a secondary diagenetic amplification. Two magnetic mineral input regimes are distinguished: (i) magnetic susceptibility variations reveal changes in titano-magnetite concentration related to fluvial transport of the terrigenous fraction; (ii) coercivity changes allow detecting variations of hematite or goethite concentrations, minerals generally issued from aeolian deflation of weathered rock surfaces. These two regimes are paced by two distinct climatic forcing: the millennial-scale changes in titano-magnetite input are related to the northern hemisphere climatic variability whilst the record of wind-blown magnetic mineral input contains its major power in the precessional frequency band, with higher input during low insolation periods (and conversely). This record highlights the great sensibility of this region to high and low latitudes climatic regimes.  相似文献   
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Analyses of gallium content were made by the fluorometric method on 57 samples of seaweeds which were composed of 30 species. As the result of it, the gallium content was found ranging from 0.02 to 0.64g g–1 and the average was 0.14g g–1 in the dried seaweeds.Generally, the gallium content in seaweeds had a close relationship to the aluminium and iron contents. The average weight ratio of Ga/Al was 3.8×10–4 and one of Ga/Fe was 4.0×10–4. The average Ga/Al weight ratio (3.8×10–4) was very similar to that reported for shallow-water deposits (2.1×10–4), but was definitely lower than that in sea water (1.5×10–2).  相似文献   
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The low-latitude hydrological cycle is a key climate parameter on different timescales, as it contributes to various feedback processes. Modelling studies suggest that the interhemispheric insolation contrast is the major factor controlling the cycle, although the influence of glacial conditions and the phase relationships relative to insolation forcing remain undetermined. In this work, we studied precipitation variability over Papua New Guinea (PNG, 3°S) for the past 400 ka using terrigenous fractions transported by the Sepik River to the Western Pacific Warm Pool (WPWP). A multi-decadal to centennial resolution of the elemental content was obtained using X-ray fluorescence scanning of a marine sediment core using an age model based on 14C dates and benthic foraminiferal δ18O. Indicators of the coarse river particulate fraction (bulk and CaCO3-free basis Ti concentrations, the log intensity ratios of Ti/K and Ti/Ca) displayed a dominant 23 ka periodicity without a clear glacial–interglacial trend. Our precipitation records showed a tight relationship with local summer insolation (3°S, January) with time-dependent lag of 0 to 4 ka. They were generally in anti-phase for U–Th dated Chinese speleothem δ18O records. Based on an analogy to modern climate, we propose that precipitation over PNG was primarily determined by interhemispheric insolation contrast, and the contribution of austral fall/winter precipitation added second-order variability that formed the lags. For the last four climate cycles, the WPWP hydrological cycle was closely associated with the eastern Asian monsoon, and the influence of glacial conditions on the low-latitude hydrological cycle was estimated to be limited.  相似文献   
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