Controls on the chemistry of runoff from an upland peat catchment     

Fred Worrall  Tim Burt  John Adamson 《水文研究》2003,17(10):2063-2083

This study uses 2 years of data from a detailed weekly water sampling programme in a 11·4 km² upland peat catchment in the Northern Pennines, UK. The sampling comprised precipitation, soil‐water samples and a number of streams, including the basin outlet. Samples were analysed for: pH, conductivity, alkalinity, Na, K, Ca, Mg, Fe, Al, Total N, SO₄, Cl and colour. Principal component analysis (PCA) was used to identify end‐members and compositional trends in order to identify controls on the development of water composition. The study showed that the direct use of PCA had several advantages over the use of end‐member mixing analysis (EMMA) as it combines an analysis of mixing and evolving waters without the assumption of having to know the compositional sources of the water. In its application to an upland peat catchment, the study supports the view that shallow throughflow at the catotelm/acrotelm boundary is responsible for storm runoff generation and shows that baseflow is controlled by cation exchange in the catotelm and mixing with a base‐rich groundwater. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Evolution of the Axial Geometry of the Southwest Indian Ocean Ridge between the Melville Fracture Zone and the Indian Ocean Triple Junction – Implications for Segmentation on Very Slow-Spreading Ridges     

Parson  Lindsay  Sauter  Daniel  Mendel  Véronique  Patriat  Philippe  Searle  Roger 《Marine Geophysical Researches》1997,19(6):535-552

Geophysical data from 900 km of the Southwest Indian Ridge are used todescribe the pattern of evolution of the plate boundary between 61° Eand 70° E over the past 20 million years. The SWIR is anobliquely-opening, ultra slow-spreading axis, and east of61° E comprises a series of ridge sections, each about 100–120 kmin length. The orientation of these sections varies fromsub-orthogonal to oblique to the approximately N–S spreadingdirection. In general, the suborthogonal sections are shallower, commonlysubdivided into an array of discrete axial segments, and carry recognisablecentral magnetic anomalies. The majority of the oblique sections are single,continuous rifts without continuous axial magnetic signatures.Morphotectonics of the Southwest Indian Ridge crust have not previously beenwell constrained off-axis, and we here present sidescan sonar andswath bathymetric data up to 100 km from the ridge to demonstrate the complexities of its spatial and temporal evolution.A model is proposed that the segmentation style correlates with analong-axis variation between: (a) relatively thick crustal sections which overlie mantle sections with higher magmatic supply created in orthogonally-spreading segments and (b) those oblique sections associated with cooler, magmatically-starved mantle and thinner crust. These latter sections are formed at broad offset zones in theplate boundary, more precisely defined on faster-spreading ridges asnontransform discontinuities. The nonsystematic pattern of crustalconstruction, extensional basin formation and the absence of extension-parallel traces of discontinuities off-axis suggest that the oblique spreading sections are not fixed in space or time.  相似文献   

Uptake and transformation of C-labelled tributyltin chloride by the dog-whelk, nucella lapillus: Importance of absorption from the diet     

G.W. Bryan  P.E. Gibbs  L.G. Hummerstone  G.R. Burt 《Marine environmental research》1989,28(1-4)

The importance of the diet as a source of tributyltin (TBT) in Nucella lapillus was studied using [¹⁴C]tributyltin chloride. In N. lapillus provided with prelabelled mussels, Mytilus edulis, in labelled water (mean 20·5 ng/litre TBT) the rate of accumulation of total ¹⁴C was 2–3 times that in unfed animals. Owing to its degradation in the tissues of both fed and unfed animals, concentrations of [¹⁴C]TBT tended to reach a plateau after only 28 days. However, total concentrations of ¹⁴C were still increasing after 49 days. Under experimental conditions (15°C, ample food, no disturbance) the diet accounted for about 50% of the body burden of TBT in N. lapillus after 49 days exposure: concentration factors (dry tissue/water) for [¹⁴C]TBT in both male and female N. lapillus were similar at about 60 000 in fed and 30 000 in unfed animals. It is concluded that the diet may contribute less than half of the body burden of TBT found in natural populations subjected to life-long exposure.  相似文献   

Factors influencing the oxidation,reduction, methylation and demethylation of mercury species in coastal waters     

Lindsay Whalin  Eun-Hee Kim  Robert Mason 《Marine Chemistry》2007

The objective of this study was to examine the redox reactions and other transformations of mercury (Hg) species in surface waters, and the factors determining the rates of these reactions. For the redox studies completed at the Chesapeake Biological Laboratory (CBL), two isotopes (¹⁹⁹Hg^II and ²⁰²Hg⁰) were added into different types of filtered water (fresh to seawater) to examine the oxidation and reduction reactions. Further studies of both the redox reactions and methylation/demethylation reactions of Hg were conducted with unfiltered water on board research vessels during cruises in May and July 2005 on the Chesapeake Bay and shelf. While CH₃¹⁹⁹Hg^II was added to allow the examination of demethylation, ²⁰¹Hg^II was used to examine both reduction and methylation, and ²⁰²Hg⁰ was used to examine oxidation. Overall, the results showed that both Hg oxidation and reduction were simultaneously occurring and were photochemically mediated in the waters investigated. In contrast to the previously assumed “unreactive” nature of Hg⁰, the studies found that the magnitude of the rate constant for Hg⁰ oxidation was greater than that for reduction, indicating its importance in estuarine and coastal waters. In addition, both experiments at CBL and on board ship showed that Hg^II reduction was similar in magnitude, suggesting that biotic processes were relatively unimportant. While no measurable methylation occurred during the incubation period during the on board studies, concentration of CH₃¹⁹⁹Hg^II decreased over the time during the experiments. It appeared that the demethylation processes were not dominantly photochemically driven, but could be microbially mediated. Further studies are needed in order to help better understand Hg redox and transformations in natural water systems.  相似文献   

Global fracture patterns of a despun planet: Application to Mercury     

J.Burt Pechmann  H.J. Melosh 《Icarus》1979,38(2):243-250

We have determined the global fracture patterns resulting from combinations of stresses due to tidal despinning and contraction or expansion. We find that Mercury's lineament pattern is consistent with a history of despinning and contraction. According to our model, the observed tectonic pattern implies that the despinning process reached completion before the planet ceased contracting. Our model predicts a stress due to contraction which is up to 1.8 times the maximum despinning stress on Mercury. The maximum contractional stress could be as large as 4 times the maximum despinning stress if the oldest fractures on the planet are N-S thrust faults in the equatorial region.  相似文献   

Effects of detailed soil spatial information on watershed modeling across different model scales     

Trevor Quinn  A.-Xing Zhu  James E. Burt   《International Journal of Applied Earth Observation and Geoinformation》2005,7(4):324-338

Hydro-ecological modelers often use spatial variation of soil information derived from conventional soil surveys in simulation of hydro-ecological processes over watersheds at mesoscale (10–100 km²). Conventional soil surveys are not designed to provide the same level of spatial detail as terrain and vegetation inputs derived from digital terrain analysis and remote sensing techniques. Soil property layers derived from conventional soil surveys are often incompatible with detailed terrain and remotely sensed data due to their difference in scales. The objective of this research is to examine the effect of scale incompatibility between soil information and the detailed digital terrain data and remotely sensed information by comparing simulations of watershed processes based on the conventional soil map and those simulations based on detailed soil information across different simulation scales. The detailed soil spatial information was derived using a GIS (geographical information system), expert knowledge, and fuzzy logic based predictive mapping approach (Soil Land Inference Model, SoLIM). The Regional Hydro-Ecological Simulation System (RHESSys) is used to simulate two watershed processes: net photosynthesis and stream flow. The difference between simulation based on the conventional soil map and that based on the detailed predictive soil map at a given simulation scale is perceived to be the effect of scale incompatibility between conventional soil data and the rest of the (more detailed) data layers at that scale. Two modeling approaches were taken in this study: the lumped parameter approach and the distributed parameter approach. The results over two small watersheds indicate that the effect does not necessarily always increase or decrease as the simulation scale becomes finer or coarser. For a given watershed there seems to be a fixed scale at which the effect is consistently low for the simulated processes with both the lumped parameter approach and the distributed parameter approach.  相似文献   

The last British Ice Sheet: growth, maximum extent and deglaciation   总被引：2，自引：0，他引：2  

Lindsay J. Wilson  William E. N. Austin  Eystein Jansen 《Polar research》2002,21(2):243-250

The growth, maximum lateral extent and deglaciation of the last British Ice Sheet (BIS) has been reconstructed using sediment, faunal and stable isotope methods from a sedimentary record recovered from the Barra Fan, north-west Scotland. During a phase of ice sheet expansion postdating the early "warmth" of Marine Isotope Stage 3 (MIS 3), ice rafting events, operating with a cyclicity of approximately 1500 years, are interspersed between warm, carbonate-rich interstadials operating with a strong Dansgaard-Oeschger (D-O) cyclicity. The data suggest that the BIS expanded westwards to the outer continental shelf break shortly after 30 Ky BP (before present) and remained there until about 15 Ky BP. Within MIS 2, as the ice sheet grew to its maximum extent, the pronounced periodicities which characterize MIS 3 are lost from the record. The exact timing of the Last Glacial Maximum is difficult to define in this record; but maxima in Neogloboquadrina pachyderma (sinistral) ع⁸O are observed between 21-17 Ky BP. A massive discharge of ice-rafted detritus, coincident with Heinrich event 1, is observed at about 16 Ky BP. Deglaciation of the margin is complete by about 15 Ky BP and surface waters warm rapidly after this date.  相似文献   

U–Pb zircon chronostratigraphy of early-Pliocene ignimbrites from La Pacana, north Chile: implications for the formation of stratified magma chambers     

Axel K Schmitt  Jan M Lindsay  Shan de Silva  Robert B Trumbull 《Journal of Volcanology and Geothermal Research》2003,120(1-2):43-53

High spatial resolution U–Pb dates of zircons from two consanguineous ignimbrites of contrasting composition, the high-silica rhyolitic Toconao and the overlying dacitic Atana ignimbrites, erupted from La Pacana caldera, north Chile, are presented in this study. Zircons from Atana and Toconao pumice clasts yield apparent ²³⁸U/²⁰⁶Pb ages of 4.11±0.20 Ma and 4.65±0.13 Ma (2σ), respectively. These data combined with previously published geochemical and stratigraphic data, reveal that the two ignimbrites were erupted from a stratified magma chamber. The Atana zircon U–Pb ages closely agree with the eruption age of Atana previously determined by K–Ar dating (4.0±0.1 Ma) and do not support long (>1 Ma) residence times. Xenocrystic zircons were found only in the Toconao bulk ignimbrite, which were probably entrained during eruption and transport. Apparent ²³⁸U/²⁰⁶Pb zircon ages of 13 Ma in these xenocrysts provide the first evidence that the onset of felsic magmatism within the Altiplano–Puna ignimbrite province occurred approximately 3 Myr earlier than previously documented.  相似文献   

Predicting the future DOC flux from upland peat catchments   总被引：6，自引：0，他引：6  

Fred Worrall  Tim Burt 《Journal of Hydrology》2005,300(1-4):126-139

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Longleaf Pine (Pinus palustris Mill.) Morphology and Climate/Growth Responses Along a Physiographic Gradient in North Carolina     

Thomas W. Patterson  Lindsay W. Cummings  Paul A. Knapp 《The Professional geographer》2016,68(2):238-248

Geographic differences in tree morphology and climate and growth responses of longleaf pine have been documented, yet how these differences vary at a larger scale has not. In this study, we documented changes in tree morphology and climate and radial growth responses of six longleaf pine (Pinus palustris Mill.) stands in three physiographic regions in North Carolina. We sampled from more than fifteen trees per stand and compared site- and regional-level total and latewood ring width values to temperature, precipitation, and drought. All morphological characteristics expressed a strong west–east gradient. Climate and radial growth response was strongest for the Sandhills region and then Piedmont and Coastal Plain regions. The distinct morphological characteristic gradient did not covary with climate and radial growth response, suggesting that additional environmental influences affect needle length, trunk diameter, and height.  相似文献