Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

2060 Chiron back to a minimum of brightness     

Daniela Lazzaro  Marcos A. Florczak  Alberto Betzler  Othon C. Winter  Silvia M. Giuliatti-Winter  Claudia A. Angeli  Dietmar W. Foryta 《Planetary and Space Science》1996,44(12):1547-1550

The results of photometric observations of comet/asteroid 2060 Chiron at the Observatório do Pico dos Dias (Brazil-OPD) and the Observatoire de Haute-Provence (France-OHP) during 1994 and 1995 are presented. The analysis of the data shows a decrease of 2060 Chiron brightness from its peak values of 1988–1991. The absolute magnitude, H_v, varies from a maximum of 6.6 in February 1994 up to a minimum of 6.8 in June 1995. Therefore 2060 Chiron is back to a minimum of activity close to that of 1983–1985. The slope parameter G is found to be G = 0.71 ± 0.15. It is suggested that the H-G magnitude system, generally adopted to present 2060 Chiron brightness, is not the most appropriate due to the cometary activity of this object.  相似文献   

Preface to tropical coastal sedimentary environments     

Chuck Nittrouer  Alberto Figueiredo 《Geo-Marine Letters》1996,16(1):1-2

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Merging of low-mass systems and the origin of the fundamental plane     

E.A. Evstigneeva  R.R. de Carvalho  A.L. Ribeiro  H.V. Capelato 《Astrophysics and Space Science》2003,284(2):487-490

We present the preliminary results of a study of how small stellar systems merge to form larger ones. As we display the families of galaxies in the μ_e - R_e plane (effective surface brightness versus effective radius) we realize that different morphological types occupy different loci, evidencing the different physical mechanisms operating in each family. As proposed by Capaccioli et al. (1992) this diagram is the logical equivalent of the HR diagram for stars. Here we take some initial steps in understanding of how we can establish the evolutionary tracks, solely due to dynamical processes, in the μ_e - R_e plane, ultimately making a dwarf elliptical to turn into a normal elliptical galaxy. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Quantitative methods in the earth sciences     

A. F?rster  D. F. Merriarn 《Mathematical Geology》1997,29(5):727

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The Auger Observatory in Argentina     

Alberto Etchegoyen 《Astrophysics and Space Science》2004,290(3-4):379-387

The Auger Project studies the highest energies known in nature with an emphasis on energies ≥5 × 10¹⁹ eV, which are cosmic rays coming from the outer space reaching the Earth's surface with a very low flux. The questions to be elucidated are what are the origin, energy, production mechanism, and chemical composition of these cosmic rays. Auger aims at building two observatories in both the hemispheres and in 2000 the construction of the austral observatory started. Auger's two distinctive features are its exceptional size and its hybrid nature. It spans over an area of 3000 km² and is constituted by 24 fluorescence detector telescopes and 1600 surface detectors. As such, it will provide a large number of events with less systematic detection uncertainties. The construction of the Southern Observatory in Argentina is quite advanced and the buildings at the Central Station in Malargüe city are already operational. So are the telescope buildings at Cerros Los Leones and Coihueco (two prototype telescopes were operational at Los Leones, which have now been dismantled), 32 surface detectors, and the telecommunication and data acquisition systems. About 20-hybrid events/months were detected and currently two events/hours are registered with the surface detector array. The detection of hybrid events is the most important issue since it shows that the equipment operates within the design parameters.  相似文献   

Opposition polarimetry and photometry of S- and E-type asteroids     

Irina N Belskaya  Vasilij G Shevchenko  Yurij N Krugly  Yurij S Efimov  Alberto Cellino 《Icarus》2003,166(2):276-284

The first results of the observational program devoted to simultaneous investigation of asteroid polarimetric and photometric opposition phenomena are presented. UBVRI polarimetric and V-band photometric observations of the S-type Asteroid 20 Massalia and the E-type Asteroids 214 Aschera and 620 Drakonia were carried out in 1996-1999 down to phase angles of 0.08°, 0.7°, and 1.2°, correspondingly. The S-type Asteroid 20 Massalia is characterized by the pronounced brightness opposition surge with an amplitude larger than that observed for the E-type asteroids. A sharp peak of negative polarization at small phase angles was not observed for this asteroid. The value of polarization degree at phase angle α<1° is less than 0.5% for both S and E types. The negative polarization branches of S and especially E-asteroids have an asymmetrical shape. The phase angle at which the polarization minimum occurs is close to the angle at which non-linear increase begins in the asteroid magnitude phase curves. A relation of the observed effects to the mechanism of coherent backscattering is discussed.  相似文献   

Building blocks in hierarchical clustering scenarios and their connection with damped Lyα systems     

Sofía A. Cora  Patricia B. Tissera †  Diego G. Lambas ‡  Mirta B. Mosconi 《Monthly notices of the Royal Astronomical Society》2003,343(3):959-970

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Testing the consistency of the Starburst scenario for active galactic nuclei     

María Luisa García Vargas  Angeles Díaz  Roberto Terlevich  Elena Terlevich 《Astrophysics and Space Science》1993,205(1):77-84

In the frame of the Starburst Model, we show that the evolution of a massive stellar cluster in a high metallicity environment can reproduce the observed emission-line spectrum and the UV-optical Spectral Energy Distribution of the Seyfert 2 galaxies and LINERs. We apply the results of our models to three objects: NGC 5506, NGC 5643 and Mk 348.  相似文献   

Chemical Enrichment of the Intra-Cluster Medium     

SofÍa A. Cora  Simon D.M. White 《Astrophysics and Space Science》2003,284(2):425-428

We investigate the metal enrichment of the intra-cluster medium by using a method that combines N-Body simulations and a semi-analytic model (SAM) of galaxy formation. The cluster of galaxies is simulated in a flat, low density universe, with a numerical resolution that allows the detection of substructures in the dark matter background of the cluster. The phenomenological approach used to model the physical processes involved in the galaxy formation and metal production is applied to the substructures found in the dark matter halos detected at different redshifts. Details of the chemical implementation in the SAM and first results related to the mean properties of the baryonic matter components are presented. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献