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Black shales of the late Neoproterozoic Gwna Group (570–580 Ma), UK, contain enrichments of tellurium (Te), selenium (Se) and cobalt (Co) relative to average shale compositions. The Te and Co enrichments bear comparison with those of ferromanganese crusts in the modern deep ocean. Gwna Group deposition coincides with the Second Great Oxidation Event, which had a significant effect on trace element fixation globally. Selenium and Te concentrations within these black shales indicate increased continental weathering rates, high biological productivity and corresponding increases in atmospheric O2 concentrations. Cobalt, nickel (Ni) and arsenic (As) enrichments in this succession are secondary mineralisation phases. Demand for many of the trace elements found enriched in the Gwna Group black shales make their mechanisms of accumulation, and variations through the geological record, important to understand, and suggests that new resources may be sought based on black shale protoliths from this period.  相似文献   
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Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca10(PO4)6(F,Cl,OH)2 solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for 37Cl/35Cl homogeneity using SIMS followed by δ37Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean 37Cl/35Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ37ClSMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 103δ37ClSMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25.  相似文献   
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Based upon a re-interpretation of previous data and a new field campaign, a structural evolution is proposed for the early history of Piton de la Fournaise volcano from 500,000 to 50,000 years. Conceptually, it is shown that the formation of a caldera in which lava flows are contained inside the caldera depression, gives time for erosion to excavate deep canyons on the external slopes of the volcano, for example, the Rivière des Remparts, the Rivière Langevin and the Rivière de l'Est canyons on Piton de la Fournaise volcano. These canyons are infilled when lavas, filling the caldera and overflowing its rim, are able again to flow on the external slopes of the volcano. In the past, this excavating/infilling process has occurred twice following the formation of the Rivière des Remparts and Morne Langevin calderas. The formation of the third caldera, the Plaine des Sables caldera, was followed by the excavation of the current canyons. In addition to this process, two large landslides have been documented in the field. The first, which happened about 300,000 years ago, is apparently the first episode of the break up of Piton de la Fournaise volcano, predating the formation of the four large calderas. The second landslide, which occurred 150,000 years ago and is considered to be less extensive, has carried away the entire southern flank of the Rivière des Remparts caldera.  相似文献   
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Closed-form expressions are obtained to calculate the approximate complex eigenvalues and eigenvectors of a system composed of a non-classically damped primary structure and a single degree of freedom oscillator. The expressions are obtained through a systematic second order perturbation analysis of a transformed eigenvalue problem of the combined system. The possibility of tuning between the structure and equipment is considered. The dynamic properties of the combined system are derived in terms of the complex eigenvalues and eigenvectors of the supporting structure and the frequency, mass and damping ratio of the equipment. Examples demonstrating the accuracy of the expressions for the eigenvalues and eigenvectors are presented. These eigenproperties are used for generation of floor response spectra for non-classically damped structures to incorporate the dynamic interaction effects between the structure and equipment.  相似文献   
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A morphometric study of 61 sub-basins of the River Segura basin (SE Spain) enables us to attribute ecological processes in streams of these arid and semiarid watersheds to altered patterns of discharge resulting from human activity. Methods used are compared to other, commonly used limnological indexes.  相似文献   
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Data of trace element composition of phosphorites are scarce and incomplete. Phosphorites of different origins can vary substantially in trace element contents. In this paper 20 trace element concentrations of 35 sample phosphorites are reported. The geographical provenance is: Bayovar-Sechura (Peru), Khouribga, Youssoufia and Boucraa (Morocco), Gafsa (Tunisia), Florida (USA), Idaho and Phosphoria Formation (USA), North Carolina (USA), Algeria, Israel, Senegal, Syria and Togo. Aqua regia extracts were used to estimate the “pseudototal” values, following standard procedures (ISO 11466, 2002) and measured by ICP-AES and ICP-MS.  相似文献   
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