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L. Melluso P. Censi G. Perini L. Vasconcelos V. Morra F. Guerreiro L. Bennio 《Mineralogy and Petrology》2004,80(3-4):201-213
Summary The Xiluvo complex of central Mozambique is made up of coarse- to fine-grained calciocarbonatites (sövites and alvikites), heavily altered lamprophyres and syenitic rocks that intruded the Precambrian basement ca. 120Ma ago. The carbonatites have fractionated rare earth element patterns (chondrite-normalized La/Yb=30–80) and markedly negative Rb, K, P, Zr and Ti anomalies in mantle-normalized incompatible element diagrams. The 18O (+7 to +8), 13C (–5), and the age-corrected 87Sr/86Sr (0.7032–0.7033) and 143Nd/144Nd (0.51263–0.51262) indicate an origin in the mantle. A few carbonatitic samples have higher 18O (+13), indicating interaction with high-18O crust or late-stage fluids. The chemical and isotopic compositions of the Xiluvo carbonatites and nearby carbonatites of similar age in Malawi indicate very similar sources, characterized by time-integrated depletion of Rb with respect to Sr and of Sm with respect to Nd. These characteristics point to a source similar in many respects to those of other East African carbonatites and to those of some ocean island basalts, with the additional influx of components possibly located in the African lithospheric mantle. 相似文献
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Sandro Conticelli Riccardo Avanzinelli Sara Marchionni Simone Tommasini Leone Melluso 《Mineralogy and Petrology》2011,103(1-4):123-148
The Radicofani Volcano is characterised by few lava flows, a cinder cone and a denudated neck, and is part of the Tuscan Magmatic Province, the northernmost volcanic region of the Italian peninsula. In spite of the short time span of activity, a large time-dependant chemical and isotopic variability is observed. Most of the rocks of the Radicofani volcano are ultrapotassic shoshonites associated to younger basaltic andesites, found at the bottom of the neck. K2O contents are positively correlated with trace element and isotopic variations. Shoshonitic and high-K calc-alkaline rocks of the Radicofani volcano are significantly different from shoshonites occurring in association with leucite-bearing ultrapotassic rocks in the southernmost portion of the Roman Magmatic Province. The studied rocks are characterised by high, but variable, levels of incompatible trace elements with a subduction-related signature, with troughs at Ba, Ta, Nb, and Ti, and peaks at Cs, K, Th, U, and Pb. Initial values of 87Sr/86Sr range from 0.71333 to 0.71588, 143Nd/144Nd ranges from 0.512050 to 0.512183, while the lead isotope ratios vary between 18.672 and 18.716 for 206Pb/204Pb, 15.665 to 15.696 for 207Pb/204Pb, and 39.981 to 39.081 for 208Pb/204Pb. Ultrapotassic shoshonites show the highest incompatible trace element contents coupled with the highest 87Sr/86Sr and the lowest 143Nd/144Nd. On the basis of geochemical and isotopic signatures it is argued that magmas were generated in a modified lithospheric peridotitic source containing metasomatic veins generated by K-rich melts from recycled sediments within the mantle via subduction. A further metasomatic event generated by slab-derived fluids pervasively enriched the peridotitic source. Partial melting of the veins produced leucite-free ultrapotassic magmas (i.e. lamproite), and was triggered by rising of the isotherms after the orogenic front migrated eastward in the Italian Peninsula. Further rise of the isotherms induced larger degrees of partial melting inducing melting of the surrounding wall peridotite. The variation of the degree of partial melting of such a heterogeneous peridotitic source produced a wide spectrum of magma compositions, which mimic a mixing line between two components: ultrapotassic magma from partial melting of the metasomatic vein and a basaltic andesitic magma from partial melting of the surrounding peridotite. 相似文献
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Vincenza Guarino Rogério Guitarrari Azzone Pietro Brotzu Celso de Barros Gomes Leone Melluso Lucio Morbidelli Excelso Ruberti Colombo Celso Gaeta Tassinari Mauro Brilli 《Mineralogy and Petrology》2012,104(1-2):43-61
The Ipanema alkaline-carbonatitic complex is part of the Meso-Cenozoic alkaline magmatism located within the southeastern part of the Brazilian Platform. Drill-core and field sampling have indicated the occurrence of glimmerites, with subordinate shonkinites (mela-syenites), clinopyroxene-bearing glimmerites, diorites and syenites. The glimmerites are cross-cut by lamprophyric dykes and calciocarbonatites. Fenitization has deeply affected the country rocks, originating dioritic and syenitic rocks. The Ipanema rocks show a distinct potassic affinity. The initial Sr-Nd- isotopic composition of the Ipanema rocks (87Sr/86Sr?=?0.70661–0.70754 and 143Nd/144Nd?=?0.51169–0.51181) is similar to that of tholeiitic and potassium-rich-alkaline rocks of the Eastern Paraguay. Stable isotope data for the Ipanema calciocarbonatite suggest interaction with fluids at temperatures typical of hydrothermal stages, as hypothesized for other carbonatite complexes from southeastern Brazil. The chemical differences between the lamprophyre, glimmerites, carbonatites, apatitites and magnetitites, and the absence of marked REE enrichment in the evolved lithologies, all indicate that fractional crystallization and accumulus of liquidus phases in a magma reservoir, likely coupled with liquid immiscibility processes, may have played an important role in the genesis of the Ipanema rocks. 相似文献
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Lorenzo Fedele Claudio Scarpati Marvin Lanphere Leone Melluso Vincenzo Morra Annamaria Perrotta Gennaro Ricci 《Bulletin of Volcanology》2008,70(10):1189-1219
The Breccia Museo is one of the most debated volcanic formations of the Campi Flegrei volcanic district. The deposit, made
up of six distinctive stratigraphic units, has been interpreted by some as the proximal facies of the major caldera-forming
Campanian Ignimbrite eruption, and by others as the product of several, more recent, independent and localized events. New
geochemical and chemostratigraphical data and Ar–Ar age determinations for several units of the Breccia Museo deposits (~39 ka),
correlate well with the Campanian Ignimbrite-forming eruption. The chemical zoning of the Breccia Museo deposits is interpreted
here to be a consequence of a three-stage event that tapped a vertically zoned trachytic magma chamber.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
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Summary New data of mineral compositions, whole-rock major and trace element contents are presented for lava flows and dykes of Mt. Vulture volcano (southeastern Roman Magmatic Province). The dominant rock series ranges from basanite, through tephrite and foidite, to phonolite. Diopsidic to Fe-salitic (hedenbergitic) clinopyroxene is the major phenocryst phase, and shows a very strong Ti- and Al-enrichment trend (up to 5 wt% TiO2 and 12 wt% Al2O3). Phonolites have Fe-rich pyroxenes low in Ti and Al, as a consequence of fractionation of Ti-magnetite and/or melanite garnet.Feldspar ranges in composition from bytownite to Ba- and Sr-rich anorthoclase (up to 7 wt % BaO and 4 wt % SrO); the latter is present in the groundmass of mafic and intermediate rocks. Phonolites are characterized by anorthoclase and sanidine with Ba-rich cores, and with Ba-depleted rims.Subordinate melilite-bearing rocks are also present, and are characterized by melilite with a very large compositional variation, Ca-rich nepheline (up to 8 wt% CaO) and lack of feldspar and amphibole. Some of them also show calcite-rich ocellar structures, possibly due to liquid immiscibility. They have also major and trace element contents different from those of the feldspar-bearing rocks. This all indicates distinct parental magmas for feldspar-bearing and melilite-bearing rocks. These latter were likely generated by differentiation processes starting from olivine- and melilite-bearing ultramafic parental magmas.Mineral compositions and suitable phase diagrams indicate that the Melfi haüynophyre, which is the most MgO-poor melilite-bearing rock of Mt. Vulture, is close to a residual melt analogous to phonolite, but in petrogenetic systems with melilite and without feldspar.The high- to very high-titanium content of most of the ferromagnesian phases, despite a relatively low TiO2 of primitive Mt. Vulture rocks, is absent in other rocks of similar degree of evolution in the Roman Province. It resembles that found in anorogenic magmas and gives further indications for a within-plate signature in this particular volcanic complex.
With 7 Figures 相似文献
Der Mt. Vulture Vulkankomplex (Italien): hinweise für unterschiedliche Ausgangsmagmen und Residualschmelzen mit Melilith
Zusammenfassung Es werden neue Daten über Mineralzusammensetzungen sowie Haupt- und Spurenelemente des Gesamtgesteins für Lavaflüsse und Gänge des Mt. Vulture Vulkans (südöstliche Römische Magmatische Provinz) vorgestellt. Die auftretenden Gesteinsabfolgen reichen von Basaniten über Tephrite und Foidite zu Phonolithen. Diopsidischer bis Fe-salitischer (hedenbergitischer) Klinopyroxen stellt die hauptsächlichen Einsprenglinge und zeigt starke Ti- und Al-Anreicherungen (bis zu 5 Gew% TiO2 und 12 Gew% Al2O3). Phonolite weisen als Konsequenz der Fraktionierung von Ti-Magnetit und/oder Melanit-Granat Fe-reiche Pyroxene mit niedrigen Ti- und Al-Gehalten auf.Der Feldspat reicht in seiner Zusammensetzung von Bytownit zu Ba- und Si-reichem Anorthoklas (bis zu 7 Gew%/o BaO und 4 Gew% SrO), der letztgenannte findet sich in der Grundmasse mafischer und intermediärer Gesteine. Phonolithe werden durch das Auftreten von Anorthoklas und Sanidin mit Ba-angereicherten Kernen und Ba-abgereicherten Rändern charakterisiert.Untergeordnet treten auch Melilith-führende Gesteine auf. Sie sind durch Melilithe mit einer großen kompositionellen Variation, durch Ca-reichen Nephelin (bis 8Gew% CaO) und durch das Fehlen von Feldspat und Amphibol gekennzeichnet. Einige dieser Melilithe zeigen auch Calcitreiche ocellare Strukturen, die möglicherweise aufgrund der Nicht-Mischbarkeit der Schmelzen entstanden sind. Sie weisen auch Gehalte an Haupt- und Spurenelementen auf, die von jenen Feldspat-führender Gesteine abweichen. All dies zeigt verschiedene Ausgangs-Magmen für Feldspat-führende und Melilith-führende vulkanische Gesteinean. Die Melilithgesteine entstanden wahrscheinlich durch Differentiationsprozesse aus Olvin- und Melilith-führenden ultramafischen Magmen.Mineralzusammensetzung und die entsprechenden Phasendiagramme zeigen, daß der Melfi Haüynophyr, welcher das MgOärmste Melilith-führende Gestein des Mt. Vulture ist, nahe an einer Ausgangschmelze analog zu einem Phonolith liegt, allerdings in einem petrogenetischen System mit Melilith und ohne Feldspat.Der hohe bis sehr hohe Titan-Gehalt der meisten ferromagnesischen Phasen fehlt, trotz des niedrigen TiO2-Gehaltes primitiver Mte. Vulture Gesteine, in anderen Gesteinen ähnlicher Entwicklung in der Römischer Magmatischen Provinz. Dies ähnelt anorogenen alkalischen Magmen und ist ein weiterer Hinweis auf eine Intra-Platten Signatur für diesen besonderen vulkanischen Komplex.
With 7 Figures 相似文献
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Composition of chromiferous spinel included in olivines of Mg-rich basalts and gabbros of the Deccan Traps (Gujarat and Western Ghats) are reported here. They vary from Al-rich compositions [Al2O3 = 53wt.%; Cr#, 100Cr/(Cr + Al) = 12] to Cr-rich compositions [Cr2O3 = 51wt.%; Cr# = 84], and from Cr-Al rich compositions towards Cr-rich Ti-magnetite (TiO2 up to 23 wt.%, ulvöspinel up to 67mol.%). The Mg# [100Mg/(Mg + Fe2+)] of spinel decreases from 81 to nearly zero. The highest Cr# has been found in the Bushe Fm., Thakurvadi Fm., and some high-Ti basalts of the Pavagadh section, whereas some of the low-Ti basalts of Saurashtra have Al-rich compositions typical of spinels found in mid-ocean ridge basalts. The chemical composition of the Deccan Trap spinels is completely different compared to that observed in mantle spinel suites, with very few exceptions. The decreasing Al and increasing Fe and Ti of spinel seems to be mainly the result of decrease of Mg in the locally coexisting melts and favourable cationic substitutions in the lattice. There is barely any evidence of general relationships between the composition of the Deccan spinels and inferred mantle sources of the host magmas. Pyroxene inclusions in spinels may witness a high-pressure stage of crystallization, but the possibility of non-equilibrium crystallization, or even magma mixing, cannot be ruled out. Overall, the compositional ranges of chromiferous spinel in the Deccan Traps closely match those observed in the other Large Igneous Provinces having mafic/ultramafic intrusions and mafic magma compositions (e.g., Siberian Traps, Karoo, Emeishan). 相似文献
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L. Beccaluva M. Coltorti P. Di Girolamo L. Melluso L. Milani V. Morra F. Siena 《Mineralogy and Petrology》2002,74(2-4):277-297
Summary The Late Pleistocene Mt. Vulture strato-volcano developed at the intersection of NE-SW and NW-SE lithospheric fault systems,
on the easternmost border of the Apennine compressional front overthrust onto the Apulian foreland. The initial phase of the
volcanic activity is represented by pyroclastic deposits, including lava blocks, and subordinate eccentric domes, mostly phonolitic
in composition. The later stages of activity formed the bulk of the strato-volcano (pyroclastic products and subordinate lavas),
mostly tephritic in composition, with minor intercalations of basanite, mela-foidite and melilitite lavas and dikes.
Variations in rock and mineral composition suggest that the volumetrically predominant basanite-tephrite (foidite)-phonotephrite-phonolite
series can be accounted for by fractional crystallization processes starting from basanitic parental magmas, in agreement
with the remarkably constant 87Sr/86Sr isotopes (0.70586–0.70581). Mass-balance calculations indicate that the variably differentiated magmas may have been produced
by removal of wehrlite, clinopyroxenite and syenite cumulates, some of which are occasionally found as cognate xenoliths in
the volcanics. Fractionation processes probably developed in multiple-zoned magma chambers, at depths of 3–5 km, corresponding
to the tectonic discontinuity between the allochthonous Apennine formations and the underlying Apulian platform. Highly differentiated
phonolitic magmas capping the magma chambers and their conduits thus appear to have fed the initial volcanic activity, whereas
dominantly tephritic products were erupted in later stages.
The least evolved mafic magmas, namely basanites, mela-foidites and melilitites, are characterized by diverse Na/K ratios
and critical SiO2-undersaturation, which indicate their derivation as independent melts generated from distinct, heterogeneously enriched mantle
sources and by variable partial melting degrees.
Primitive mantle-normalized incompatible element patterns of Vulture mafic lavas invariably share analogies with both orogenic
subduction-related magmas (high Low Field Strength Elements/High Field Strength Elements ratios, K, Rb and Th contents and
marked Ti and Nb negative anomalies) and alkaline lavas from within-plate and rift settings (high Light Rare Earth Elements,
P, Zr, Nb and Na). These geochemical features may be accounted for by magma generation from deep lithospheric mantle sources,
enriched in Na-alkali silicate/carbonatite anorogenic components, subsequently affected by orogenic subduction-related K-metasomatism,
analogous to that which modified magma sources of the Roman Magmatic Province along the internal Apennine Chain.
Received April 12, 2000; revised version accepted June 7, 2001 相似文献
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Guarino Vincenza Wu Fu-Yuan Melluso Leone de Barros Gomes Celso Tassinari Colombo Celso Gaeta Ruberti Excelso Brilli Mauro 《International Journal of Earth Sciences》2017,106(6):1963-1989
International Journal of Earth Sciences - The Catalão II carbonatitic complex is part of the Alto Paranaíba Igneous Province (APIP), central Brazil, close to the Catalão I complex.... 相似文献