Annual variation of methane in seawater in Funka bay,Japan     

Shuichi Watanabe  Naoto Higashitani  Nobuo Tsurushima  Shizuo Tsunogai 《Journal of Oceanography》1994,50(4):415-421

The concentration of methane in seawater was determined approximately once a month for one year from August 1990 to July 1991 at a station close to the center of Funka bay (92 m depth) and some supplementary observations were also carried out. The concentration of methane was usually increased with increasing depth, suggesting that methane was emitted from the bottom of the bay. While highly variable both spatially and temporally, the emission was intense in March and April, a period immediately after the spring bloom of phytoplankton. The maximum of methane found in the intermediate water suggests its source from the slope of the bay. The concentration of methane in the surface water changed seasonally and also interannually. The annually averaged flux of methane transferred to the atmosphere in the bay was estimated to be 6×10^–3 gCH₄m²/day. The coastal zone in the world may be a significant source of the atmospheric methane, although its source strength has yet to be accurately estimated from more data in different coastal seas.  相似文献   

Influence of Mesoscale Eddies on Variations of the Kuroshio Path South of Japan     

Naoto Ebuchi  Kimio Hanawa 《Journal of Oceanography》2003,59(1):25-36

The influences of mesoscale eddies on variations of the Kuroshio path south of Japan have been investigated using time series of the Kuroshio axis location and altimeter-derived sea surface height maps for a period of seven years from 1993 to 1999, when the Kuroshio followed its non-large meander path. It was found that both the cyclonic and anticyclonic eddies may interact with the Kuroshio and trigger short-term meanders of the Kuroshio path, although not all eddies that approached or collided with the Kuroshio formed meanders. An anticyclonic eddy that revolves clockwise in a region south of Shikoku and Cape Shionomisaki with a period of about 5–6 months was found to propagate westward along about 30°N and collide with the Kuroshio in the east of Kyushu or south of Shikoku. This collision sometimes triggers meanders which propagate over the whole region south of Japan. The eddy was advected downstream, generating a meander on the downstream side to the east of Cape Shionomisaki. After the eddy passed Cape Shionomisaki, it detached from the Kuroshio and started to move westward again. Sometimes the eddy merges with other anticyclonic eddies traveling from the east. Coalescence of cyclonic eddies, which are also generated in the Kuroshio Extension region and propagate westward in the Kuroshio recirculation region south of Japan, into the Kuroshio in the east of Kyushu, also triggers meanders which mainly propagate only in a region west of Cape Shionomisaki. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Detecting fluctuations of the Kuroshio axis south of Japan using TOPEX/POSEIDON altimeter data   总被引：1，自引：0，他引：1  

Shiro Imawaki  Mayumi Gotoh  Hiroyuki Yoritaka  Noriya Yoshioka  Atsunobu Misumi 《Journal of Oceanography》1996,52(1):69-92

Sea surface dynamic topography (SSDT) can be divided into temporal mean SSDT and fluctuation SSDT. The former is approximated with a climatological mean SSDT and the latter is derived from satellite altimetry data, to give an approximated total SSDT (called a composite SSDT). The method is applied to detecting fluctuations of the Kuroshio axis south of Japan using TOPEX/POSEIDON altimeter data from the first year mission in 1992–1993. The fluctuation SSDT averaged over a wide area south of Japan clearly shows an annual cycle with an amplitude of about 15 cm. Temporal changes of SSDT along a subsatellite track crossing the Kuroshio compare moderately well with those estimated from repeated hydrographic observations, although there is a discrepancy of unknown origin. The composite SSDT also compares well with SSDT estimated from the same hydrographic data. Horizontal distribution of the surface geostrophic velocity component normal to subsatellite tracks is derived every ten days from the composite SSDT. Most locations of estimated strong eastward geostrophic velocities coincide well with locations of the Kuroshio axis determined every 15 days fromin situ surface velocity measurements on various vessels; for example, a fairly large meander of the Kuroshio south of Honshu is clearly detected. It is concluded that the composite SSDT can be used reliably to detect fluctuations of the Kuroshio axis south of Japan.  相似文献   

Seasonal and interannual variations in the East Sakhalin current revealed by TOPEX/POSEIDON altimeter data     

Naoto Ebuchi 《Journal of Oceanography》2006,62(2):171-183

Seasonal and interannual variations in the East Sakhalin Current (ESC) are investigated using ten-year records of the sea level anomaly (SLA) observed by the TOPEX/POSEIDON (T/P) altimeter. The T/P SLA clearly documents seasonal and interannual variations in the ESC along the east coast of Sakhalin Island, although sea ice masks the region from January to April. Estimates of surface current velocity anomaly derived from T/P SLA are in good agreement with drifting buoy observations. The ESC is strong in winter, with a typical current velocity of 30–40 cm s⁻¹ in December, and almost disappears in summer. Southward flow of the ESC is confined to the shelf and slope region and consists of two velocity cores. These features of the ESC are consistent with short-term observations reported in previous studies. Analysis of the ten-year records of T/P SLA confirms that the structure of the ESC is maintained each winter and the seasonal cycle is repeated every year, although the strength of the ESC shows large interannual variations. Seasonal and interannual variations in the ESC are discussed in relation to wind-driven circulation in the Sea of Okhotsk, using wind stress and wind stress curl fields derived from European Centre for Medium Range Weather Forecasts (ECMWF) reanalysis data and a scatterometer-derived wind product. Seasonal and interannual variations of the anticyclonic eddy in the Kuril Basin are also revealed using T/P SLA.  相似文献   

A laboratory experiment to monitor the contact state of a fault by transmission waves   总被引：1，自引：0，他引：1  

Naoto Yoshioka  Koji Iwasa 《Tectonophysics》2006,413(3-4):221-238

We performed a series of laboratory experiments in which elastic waves were transmitted across a simulated fault. Two types of experiments were carried out: (1) Normal Stress Holding Test (NSHT): normal stress was kept constant for about 3 h without shear stress and transmission waves were observed. (2) Shear Stress Increasing Test (SSIT): shear stress was gradually increased until a stick-slip event occurred. Transmission waves were continuously observed throughout the process of stress accumulation. We focused on the change in transmission waves during the application of shear stress and especially during precursory slips.It was found in NSHT that the amplitude of transmission waves linearly increased with the logarithm of stationary contact time. The increase amounted to a few percent after about 3 h. Creep at asperity contacts is responsible for this phenomenon. From a theoretical consideration, it was concluded that the real contact area increased with the logarithm of stationary contact time.We observed in SSIT a significant increase in wave amplitude with shear stress application. This phenomenon cannot be attributed to the time effect observed in NSHT. Instead, it can be explained by the mechanism of “junction growth” proposed by Tabor. Junction growth yields an increase in real contact area. It is required for junction growth to occur that the material in contact is already plastic under a purely normal loading condition. A computer simulation confirmed that this requirement was satisfied in our experiments. We also found that the rate at which the amplitude increased was slightly reduced prior to a stick-slip event. The onset time of the reduction well coincides with the onset of precursory slip. The cause of the reduction is attributed to the reset of stationary contact time due to displacement. This interpretation is supported by the result of NSHT. Taking the time of stationary contact in SSIT into account, we may expect the change in wave amplitude to be, at most, only a few percent. The observed slight reduction in increasing rate is, in this sense, reasonable. The static stiffness of the fault also decreases with precursory slip. It was also found that low frequency waves are a better indicator of precursory slip than high frequency waves. This might suggest that low frequency waves with longer wavelength are a better indicator of average behavior of faults. The problem, however, merits a further investigation. The shifts in phase were also found to be a good indicator of the change in contact state of the fault. The changes in both amplitude and phase of transmission waves are unifyingly understood through the theory of transmission coefficient presented by Pyrak-Nolte et al. Rough surfaces have a tendency to give larger stick-slips than smooth surfaces. The amount of precursory slip is larger for rough surfaces than for smooth surfaces. Although it was confirmed by a computer simulation that rough surfaces have larger contact diameters than smooth surfaces, the rigorous relationship between the surface roughness (contact diameter) and the amount of precursory slips was not established.  相似文献   

Carbon isotopes and petrography of kerogens in ∼3.5-Ga hydrothermal silica dikes in the North Pole area, Western Australia     

Yuichiro Ueno  Hideyoshi Yoshioka  Yukio Isozaki 《Geochimica et cosmochimica acta》2004,68(3):573-589

More than 600 specimens of ∼3.5 Ga-old hydrothermal silica dikes from the North Pole area, Pilbara craton, Western Australia, have been studied petrographically. The kerogens in 44 samples have been analyzed isotopically (C and N) and chemically (C, N, and H). The silica dikes are composed mainly of fine-grained silica (modal abundance: >97%) and are classified into two types by minor mineral assemblages: B(black)-type and G(gray)-type. The B-type silica dikes contain kerogen (0.37 to 6.72 mgC/g; average 2.44 mgC/g, n = 21) and disseminated sulfides, dominantly pyrite and Fe-poor sphalerite. In some cases, carbonate and apatite are also present. Their silica-dominated and sulfide-poor mineral assemblages suggest precipitation from low-temperature reducing hydrothermal fluid (likely 100-200°C). On the other hand, the G-type silica dikes are sulfide-free and concentrations of kerogen are relatively low (0.05 to 0.41 mgC/g; average 0.17 mgC/g, n = 13). They typically contain Fe-oxide (mainly hematite) which commonly replaces cubic pyrite and rhombic carbonate. Some G-types occur along secondary quartz veins. These textures indicate that the G-type silica dikes were formed by postdepositional metasomatism (oxidation) of the B-types, and that the B-types probably possess premetasomatic signatures. The δ¹³C values of kerogen in the B-types are −38.1 to −33.1‰ (average −35.9‰, n = 21), which are ∼4‰ lower than those of the G-types (−34.5 to −30.0‰; average −32.2‰, n = 19), and ∼6‰ lower than bedded chert (−31.2 to −29.4‰; average −30.5‰, n = 4). This indicates the preferential loss of ¹²C during the metasomatism (estimated fractionation factor: 0.9985). Considering the metasomatic effect on carbon isotopes with probably minor diagenetic and metamorphic overprints, we conclude that the original δ¹³C values of the kerogen in the silica dikes would have been heterogeneous (∼5‰) and at least some material had initial δ¹³C values of ≤ −38‰. The inferred ¹³C-depletions of organic carbon could have been produced by anaerobic chemoautotrophs such as methanogen, but not by aerobic photoautotrophs. This is consistent with the estimated physical and chemical condition of the hydrothermal fluid, which was probably habitable for anaerobic and thermophilic/hyperthermophilic chemoautotrophs. Alternatively, the organic matter may have been possibly produced by abiological reaction such as Fischer-Tropsch Type (FTT) synthesis under the hydrothermal condition. However, the estimated condition is inconsistent with the presence of the effective catalysts for the FTT reaction (i.e., Fe-Ni alloy, magnetite, and hematite). These lines of evidence suggest the possible existence of biosphere in the ∼3.5 Ga sub-seafloor hydrothermal system.  相似文献   

Effectiveness of Mg–Al-layered double hydroxide for heavy metal removal from mine wastewater and sludge volume reduction     

M. Tamzid Rahman  T. Kameda  S. Kumagai  T. Yoshioka 《International Journal of Environmental Science and Technology》2018,15(2):263-272

Health hazards from heavy metal pollution in water systems are a global environmental problem. Of similar concern is sludge that results from wastewater treatment due to unsatisfactory sludge management technology. Therefore, the effectiveness of using Mg–Al-layered double hydroxide in the removal of heavy metals from mine wastewater was tested and compared with that of calcium hydroxide [Ca(OH)₂], which is a common treatment method for heavy metal removal. Initially, the mine wastewater contained cations of the heavy metals iron (Fe), zinc (Zn), copper (Cu), and lead (Pb). The Mg–Al-layered double hydroxides were able to remove 371, 7.2, 121, and 0.4 mg/L of these pollutants, respectively, using the co-precipitation method. The removal of these metals is most effective using 0.5 g Mg–Al-layered double hydroxide (Mg/Al molar ratio 4) and 20 min of shaking. Zn was removed by the formation of Zn(NO₃)(OH)·H₂O and Zn₅(NO₃)₂(OH)₈ when LDH, Mg/Al molar ratios of 4 and 2, respectively, were used. Similarly, Fe, Cu, and Pb were removed by the formation of Fe–Al-layered double hydroxide, Cu₂(OH)₃·NO₃ and Pb₄(OH)₄(NO₃)₄, respectively. While Ca(OH)₂ is also capable of reducing the heavy metal concentrations below the Japanese recommended values, this analysis shows that using 0.5 g Mg–Al-layered double hydroxide is a better treatment condition for mine wastewater, because it generates lower sludge volumes than 0.1 g of Ca(OH)₂. The measured sludge volume was 1.5 mL for Mg–Al-layered double hydroxide and 2.5 mL for Ca(OH)₂, a nearly twofold further reduction.  相似文献   

Preliminary results of a study on the responses of sedimentary rocks to shaft excavation     

Kozo Sugihara  Hisaya Yoshioka  Hiroya Matsui  Toshinori Sato 《Engineering Geology》1993,35(3-4):223-228

A shaft with a diameter of 6 m and a depth of 150 m was excavated in sedimentary rocks. Anin situ study was carried out to identify the size and rock properties of the zone disturbed by the excavation and to estimate the applicability of existing methods for measuring and modelling such a zone. The study detected displacements and changes in the properties of the rock within about 1 m of the shaft wall. Numerical analysis using a model of continuous rock mass can simulate some features of disturbance due to excavation, although slight discrepancies exist between the measured and analysed results. The excavation disturbance detected in this study is probably due to fracturing, the redistribution of stress and undersaturation. However, the relationships between the disturbance due to excavation and these processes have not been quantified. The existing methods for measurements and numerical analysis can provide important information on the disturbance due to excavation but need to be improved to understand disturbance due to excavation further.  相似文献   

Slab weakening: Mechanical and thermal-mechanical consequences for slab detachment     

Shoichi  Yoshioka David A.  Yuen Tine B.  Larsen 《Island Arc》1995,4(2):89-103

Abstract Slab detachment is a geophysical instability whose manifestation can be revealed by seismic tomography. Evidence of this phenomenon is in the Dinarides/Hellenic and the New Hebrides subduction zones. Subducted slabs in these regions are torn horizontally at depths ranging from 100 to 300 km. We constructed a viscoelastic three-dimensional finite element model and investigated the state of stress. We found that an area with high stress concentration of the order of several hundred MPa is formed near the tip of the tear inside the slab, which can cause lateral migration of the tear. Favorable conditions for slab detachment are characterized by large interplate frictional force at a subduction zone and small slab resistance force deeper down. Stress concentration increases with the down-dip tension inside the slab. The phenomenon of slab weakening has also been studied from a thermal-mechanical standpoint, using a two-dimensional convection model with non-Newtonian, temperature-dependent rheology. The stress-dependent rheology plays an important role in causing local weakening of the descending slab. In strongly time-dependent situations the fast descending slab is not strong everywhere but has a weak region in the middle, making it vulnerable to slab detachment. The presence of viscous heating will enhance slab detachment tendency by further weakening the interior by the frictional heating. Besides these effects, there are other mechanisms which can also weaken the slab interior and help to make slabs more pliable and susceptible to detachment.  相似文献   

Magnetic petrology of the 1991–1995 dacite lava of Unzen volcano,Japan: Degree of oxidation and implications for the growth of lava domes     

Takeshi Saito  Naoto Ishikawa  Hiroki Kamata 《Journal of Volcanology and Geothermal Research》2007

To understand the oxidation state and process of oxidation of lava domes, we carried out magnetic petrological analyses of lava samples obtained from domes and block-and-ash-flow deposits associated with the 1991–1995 eruption of Unzen volcano, Japan. As a result, we recognize three different types of magnetic petrology, each related to deuteric high-temperature oxidation during initial cooling. Type A oxides are characterized by homogenous titanomagnetite and titanohematite, indicating a low oxidation state and high titanomagnetite concentrations. Type B oxides are weakly exsolved and contain titanohematite laths and rutile lenses, indicating a higher oxidation state. Type C oxides, which represent the highest oxidation state, are completely exsolved and composed of Ti-poor titanomagnetite, titanohematite, rutile, and pseudobrookite, indicating high hematite concentrations. Some grains in Types A and B show indications of reduction, which was related to interaction with volcanic gases subsequent to high-temperature oxidation. In terms of geological occurrence, the oxidation processes probably differed for endogenous and exogenous domes. Endogenous dome lavas are oxidized concentrically and are classified into the three types according to their location within the dome: samples from the surface are strongly oxidized and classified as Type C, while the inner part is unoxidized and classified as Type A. Exogenous dome lavas are unoxidized and assigned to Type A. Some samples show signs of reduction, which may have occurred around fumaroles. We propose that location within the dome and the process of dome growth are the factors that control oxidation.  相似文献