Stable isotope study of carbonate-cemented rocks from the Pobitite Kamani area,north-eastern Bulgaria     

R. W. Botz  V. Georgiev  P. Stoffers  Kh. Khrischev  V. Kostadinov 《International Journal of Earth Sciences》1993,82(4):663-666

The Precipitation of carbonate cements in the Pobitite Kamani area (Lower Eocene) began during early diagenesis of sediments. There is evidence, however, that calcite is still forming today.The negative ¹³C values to –29.2 suggest that the carbonate formed during degradation of ¹²C-enriched organic matter (perhaps partly from oxidation of methane). The ¹⁸O values of –0.9 to –1.6 reflect the marine origin of the early diagenetic carbonate cements. Most of the carbonates, however, formed during late diagenesis (at approximately 1300 m burial depth) and/or recently (after uplift) from percolating groundwaters. These carbonates have an isotopic composition characteristic of carbonates which precipitated from meteoric waters under normal sedimentary temperatures in isotopic equilibrium with ¹²C-enriched soil carbon dioxide.  相似文献   

The effect of solar wind latitudinal dependence on the cosmic-ray propagation in the heliosphere     

L. M. Georgiev  S. P. Kavlakov  J. R. Popov 《Astrophysics and Space Science》1991,175(2):173-189

We have investigated how the latitude dependence of the solar wind velocity (SWV) influenced the cosmic-ray (CR) modulation and distribution in the heliosphere. The dependence proposed by Fry and Akasofu (1987) is used:v _SW=v _O+v ₁(1-cos ⁿ _m , where the SWV,v _SW is a function of the heliomagnetic latitude _m andv ₀ andv ₁ are constants. An estimation of the diffusion and drift terms in the transport equation is made, which shows that towards the poles the effects of the drift transfer decrease, while the diffusion terms in the equation increase due to the change of the interplanetary magnetic field (IMF) geometry. The numerical solutions of the two-dimensional (2-D) transport equation show that when the SWV changes with latitude: (1) The CR intensities away from the neutral sheet are larger for both IMF polarity periods in comparison with the case when the SWV does not change with the latitude. (2) The latitude gradients are negative during negative magnetic polarity periods. (3) The Voyager 1 and Voyager 2 long-time observations showing greater galactic CR intensities nearer the Sun at greater distances, could be explained by the proposed model.  相似文献   

Numerical algorithm for the dynamic analysis of base-isolated structures with dry friction     

S. Dimova  V. Georgiev 《Natural Hazards》1992,6(1):71-86

This paper deals with the techniques for solving ordinary differential equations with essential nonlinearity arising from the representation of frictional force by the sign function of the relative velocity. This problem is connected with dynamic behavior studies of base-isolated structures with dry friction devices.Mathematical evidence is presented concerning the inaccuracies of the solution which are connected with the representation of the frictional force by the sign function. An approximation of this sign model is made on the basis of the appropriate linearization of a small part of the frictional force function. A numerical algorithm for the dynamic analysis of base-isolated structures with dry friction is proposed. Numerical tests are carried out for establishing the exactness of the proposed techniques. The obtained results prove the accuracy of the techniques.  相似文献   

Kinetic and equilibrium studies of copper-dissolved organic matter complexation in water column of the stratified Krka River estuary (Croatia)     

Yoann Louis  Cdric Garnier  Vronique Lenoble  Stphane Mounier  Neven Cukrov  Dario Omanovi&#x;  Ivanka Pieta 《Marine Chemistry》2009,114(3-4):110-119

An interaction of dissolved natural organic matter (DNOM) with copper ions in the water column of the stratified Krka River estuary (Croatia) was studied. The experimental methodology was based on the differential pulse anodic stripping voltammetric (DPASV) determination of labile copper species by titrating the sample using increments of copper additions uniformly distributed on the logarithmic scale. A classical at-equilibrium approach (determination of copper complexing capacity, CuCC) and a kinetic approach (tracing of equilibrium reconstitution) of copper complexation were considered and compared. A model of discrete distribution of organic ligands forming inert copper complexes was applied. For both approaches, a home-written fitting program was used for the determination of apparent stability constants (K_i^equ), total ligands concentration (L_iT) and association/dissociation rate constants (k_i¹,k_i^- 1).A non-conservative behaviour of dissolved organic matter (DOC) and total copper concentration in a water column was registered. An enhanced biological activity at the freshwater–seawater interface (FSI) triggered an increase of total copper concentration and total ligand concentration in this water layer. The copper complexation in fresh water of Krka River was characterised by one type of binding ligands, while in most of the estuarine and marine samples two classes of ligands were identified. The distribution of apparent stability constants (log K₁^equ: 11.2–13.0, log K₂^equ:8.8–10.0) showed increasing trend towards higher salinities, indicating stronger copper complexation by autochthonous seawater organic matter.Copper complexation parameters (ligand concentrations and apparent stability constants) obtained by at-equilibrium model are in very good accordance with those of kinetic model. Calculated association rate constants (k₁¹:6.1–20 × 10³ (M s)^− 1, k₂¹: 1.3–6.3 × 10³ (M s)^− 1) indicate that copper complexation by DNOM takes place relatively slowly. The time needed to achieve a new pseudo-equilibrium induced by an increase of copper concentration (which is common for Krka River estuary during summer period due to the nautical traffic), is estimated to be from 2 to 4 h.It is found that in such oligotrophic environment (dissolved organic carbon content under 83 µM_C, i.e. 1 mg_CL^− 1) an increase of the total copper concentration above 12 nM could enhance a free copper concentration exceeding the level considered as potentially toxic for microorganisms (10 pM).  相似文献   

A critical evaluation of using bulk sediment instead of fine fraction in environmental marine studies, investigated on example of Rijeka harbor, Croatia     

Stanislav Frančišković-Bilinski  Neven Cukrov 《Environmental Earth Sciences》2014,71(1):341-356

This work tested the preferential use of fine (<63 μm) or bulk sediment (<2 mm) in environmental research of marine sediments in the Eastern Adriatic. Fine fraction sediment containing silt and clay (<63 μm), predominating in the studied area, was examined to evaluate past and present anthropogenic inputs and to test our hypothesis that investigation of bulk sediment should be preferred. Following aqua regia digestion, chemical analyses of 58 elements were performed by ICP/OES, ICP-MS and cold vapor AAS, and statistical analysis was performed. The concentrations of the majority of the analyzed elements increased with age of the sediment, except for Ag and Sn, which had higher concentrations in recent sediments. The previous main sources of metal contamination in Rijeka harbor were now abandoned municipal-sewage outflow and oil refinery, and continuing harbor activities and antifouling paint use. All activities except of antifouling paint use have been decreasing significantly. Anomalies of selected elements were determined by the box-plot method. More anomalies were found in the bulk sediment than in the fine fraction. Results of Q-modality clustering and factor analysis in the fine fraction almost correlate with that applied on bulk sediments. Thus, it can be said that the differences between the element distribution in the bulk and fine fraction are not statistically significant. Our conclusion is that analysis of bulk marine sediment gives a better insight into the state of pollution and supports previous recommendations to use bulk sediment as a chosen media for environmental studies.  相似文献   

On the occurrence of convective motions in the upper photosphere     

C. De Jager  L. Neven 《Solar physics》1968,4(4):379-385

We have examined whether the motion field in the photosphere in the range of optical depths 0.25< ₀< 0.6 is dominated by thermal convection or by vibrations. The observed asymmetries of infrared Fraunhofer lines indicate the presence of motions, and the fact that the asymmetry is zero for lines of low excitation and increases with the excitation potential shows that these motions are chiefly convective in this part of the photosphere: upward moving elements appear to be hotter than downward moving ones.Assuming furthermore that the photosphere can be described by a three-column model, with temperature differences as given by Edmonds (1967), we find that in the range of optical depths given above, where T seems to vary between 80 and 160 °K, average convective velocities of 2.3 to 3.2 km/sec should occur. This result is in numerical agreement with (a) a previous one by the present authors (1967) derived from the variation of line asymmetry with depth in lines of one multiplet, (b) a finding by Lambert and Mallia (1968) deduced from absolute wavelength measurements of Fraunhofer lines, and (c) a recent result of Beckers (1968) found from a comparison of two granulation pictures obtained simultaneously with a narrow-band filter centred on the two wings of a faint line.  相似文献   

Optical monitoring of the z= 4.40 quasar Q 2203+292     

E. P. Ovcharov  P. L. Nedialkov  A. T. Valcheva  V. D. Ivanov  N. A. Tikhonov  I. S. Stanev  A. B. Kostov  Ts. B. Georgiev 《Monthly notices of the Royal Astronomical Society》2008,386(2):819-825

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Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step     

Gang Yang  Aaron Zimmerman  Nicole C. Hurtig  Svetoslav V. Georgiev  Vineet Goswami  Judith L. Hannah  Holly J. Stein 《Geostandards and Geoanalytical Research》2020,44(2):231-242

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.  相似文献   

Elements of groundwater protection in a karst environment   总被引：2，自引：0，他引：2  

Neven Kresic  Petar Papic  Radisav Golubovic 《Environmental Geology》1992,20(3):157-164

The large spread of karst in Yugoslavia (over one third of the territory) and the importance of its water resources due to the growing pollution of the environment lead to complicated research activities in various scientific fields. A multidisciplinary approach to this research should have the following basic directions: defining sources of pollution; classification of pollutants; defining hydrological, geological, and hydrogeological characteristics of the area studied; study of interaction among pollutants, groundwater, and rocks; and, finally, defining of specific protection measures. The prerequisite for any decision making should already exist in local and regional urban plans. Some basic principles of the listed directions of research are illustrated by examples from practice.  相似文献   

River runoff changes and recent climatic fluctuations in Bulgaria     

Ivan Vassilev  Bojidar  N. Georgiev 《GeoJournal》1996,40(4):379-385

Some estimates of global climatic change in the next 100 years suggest a general warming and rainfall decrease on the Balkan Peninsula. Our studies suggest that in Bulgaria climatic changes have already started. Because water resources to a great extent depend upon climate dynamics, this paper develops the linkage of climatic fluctuations and water resources using time-series analysis of climatic parameters and some river runoff characteristics and their correlation. One of the main conclusions, based on the results, is that climatic change manifested in the last 15 years has significantly influenced river runoff. A study of the recent prolonged drought and the influence of changes on water resources and human activity begins with characterizing climate-hydrology linkages. The results of this study point to several problems of regional and local importance.  相似文献