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1.
The Kuroko deposits of NE Honshu are a key type deposit for the study of volcanogenic massive sulfide deposits. However, these deposits have not been studied in detail since the early 1980's and knowledge of their mode of formation is now dated. In this study, we present the analysis of 12 samples of the Kuroko deposits, 12 samples of submarine hydrothermal minerals from the Sunrise deposit and 6 samples from Suiyo Seamount, both of which are located on the Izu-Ogasawara (Bonin) Arc, for 27 elements. For the Kuroko deposit, Cd>Sb>Ag>Pb>Hg>As>Zn>Cu are highly enriched, Au>Te>Bi>Ba>Mo are moderately enriched, In>Tl are somewhat enriched and Fe is not significantly enriched relative to the average continental crust. Within each of these deposits, a similar pattern of element associations is apparent: Zn–Pb with As, Sb, Cd, Ag, Hg, Tl and Au; Fe–Cu–Ba with As, Sb, Ag, Tl, Mo, Te and Au; Si–Ba with Ag and Au; CaSO4. The enrichment of the chalcophilic elements in these deposits is consistent with hydrothermal leaching of these elements from the host rocks which are dominantly rhyolite–dacite in the case of the Kuroko deposits, rhyolite in the case of the Sunrise deposit and dacite–rhyolite in the case of the Suiyo Seamount deposit. However, this pattern of element enrichment is also similar to that observed in fumarolic gas condensates from andesitic volcanoes. This suggests that there may be a significant magmatic contribution to the composition of the hydrothermal fluids responsible for the formation of the Kuroko deposits, although it is not yet possible to quantify the relative contributions of these two sources of elements.The compositional data show that Sunrise and Suiyo Seamount deposits are much closer compositionally to the Kuroko deposits from NE Honshu than are the submarine hydrothermal deposits from the JADE site in the Okinawa Trough which contain, on average, significantly higher concentrations of Pb, Zn, Sb, As and Ag than each of these deposits. In spite of the greater similarity in tectonic setting of the Hokuroku Basin in which the Kuroko deposits formed to the Okinawa Trough (intracontinental rifted back-arc basin) compared to Myojin Knoll and Suiyo Seamount (active arc volcanoes), it appears that submarine hydrothermal deposits from Myojin Knoll and Suiyo Seamount are closer analogues of the Kuroko deposit than are those from the Okinawa Trough. The present data are consistent with the magmatic hydrothermal model for the formation of Kuroko-type deposits as formulated by Urabe and Marumo [Urabe, T., Marumo, K., 1991. A new model for Kuroko-type deposits of Japan. Episodes 14, 246–251].  相似文献   
2.
G. P. Glasby  K. Notsu   《Ore Geology Reviews》2003,23(3-4):299-339
The Okinawa Trough is a heavily sedimented, rifted back-arc basin formed in an intracontinental rift zone. Submarine hydrothermal activity is located within the six back-arc rifts located in the middle and southern Okinawa Trough and its distribution is controlled principally by tectonic factors. Subduction of the Daito and Gagua Ridges beneath the Ryukyu Arc has resulted in fracturing of the brittle lithosphere beneath the Okinawa Trough. Hydrothermal activity is strongest in the volcanic arc-rift migration phenomenon (VAMP) area plus the JADE site and Southernmost Part of the Okinawa Trough (SPOT) area which form the prolongation of these two ridges. These areas are characterized by extremely high heat flow locally. Submarine hydrothermal fluids from the Okinawa Trough tend to be strongly influenced by interaction of the hydrothermal fluids with organic matter in the sediment resulting in high alkalinity and NH4+ concentrations of the fluids. The fluids also contain high concentrations of CO2 of magmatic origin. Submarine hydrothermal mineralization in the trough is diverse. The CLAM site consists principally of carbonate chimneys. Interaction of the hydrothermal fluid with organic matter in the sediment is particularly strong at this site. This is most probably a sediment-hosted deposit in which sulphide minerals have deposited within the sediment column leaving ‘spent ore-fluids’ to emerge at the seafloor. The JADE site consists of active and inactive sulphide–sulphate chimneys and mounds. The Zn–Pb-rich sulphides at this site contain the highest concentrations of Pb, Ag and Au so far recorded in submarine hydrothermal sulphide deposits. At Minami-Ensei Knoll and Hatoma Knoll, active and inactive chimneys consist principally of anhydrite and barite as a result of phase separation of the hydrothermal fluids beneath the seafloor. An intense black smoker has recently been discovered at Yonaguni Knoll in the SPOT area. If it is confirmed that sulphide mineralization is dominant at this site, this could be a highly prospective area. The most prospective areas for economic-grade minerals in the Okinawa Trough appear to be the JADE site and the SPOT area.  相似文献   
3.
Anomalous water level changes were observed at two wells associated with seismic swarm activity off Izu Peninsula on March, 1997. These are coseismic water level drops followed by gradual postseismic water level rise at the time of large earthquakes during the swarm activity. The post-seismic water level rises, which can be fitted by an exponential function with a time constant of about six hours, are explained in terms of the horizontal pressure diffusion due to the pressure gradient in the aquifer induced by the coseismic static strain.  相似文献   
4.
Two soil CO2 efflux surveys were carried out in September 1999 and June 2002 to study the spatial distribution of diffuse CO2 degassing and estimate the total CO2 output from Showa-Shinzan volcanic dome, Japan. Seventy-six and 81 measurements of CO2 efflux were performed in 1999 and 2002, respectively, covering most of Showa-Shinzan volcano. Soil CO2 efflux data showed a wide range of values up to 552 g m-2 d-1. Carbon isotope signatures of the soil CO2 ranged from -0.9‰ to -30.9‰, suggesting a mixing between different carbon reservoirs. Most of the study area showed CO2 efflux background values during the 1999 and 2002 surveys (B = 8.2 and 4.4 g m-2 d-1, respectively). The spatial distribution of CO2 efflux anomalies for both surveys showed a good correlation with the soil temperature, indicating a similar origin for the extensive soil degassing generated by condensation processes and fluids discharged by the fumarolic system of Showa-Shinzan. The total diffuse CO2 output of Showa-Shinzan was estimated to be about 14.0–15.6 t d-1 of CO2 for an area of 0.53 km2.  相似文献   
5.
6.
Secular variations in 13C/12C ratios and chemical compositions of gas samples from October 1986 to July 1992 are reported from a 92–95 °C steam well located about 3 km north of Mt. Mihara, an active volcano on Izu-Oshima Island, Japan. The δ13C value steeply increased from −2.97‰ (relative to PDB carbonate) in December 1986 to −1.15‰ in March 1988 and then gradually decreased to −1.75‰ in July 1992. Over the same period, the CO2 content changed similarly with time, even though the experimental error is relatively large. These variations are consistent with helium isotope changes. Initially rapid and then slow enhancements of 3He/4He ratio, δ13C value and CO2 content are invoked by violent eruptions of Izu-Oshima volcano from 15 November to 18 December 1986. After the eruptive activity, depletion of magmatic gas emission and subsequent mixing with crustal fluids in the hydrothermal system may produce the gradual decreases of 3He/4He ratio, δ13C value and CO2 content. Taking into account the rates of these decreases, we suggest that helium and carbon isotope ratios will return to the situation of before the magmatic eruption within 15 years.  相似文献   
7.
Soil H2 and CO2 surveys were carried out along seven active faults and around the aftershock region of the 2000 Tottori-ken Seibu earthquake in Japan. Diffuse CO2 effluxes were also measured along one fault and around the 2000 aftershock region. The results show highly variable H2 concentration in space and time and it seems that the maximum H2 concentration at each active fault correlates with fault activity as exemplified by the time of the latest big earthquakes. Even though observed H2 concentrations in four faults were markedly lower than those collected previously in the latter half of the 1970s, it is evident that the higher H2 concentrations in this study are due to the addition of the fault gases. Comparing the chemical composition of trapped gases (H2: 5–20% and CO2/H2: 0.5–12) in fractured rocks of drill cores bored at the Nojima fault, a soil gas sample with the highest H2 concentration showed large amounts of the trapped fault gas, diluted with atmospheric component. The profile experiment across a fracture zone at the Yamasaki fault showed higher H2 concentrations and lower CO2/H2 ratios as was observed in soil gas from the fracture zone. A few days after the 2000 Tottori-kei Seibu earthquake, no CO2 effluxes related to the occurrence of earthquakes were observed at the aftershock region. However, only above the epicenter zone, relatively high H2 concentrations in soil gases were observed.  相似文献   
8.
A new continuous monitoring system has been developed for the measurement of volcanic gas from the steam well located 3 km north from the summit of Izu-Oshima volcano, Japan. After removing the water vapor using three sequential dehydration methods, CO2 and SO2 contents are measured using IR sensors, and O2 and H2 using a zirconia sensor and a semiconductor sensor, respectively. This system has been in operation without any significant trouble for 3 years.The dehydrated volcanic gas from the well consists of a mixture of CO2, O2 and N2. A decreasing trend of the CO2 content was observed from 1995 to 1998 together with a decrease of volcanic activity. Seasonal changes have also been observed in CO2 and O2 contents, CO2 being higher and O2 lower in summer, which suggests larger contribution of magmatic components in summer. While changes in short-term variation in CO2 and O2 are influenced by atmospheric pressure changes; the CO2 content correlates inversely with atmospheric pressure unlike O2 with some hours delay. In contrast, the H2 content increased intermittently up to 1200 ppm one to several hours after a sudden drop in the atmospheric pressure and without any apparent correlation with seasonal changes.This system allows us to study temporal variation in chemical composition of volcanic gas during quiescent periods of volcanic activity of Izu-Oshima volcano, and might help us detect anomalous changes before future eruptive events.  相似文献   
9.
The present work reports the results of 15 studies of diffuse CO2 degassing performed at Teide Volcano crater (Canary Island, Spain) and the chemical and isotopic compositions of fluids discharged from a fumarolic field located at the top of the volcano as measured between 1991 and 2010. A higher contribution of magmatic gases accompanied by enhanced total diffuse CO2 emissions were observed in relation with a seismic crisis that occurred in Tenerife Island between 2001 and 2005, with the main peak of seismic activity between April and June 2004. A significant pulse in total diffuse CO2 emission was observed at the crater of Teide (up to 26.3?t day?1) in 2001. In December 2003, the chemical composition of the Teide fumarole changed significantly, including the appearance of SO2, an increase in the HCl and CO concentrations and in the C2H6/C2H4 and C3H8/C3H6 ratios, and a decrease in the H2S, CH4, and C6H6 concentrations and in the gas/steam ratio. A few months after a drastic decrease in seismic activity, the SO2, HCl, and CO concentrations and the C2H6/C2H4 and C3H8/C3H6 ratios strongly decreased, whereas the CH4 and C6H6 concentrations and the gas/steam ratios increased. According to the trends shown by both the geochemical parameters and the seismic signals late in the observation period, the risk of a rejuvenation of volcanic activity at Teide is considered to be low. The associated temporal changes in seismic activity and magmatic degassing indicate that geophysical and fluid geochemistry signals in this system are related. Future monitoring programs aimed at mitigating volcanic hazard on Tenerife Island should involve coupled geophysical and geochemical studies.  相似文献   
10.
In contrast to most other arcs with oceanic plate subduction, the Aegean arc is characterized by continent–continent subduction. Noble gas abundances and isotopic compositions of 45 gas samples have been determined from 6 volcanoes along the arc, 2 islands in the back-arc region and 7 sites in the surrounding areas. The 3He/4He ratios of the samples ranged from 0.027RA to 6.2RA (RA denotes the atmospheric 3He/4He ratio of 1.4×10−6), demonstrating that even the maximum 3He/4He ratio in the region is significantly lower than the maximum ratios of most oceanic subduction systems, which are equal to the MORB value of 8±1 RA. Regional variations in the 3He/4He ratio were observed both along and across the arc. The maximum 3He/4He ratio was obtained from Nisyros volcano located in the eastern end of the arc, and the ratio decreased westward possibly reflecting the difference in potential degree of crustal assimilation or the present magmatic activity in each volcano. Across the volcanic arc, the 3He/4He ratio decreased with an increasing distance from the arc front, reaching a low ratio of 0.063RA in Macedonia, which suggested a major contribution of radiogenic helium derived from the continental crust. At Nisyros, a temporal increase in 3He/4He ratio due to ascending subsurface magma was observed after the seismic crisis of 1995–1998 and mantle neon was possibly detected. The maximum 3He/4He ratio (6.2RA) in the Aegean region, which is significantly lower than the MORB value, is not probably due to crustal assimilation at shallow depth or addition of slab-derived helium to MORB-like mantle wedge, but inherent characteristics of the subcontinental lithospheric mantle (SCLM) beneath the Aegean arc.  相似文献   
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