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Leachate was a major cause of high risk classification. This landfill was set as one with highest possible risk classification due to high vulnerability of private water wells to contamination from leachate flows. The aim of this study is to determine the present and possible environmental risks of the leachate spreading from solid waste dumping site in Tunceli and offer solutions for those determined environmental risks. For this purpose, the characteristics of the leachate were monitored at two station points detected in the solid waste dumping site for 7 months. The characteristics of the leachate were found for pH between 7.9 and 8.7. Oxidation reduction potential (ORP) occurred between ??143 and ??48 mV while conductivity was between 2.8 and 2.6 mS. Total solid matter (TSM) and suspended solid matter (SSM) were between 1000 and 7000 mg/l, 0.2–22.5 mg/l, respectively, while total volatile solids (TVS) occurred between 300 and 1800 mg/l for the two stations. Alkalinity was approximately between 290 and 5210 mg/l, while biological oxygen demand (BOD5) and chemical oxygen demand (COD) results were 15–606 mg/l and 60–1160 mg/l, respectively, for two stations in all sampling time. In both stations, orthophosphate, ammonium nitrogen, nitrate, sulfate, and chloride analyses stayed between 3.04 and 921.1 mg/l; 0.29–619.36 mg/l; 8.94–135.04 mg/l; 125.9–1360.9 mg/l and 99.9–1249.9 mg/l, respectively, in 6 months. As a result of the characterization studies obtained from the leachate, it was found that the amounts of water entering into the waste mass and the retention period of the water in the mass were very effective in the temporal character change of the leachate. According to the Discharge Standards for Solid Waste Assessment and Disposal Facilities and Discharge to Waste Water Infrastructure Facilities of waste management regulation, the results were found to be risky. Consequently, the site in question needs to be urgently rehabilitated when considering the environmental risks of the leachate spreading from the site.  相似文献   
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Gold in the Sahinli and Tespih Dere intermediate sulfidation gold-base metal deposits in Western Turkey occurs in relatively deep epithermal quartz veins along with base metal minerals which have epithermal textures, including plumose quartz, vug infills, comb and cockade textures and matrix-supported milled breccias. The total sulfide content of the veins in the area is variable ranging from < 1% to 60% and is dominated by pyrite, galena, sphalerite and chalcopyrite. Sphalerite is Fe-poor (0.6 to 1.4 mol% FeS). Minor amounts of Ag-rich tetrahedrite are present. Primary hydrothermal alteration minerals include illite/muscovite, mixed-layer illite/smectite (11.6 Å) and clinochlore towards the east and, alunite, dickite/nacrite and pyrophyllite towards the west at Sahinli; major illite/muscovite and dickite occur at Tespih Dere and Sarioluk, respectively.Fluid inclusions in main-stage quartz at Sahinli are only liquid-rich, with homogenization temperatures ranging from 220 to 322 °C and the majority of Th values between 250 and 300 °C. Salinity ranges from 4.3 to 6.9 wt.% NaCl equiv. First ice-melting temperatures (Tmf) between ?24.5 and ?19.0 °C indicate that the fluids were dominated by NaCl  H2O during mineralization. The relatively higher average Th at the Tespih Dere deposit (295 °C) is attributed to a relatively deeper level of exposure.Calculated δ18O values indicate that ore-forming hydrothermal fluids in the study area had δ18OH2O ranging from + 1.1 to + 9.7‰ (average = 3.8‰), strongly 18O-enriched compared with present-day hydrothermal meteoric water in the area (δ18O = ?8.5‰). δD values of fluid inclusions in quartz range from ?58 to ?93‰ and δD values of clay minerals and alunite from ?40 to ?119‰. δD values from intermediate argillic alteration (average = ?68‰) in the study area are very similar to δD values of the present-day local geothermal system (average δD = ?54‰) whereas δD values from advanced-argillic alteration (average δD = ?33‰) are very different from the present-day local geothermal system.The δ34S values in samples from the Sahinli and Tespih Dere deposits average ?2.9‰ for pyrite; ?3.3‰ for chalcopyrite; ?5.4‰ for sphalerite and ?7.6‰ for galena. These data are consistent with derivation of the sulfur from either igneous rocks or possibly from local wallrock.  相似文献   
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This study was performed to propose a suitable treatment for waste foundry sand (WFS) before persistent disposal. It was observed that solidification/stabilization (S/S), which is the common pre‐treatment method because of its comparatively easy and inexpensive applicability, can treat WFS including dissolved organic carbon (DOC) above hazardous landfilling limits. Regular sand was partially replaced with WFS with a ratio of 0–90 wt% in order to prepare three different kinds of mortar samples, where Portland limestone cement (PLC) alone, calcium lime (CL) alone, and PLC together with CL were contained as binders. Leaching behaviors of all S/S products were analyzed according to the TS EN 12457‐4 leaching test. The treatment efficiency was assessed to reduce the DOC content to the levels under the European landfill acceptance criteria. Furthermore, heavy metals (Ni, Zn, Cr), fluoride (F?), total dissolved solids leachability, and total organic carbon content were analyzed in order to investigate the pre‐treatment ability and to determine whether S/S products can be disposed of in a landfill site with municipal wastes or in a separate landfill site. The results showed that S/S of WFS is an efficient pre‐treatment technique before its disposal in a landfill and provides economical advantages compared to hazardous waste landfilling.  相似文献   
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Southwestern Turkey experienced a transition from crustal shortening to extension during Late Cenozoic, and evidence of this was recorded in four distinct basin types in the Mu?la–Gökova Gulf region. During the Oligocene–Early Miocene, the upper slices of the southerly moving Lycian Nappes turned into north-dipping normal faults due to the acceleration of gravity. The Kale–Tavas Basin developed as a piggyback basin along the fault plane on hanging wall blocks of these normal faults. During Middle Miocene, a shift had occurred from local extension to N–S compression/transpression, during which sediments in the Eskihisar–T?naz Basins were deposited in pull-apart regions of the Menderes Massif cover units, where nappe slices were already eroded. During the Late Miocene–Pliocene, a hiatus occurred from previous compressional/transpressional tectonism along intermountain basins and Yata?an Basin fills were deposited on Menderes Massif, Lycian Nappes, and on top of Oligo–Miocene sediments. Plio-Quaternary marked the activation of N–S extension and the development of the E–W-trending Mu?la–Gökova Grabens, co-genetic equivalents of which are common throughout western Anatolia. Thus, the tectonic evolution of the western Anotolia during late Cenozoic was shifting from compressional to extensional with a relaxation period, suggesting a non-uniform evolution.  相似文献   
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