Mono- and dicyclic unsaturated triterpenoid hydrocarbons in sediments from Lake Masoko (Tanzania) widely extend the botryococcene family     

Romain de Mesmay  Pierre Metzger  Vincent Grossi  Sylvie Derenne 《Organic Geochemistry》2008,39(7):879-893

A mixture of C₃₃–C₃₇ botryococcenes and partially reduced derivatives was isolated from ca. 32,000 year old sediment from Lake Masoko, a freshwater crater lake in the Rungwe Range area (Tanzania). Botryococcenes and derivatives accounted for 246 μg/g dry sediment and for >92% of the hydrocarbon fraction; 1D and 2D nuclear magnetic resonance spectroscopy (NMR) and mass spectrometry allowed the structure of the dominant botryococcene (43% of hydrocarbon fraction) to be established, after purification using high performance liquid chromatography (HPLC). The compound is a novel tetraunsaturated dicyclic C₃₄ botryococcene and is named C₃₄ masokocene. Overall, the structures of six other novel botryococcenes and four partially reduced derivatives were tentatively assigned. The structures of the new biomarkers, three dicyclic C₃₄–C₃₆ botryococcenes (or masokocenes) and seven monocyclic C₃₄–C₃₇ analogues are discussed along with their biosynthetic relationship. The high abundance of such polyunsaturated compounds preserved in 32,000 year old sediment from the lake indicates an aquatic ecosystem dominated at the time by the green alga Botryococcus braunii, as well very good preservation of the organic matter.  相似文献   

Dissolution/precipitation kinetics of boehmite and gibbsite: Application of a pH-relaxation technique to study near-equilibrium rates     

Pascale Bnzeth  Donald A. Palmer  David J. Wesolowski 《Geochimica et cosmochimica acta》2008,72(10):2429-2453

The dissolution and precipitation rates of boehmite, AlOOH, at 100.3 °C and limited precipitation kinetics of gibbsite, Al(OH)₃, at 50.0 °C were measured in neutral to basic solutions at 0.1 molal ionic strength (NaCl + NaOH + NaAl(OH)₄) near-equilibrium using a pH-jump technique with a hydrogen-electrode concentration cell. This approach allowed relatively rapid reactions to be studied from under- and over-saturation by continuous in situ pH monitoring after addition of basic or acidic titrant, respectively, to a pre-equilibrated, well-stirred suspension of the solid powder. The magnitude of each perturbation was kept small to maintain near-equilibrium conditions. For the case of boehmite, multiple pH-jumps at different starting pHs from over- and under-saturated solutions gave the same observed, first order rate constant consistent with the simple or elementary reaction: .

This relaxation technique allowed us to apply a steady-state approximation to the change in aluminum concentration within the overall principle of detailed balancing and gave a resulting mean rate constant, (2.2 ± 0.3) × 10⁻⁵ kg m⁻² s⁻¹, corresponding to a 1σ uncertainty of 15%, in good agreement with those obtained from the traditional approach of considering the rate of reaction as a function of saturation index. Using the more traditional treatment, all dissolution and precipitation data for boehmite at 100.3 °C were found to follow closely the simple rate expression:

R_net,boehmite=10^-5.485{m_OH^-}{1-exp(ΔG_r/RT)}, with R_net in units of mol m⁻² s⁻¹. This is consistent with Transition State Theory for a reversible elementary reaction that is first order in OH⁻ concentration involving a single critical activated complex. The relationship applies over the experimental ΔG_r range of 0.4–5.5 kJ mol⁻¹ for precipitation and −0.1 to −1.9 kJ mol⁻¹ for dissolution, and the pH_m ≡ −log(mH⁺) range of 6–9.6. The gibbsite precipitation data at 50 °C could also be treated adequately with the same model:R_net,gibbsite=10^-5.86{m_OH^-}{1-exp(ΔG_r/RT)}, over a more limited experimental range of ΔG_r (0.7–3.7 kJ mol⁻¹) and pH_m (8.2–9.7).  相似文献   

A multidisciplinary multi-scale framework for assessing vulnerabilities to global change   总被引：3，自引：0，他引：3  

Marc J. Metzger  Rik Leemans  Dagmar Schrter 《International Journal of Applied Earth Observation and Geoinformation》2005,7(4):253-267

Terrestrial ecosystems provide a number of vital services for people and society, such as food, fibre, water resources, carbon sequestration, and recreation. The future capability of ecosystems to provide these services is determined by changes in socio-economic factors, land use, atmospheric composition, and climate. Most impact assessments do not quantify the vulnerability of ecosystems and ecosystem services under such environmental change. They cannot answer important policy-relevant questions such as 'Which are the main regions or sectors that are most vulnerable to global change?’ 'How do the vulnerabilities of two regions compare?’ 'Which scenario is the least harmful for a sector?’This paper describes a new approach to vulnerability assessment developed by the Advanced Terrestrial Ecosystem Analysis and Modelling (ATEAM) project. Different ecosystem models, covering biodiversity, agriculture, forestry, hydrology, and carbon sequestration are fed with the same Intergovernmental Panel on Climate Change (IPCC) scenarios based on the Special Report on Emissions Scenarios (SRES). Each model gives insights into specific ecosystems, as in traditional impact assessments. Moreover, by integrating the results in a vulnerability assessment, the policy-relevant questions listed above can also be addressed. A statistically derived European environmental stratification forms a key element in the vulnerability assessment. By linking it to other quantitative environmental stratifications, comparisons can be made using data from different assessments and spatial scales.  相似文献   

The influence of the coast on the dynamics of upwelling fronts: Part II. Numerical simulations     

Pascale Bouruet-Aubertot  Vincent Echevin 《Dynamics of Atmospheres and Oceans》2002,36(1-3)

We investigated the dynamics of upwelling fronts near a coast. This work was first motivated by laboratory experiments [Bouruet-Aubertot, Linden, Dyn. Atmos. Oceans, 2002] in which the front is produced by the adjustment of a buoyant fluid initially confined within a bottomless cylinder. It was shown that cyclonic eddies consisting of coastal waters are enhanced when the front is unstable near the coast (the outer vertical boundary). The purpose of this paper is to provide further insights into this process. We reproduced the experimental configuration using a three-dimensional model of the primitive equations. We first show that for coastal fronts more potential energy, in terms of the maximum available potential energy, is released than for open-ocean fronts. Therefore, waves of larger amplitude are generated during the adjustment and the mean flow that establishes has a higher kinetic energy in the former case. Then as baroclinic instability starts and wave crests reach the boundary, cyclonic eddies are enhanced as in the laboratory experiments and in a similar way. However, in contrast to the laboratory experiments, offshore advection of cyclonic eddies can occur in two stages, depending on the spatial organization of the baroclinic wave. When the baroclinic wave consists of the sum of different modes and is thus highly asymmetric, the offshore advection of cyclonic eddies occurs just after their enhancement at the boundary, as in the laboratory experiments. By contrast, when a single-mode baroclinic wave develops, neighboring cyclonic eddies first merge before being advected offshore. Very different behavior is observed for open-ocean fronts. First a mixed baroclinic–barotropic instability grows. Then the eddies transfer their energy to the mean flow and the barotropic and baroclinic instabilities start again. An excellent agreement is obtained with the main result obtained in the laboratory experiments: the ratio between growth rates of surface cyclonic and anticyclonic vorticity increases as the instability develops nearer to the coast.  相似文献   

Projected changes of rainfall seasonality and dry spells in a high greenhouse gas emissions scenario     

Salvatore Pascale  Valerio Lucarini  Xue Feng  Amilcare Porporato  Shabeh ul Hasson 《Climate Dynamics》2016,46(3-4):1331-1350

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Resilience and seismic risk perception at school: a geoethical experiment in Aiello Calabro,southern Italy     

De Pascale  Francesco  Bernardo  Marcello  Muto  Francesco  Di Matteo  Dante  Dattilo  Valeria 《Natural Hazards》2016,86(2):569-586

The last few years have seen the debate on the geoethics of environmental and climatic protection growing to include resilience as a central idea within this new discipline, which holds many similarities with geography. Resilience analysis often looks at the capacity to re-establish conditions of equilibrium within a system which has been hit by a serious shock, e.g. a natural or man-made disaster. Geoethics works, in tandem with geological analyses and the geography of risk, to inform a population and develop integrated risk management in such a way as to strengthen a community’s resilience. The aim of this work is to study some people’s capacity to overcome what was potentially a disastrous event and, through a process of reconstruction, turn it into an occasion for growth. The experiment, carried out in the primary and middle schools in Aiello Calabro (Calabria, southern Italy), was conducted on the basis of the belief that there is a close relationship between a population’s having a realistic understanding of the risk of such an event, e.g. an earthquake, and high levels of resilience. We also tried to gain an insight into the relationship that may exist between resilience in primary and secondary school children and methods of coping which give an appropriate management of seismic risk. To be more precise, we try to discover whether there is a link between good/appropriate resilience and good/appropriate risk management.

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Estuarine Habitat and Demographic Factors Affect Juvenile Chinook (<Emphasis Type="Italic">Oncorhynchus tshawytscha</Emphasis>) Growth Variability in a Large Freshwater Tidal Estuary     

Pascale?A.?L.?GoertlerEmail author  Charles?A.?Simenstad  Daniel?L.?Bottom  Susan?Hinton  Lia?Stamatiou 《Estuaries and Coasts》2016,39(2):542-559

Estuarine rearing has been shown to enhance within watershed biocomplexity and support growth and survival for juvenile salmon (Oncorhynchus sp.). However, less is known about how growth varies across different types of wetland habitats and what explains this variability in growth. We focused on the estuarine habitat use of Columbia River Chinook salmon (Oncorhynchus tshawytscha), which are listed under the Endangered Species Act. We employed a generalized linear model (GLM) to test three hypotheses: (1) juvenile Chinook growth was best explained by temporal factors, (2) habitat, or (3) demographic characteristics, such as stock of origin. This study examined estuarine growth rate, incorporating otolith microstructure, individual assignment to stock of origin, GIS habitat mapping, and diet composition along ~130 km of the upper Columbia River estuary. Juvenile Chinook grew on average 0.23 mm/day in the freshwater tidal estuary. When compared to other studies in the basin our growth estimates from the freshwater tidal estuary were similar to estimates in the brackish estuary, but ~4 times slower than those in the plume and upstream reservoirs. However, previous survival studies elucidated a possible tradeoff between growth and survival in the Columbia River basin. Our GLM analysis found that variation in growth was best explained by habitat and an interaction between fork length and month of capture. Juvenile Chinook salmon captured in backwater channel habitats and later in the summer (mid-summer and late summer/fall subyearlings) grew faster than salmon from other habitats and time periods. These findings present a unique example of the complexity of understanding the influences of the many processes that generate variation in growth rate for juvenile anadromous fish inhabiting estuaries.  相似文献   

Diel variation of benthic respiration in a coral reef sediment (Reunion Island,Indian Ocean)     

Jacques Clavier  Laurent Chauvaud  Pascale Cuet  Clémentine Esbelin  Patrick Frouin  Dorothée Taddei  Gérard Thouzeau 《Estuarine, Coastal and Shelf Science》2008

Oxygen and total dissolved inorganic carbon (DIC) fluxes at the water–sediment interface were measured using benthic chambers to assess the short-term variations of community respiration (CR) in the back reef sediments of Reunion Island (Indian Ocean). Benthic CR had a daily cycle of minimal (6:00 AM) and maximal values (6:00 PM), showing increases of oxygen and DIC fluxes of 2.8- and 3.8-fold, respectively. Average CR values were observed at midday and midnight. The evolution of fluxes was positively related to oxygen concentration in ambient water, but not to temperature changes. In the study area, high daytime primary production augments the amount of energy available for community metabolism and increases benthic respiration. The benthic communities are therefore subjected to short-term variable environmental conditions with oxygen supersaturation during the day, and moderately hypoxic conditions at the end of the night.  相似文献   

Time Transfer for TAI Using a Geodetic Receiver: An Example with the Ashtech ZXII-T   总被引：1，自引：0，他引：1  

Pascale Defraigne  Carine Bruyninx 《GPS Solutions》2001,5(2):43-50

The International Atomic Time scale (TAI) is computed by the Bureau International des Poids et Mesures (BIPM) from a set of atomic clocks distributed in about 40 time laboratories around the world. The time transfer between these remote clocks is mostly performed by the so-called GPS common view method: The clocks are connected to a GPS time receiver whose internal software computes the offsets between the remote clocks and GPS time. These data are collected in a standard formal called CCTF. In the present study we develop both the procedure and the software tool that allows us to generate the CCTF files needed for time transfer to TAI, using RINEX files produced by geodetic receivers driven by an external frequency. The CCTF files are then generated from the RINEX observation files. The software is freely available at ftp://omaftp.oma.be/dist/astro/time/RINEX_CCTF. Applied to IGS (International GPS Service) receivers, this procedure will provide a direct link between TAI and the IGS clock combination. We demonstrate here the procedure using the RINEX files from the Ashtech Metronome (ZXII-T) GPS receiver, to which we apply the conventional analysis to compute the CCTF data. We compared these results with the CCTF files produced by a time receiver R100-30T from 3S-Navigation. We also used this comparison with the results of a calibrated time receiver to determine the hardware delay of the geodetic receiver. ? 2001 John Wiley & Sons, Inc.  相似文献   

Marée de l'écorce: L'effet du dephasage dans l'analyse des observations     

J. Metzger 《Pure and Applied Geophysics》1954,29(1):71-83

Résumé L'amplitude relativeA de la marée de l'écorce se déduit du rapport entre les variations de pesanteur théorique et observée. La comparaison directe de leurs valeurs horaires permet de déterminer ce rapport, mais cette méthode néglige le déphasage éventuel de la marée de l'écorce par rapport aux forces génératrices. L'erreur (négative) qui en résulte sur les valeurs habituelles deA est d'environ 11% (en supposant un déphasage de 1 h), si l'on compare uniquement les amplitudes extrêmes; elle atteint 14% si l'on tient compte de l'ensemble des valeurs horaires.Si l'effet du déphasage se fait peu ressentir aux heures où la marée est importante, on conçoit qu'il introduise une erreur relative considérable sur les valeurs horaires correspondant à une marée faible. Le calcul montre cependant qu'on n'améliore guère lè résultat global en éliminant systématiquement ces dernières.

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Summary The relative amplitudeA of the earth tide is deduced from the ratio of the theoretical variations of gravity to the observed. The direct comparison of their hourly values allows the determination of this ratio, but this method neglects the eventual dephasing of the earth tide over the generating forces. The resulting (negative) error on the usual values ofA is about 11% (supposing a dephasing of 1 hour), if only extreme amplitudes are compared; it reaches 14% if the totality of the hourly values is taken into account.If the effect of the dephasing is slight at the hours when the tide has a great value, it is conceivable that it introduces a noticeable relative error on the hourly readings corresponding to a low value. The computation shows nevertheless that the total result is little improved by systematic elimination of the latter.

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