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1.
Abstract— It has now been about a decade since the first demonstrations that hypervelocity particles could be captured, partially intact, in aerogel collectors. But the initial promise of a bonanza of partially‐intact extraterrestrial particles, collected in space, has yet to materialize. One of the difficulties that investigators have encountered is that the location, extraction, handling and analysis of very small (10 μm and less) grains, which constitute the vast majority of the captured particles, is challenging and burdensome. Furthermore, current extraction techniques tend to be destructive over large areas of the collectors. Here we describe our efforts to alleviate some of these difficulties. We have learned how to rapidly and efficiently locate captured particles in aerogel collectors, using an automated microscopic scanning system originally developed for experimental nuclear astrophysics. We have learned how to precisely excavate small access tunnels and trenches using an automated micromanipulator and glass microneedles as tools. These excavations are only destructive to the collector in a very small area—this feature may be particularly important for excavations in the precious Stardust collectors. Using actuatable silicon microtweezers, we have learned how to extract and store “naked” particles—essentially free of aerogel—as small as 3 μm in size. We have also developed a technique for extracting particles, along with their terminal tracks, still embedded in small cubical aerogel blocks. We have developed a novel method for storing very small particles in etched nuclear tracks. We have applied these techniques to the extraction and storage of grains captured in aerogel collectors (Particle Impact Experiment, Orbital Debris Collector Experiment, Comet‐99) in low Earth orbit.  相似文献   
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This paper deals with the formation processes and the palaeoenvironmental significance of relict slope deposits located on the uppermost part of the north Portugal mountains. For this purpose, seven key sites representative of the different lithofacies have been selected and analysed in detail. The data show that three main dynamic processes are responsible for the emplacement of regional fossil slope deposits: runoff, debris flows and dry grain flows. The ubiquity of these processes and the lack of frost‐related features or landforms do not support the existence of severe Pleistocene climates in this part of the lberian Peninsula as postulated by previous work. Pedological data gathered at one of the study sites show that a subalpine environment was probably present at 700–800 m altitude between 29 and 14 kyr. Using data from the Pyrenees Mountains, a 6.5 to 12°C depression in mean annual temperature has been tentatively postulated for this Pleniglacial period. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
4.
This paper studies the long period variations of the eccentricity vector of the orbit of an artificial satellite, under the influence of the gravity field of a central body. We use modified orbital elements which are non-singular at zero eccentricity. We expand the long periodic part of the corresponding Lagrange equations as power series of the eccentricity. The coefficients characterizing the differential system depend on the zonal coefficients of the geopotential, and on initial semi-major axis, inclination, and eccentricity. The differential equations for the components of the eccentricity vector are then integrated analytically, with a definition of the period of the perigee based on the notion of “free eccentricity”, and which is also valid for circular orbits. The analytical solution is compared to a numerical integration. This study is a generalization of (Cook, Planet. Space Sci., 14, 1966): first, the coefficients involved in the differential equations depend on all zonal coefficients (and not only on the very first ones); second, our method applies to nearly circular orbits as well as to not too eccentric orbits. Except for the critical inclination, our solution is valid for all kinds of long period motions of the perigee, i.e., circulations or librations around an equilibrium point.  相似文献   
5.
Recent research on the Somme Valley terrace deposits, that began in 1987, has resulted in an integrated sequence of geological and geomorphological evidence for this area that is of particular significance for prehistoric investigations. This has been achieved using previous evidence and new results from archaeological and geological excavations. These include longitudinal profiles, cartography and detailed synthesis of sections of alluvial deposits, stratigraphy of river deposits and overlying loess sequences. The work, based on a study of the geometry of the terrace system, has resulted in the identification of ninestepped alluvial formations that occur along 70 km of the valley. Detailed study permits the integration of the various alluvial sequences. This suggests that each alluvial sequence results from sedimentation through a single glacial-interglacial climatic cycle. This hypothesis is confirmed by investigation of soil and loess sequences of the deposits overlying the fluvial sediments. The synthesis presented provides a basis for understanding the deposition of the terrace system and an initial chronostratigraphic interpretation for the deposits.  相似文献   
6.
Ocean surface mixing and drift are influenced by the mixed layer depth, buoyancy fluxes and currents below the mixed layer. Drift and mixing are also functions of the surface Stokes drift Uss, volume Stokes transport TS, a wave breaking height scale Hswg, and the flux of energy from waves to ocean turbulence Φoc. Here we describe a global database of these parameters, estimated from a well-validated numerical wave model, that uses traditional forms of the wave generation and dissipation parameterizations, and covers the years 2003–2007. Compared to previous studies, the present work has the advantage of being consistent with the known physical processes that regulate the wave field and the air–sea fluxes, and also consistent with a very large number of in situ and satellite observations of wave parameters. Consequently, some of our estimates differ significantly from previous estimates. In particular, we find that the mean global integral of Φoc is 68 TW, and the yearly mean value of TS is typically 10–30% of the Ekman transport, except in well-defined regions where it can reach 60%. We also have refined our previous estimates of Uss by using a better treatment of the high frequency part of the wave spectrum. In the open ocean, Uss  0.013U10, where U10 is the wind speed at 10 m height.  相似文献   
7.
A mixture of C33–C37 botryococcenes and partially reduced derivatives was isolated from ca. 32,000 year old sediment from Lake Masoko, a freshwater crater lake in the Rungwe Range area (Tanzania). Botryococcenes and derivatives accounted for 246 μg/g dry sediment and for >92% of the hydrocarbon fraction; 1D and 2D nuclear magnetic resonance spectroscopy (NMR) and mass spectrometry allowed the structure of the dominant botryococcene (43% of hydrocarbon fraction) to be established, after purification using high performance liquid chromatography (HPLC). The compound is a novel tetraunsaturated dicyclic C34 botryococcene and is named C34 masokocene. Overall, the structures of six other novel botryococcenes and four partially reduced derivatives were tentatively assigned. The structures of the new biomarkers, three dicyclic C34–C36 botryococcenes (or masokocenes) and seven monocyclic C34–C37 analogues are discussed along with their biosynthetic relationship. The high abundance of such polyunsaturated compounds preserved in 32,000 year old sediment from the lake indicates an aquatic ecosystem dominated at the time by the green alga Botryococcus braunii, as well very good preservation of the organic matter.  相似文献   
8.
Non-conservative behavior of dissolved inorganic phosphate (DIP) in estuaries is generally ascribed to desorption from iron and aluminum (hydr)oxides with increasing salinity. Here, we assess this hypothesis by simulating the reversible adsorption of phosphate onto a model oxide (goethite) along physico-chemical gradients representative of surface and subsurface estuaries. The simulations are carried out using a surface complexation model (SCM), which represents the main aqueous speciation and adsorption reactions of DIP, plus the ionic strength-dependent coulombic interactions in solution and at the mineral-solution interface. According to the model calculations, variations in pH and salinity alone are unlikely to explain the often reported production of DIP in surface estuaries. In particular, increased aqueous complexation of phosphate by Mg2+ and Ca2+ ions with increasing salinity is offset by the formation of ternary Mg-phosphate surface complexes and the drop in electrical potential at the mineral-water interface. However, when taking into account the downstream decrease in the abundance of sorption sites, the model correctly simulates the observed release of DIP in the Scheldt estuary. The sharp increase in pH accompanying the admixing of seawater to fresh groundwater should also cause desorption of phosphate from iron oxyhydroxides during seawater intrusion in coastal aquifers. As for surface estuaries, the model calculations indicate that significant DIP release additionally requires a reduction in the phosphate sorption site density. In anoxic aquifers, this can result from the supply of seawater sulfate and the subsequent reductive dissolution of iron oxyhydroxides coupled to microbial sulfate reduction.  相似文献   
9.
Column experiments, simulating the behavior of passive treatment systems for acid mine drainage, have been performed. Acid solutions (HCl or H2SO4, pH 2), with initial concentrations of Fe(III) ranging from 250 to 1500 mg L−1, were injected into column reactors packed with calcite grains at a constant flow rate. The composition of the solutions was monitored during the experiments. At the end of the experiments (passivation of the columns), the composition and structure of the solids were measured. The dissolution of calcite in the columns caused an increase in pH and the release of Ca into the solution, leading to the precipitation of gypsum and Fe–oxyhydroxysulfates (Fe(III)–SO4–H+ solutions) or Fe–oxyhydroxychlorides (Fe(III)–Cl–H+ solutions). The columns worked as an efficient barrier for some time, increasing the pH of the circulating solutions from 2 to 6–7 and removing its metal content. However, after some time (several weeks, depending on the conditions), the columns became chemically inert. The results showed that passivation time increased with decreasing anion and metal content of the solutions. Gypsum was the phase responsible for the passivation of calcite in the experiments with Fe(III)–SO4–H+ solutions. Schwertmannite and goethite appeared as the Fe(III) secondary phases in those experiments. Akaganeite was the phase responsible for the passivation of the system in the experiments with Fe(III)–Cl–H+ solutions.  相似文献   
10.
The S and O isotopic composition of dissolved SO4, used as a tracer for SO4 sources, was applied to the water of the Llobregat River system (NE Spain). The survey was carried out at 30 sites where surface water was sampled on a monthly basis over a period of 2a. The concentration of dissolved SO4 varied from 20 to 1575 mg L−1. Sulphur isotopic compositions clustered in two populations: one – 93% of the samples – had positive values with a mode of +9‰; the other had negative values and a mode of −5‰. Data for δ18OSO4 showed a mean value of +11‰, with no bi-modal distribution, though lower values of δ18O corresponded to samples with negative δ34S. These values can not be explained solely by the contribution of bedrock SO4 sources: that is, sulphide oxidation and the weathering of outcrops of sulphates, though numerous chemical sediments exist in the basin. Even in a river with a high concentration of natural sources of dissolved SO4, such as the Llobregat River, the δ34S values suggest that dissolved SO4 is controlled by a complex mix of both natural and anthropogenic sources. The main anthropogenic sources in this basin are fertilizers, sewage, potash mine effluent and power plant emissions. Detailed river water sampling, together with the chemical and isotopic characterisation of the main anthropogenic inputs, allowed determination of the influence of redox processes, as well as identification of the contribution of natural and anthropogenic SO4 sources and detection of spatial variations and seasonal changes among these sources. For instance, in the Llobregat River the input of fertilisers is well marked seasonally. Minimum values of δ34S are reported during fertilization periods – from January to March – indicating a higher contribution of this source. The dual isotope approach, δ34S and δ18O, is useful to better constrain the sources of SO4. Moreover, in small-scale studies, where the inputs are well known and limited, the mixing models can be enhanced and the contribution of the different sources can be quantified to some extent.  相似文献   
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