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1.
利用粉煤灰合成沸石及其去除水中重金属的实验研究 总被引：8，自引：0，他引：8
在水热条件下直接对粉煤灰进行晶化, 合成反应结束后得到的产物有NaP1沸石、方沸石、菱沸石三种沸石. 粉煤灰转化为单种沸石的最大转化率为40% ~ 75%左右, 总转化率达60% ~ 80%左右. 实验结果表明, 合成体系中的涡流、粘度以及温度、时间、NaOH浓度等参数对合成沸石品种及转化率影响较大. 利用合成沸石去除水中Cu2+, Pb2+和Cd2+分批实验表明, 合成沸石对重金属的吸附容量比粉煤灰的高. 相似文献
2.
Synthesis of zeolites using fly ash and their application in removing heavy metals from waters 总被引：1，自引：0，他引：1
Fly ash is the solid waste of thermal power plants where coal is used as fuel, and its management and utilization have been of environmental concern for decades. Since the technique of synthesizing zeolite from coal fly ash was introduced by Holler[1] (19… 相似文献
3.
The incidence of power station emissions in the composition of the atmospheric aerosols in an urban-industrial area is presented in this study. The Iberdrola (Spanish electrical company) thermoelectric power station is located at Castellon's industrial estate along the Spanish Mediterranean coast. Due to the fact that there are other polluting industries in this region, the present study is also helpful to investigate potential tracers to discriminate the origin and source of particular pollution events. The analysis of air particulate samples, collected on cellulose membrane filters, was carried out by means of the following instrumentation: (1) mineralogical analysis by X-ray diffraction (XRD), (2) morphological study by scanning electron microscopy (SEM/EDX), and (3) chemical analysis by inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS), to carry out quantitative chemical analyses of both major and trace elements. This analysis has allowed the authors to find marker elements, V and Zn, for the power station emissions. 相似文献
4.
J. L. Fernndez-Turiel M. E. Durn X. Querol A. Lpez-Soler 《Journal of Geochemical Exploration》1992,43(3)
The scheelite dispersion was studied in a drainage system over an area of 150 km2 with stratabound mineralization of scheelite in a Pre-Ordovician volcano-sedimentary Series in the Hercynian Iberian Massif (Zamora province, NW Spain). A density of two samples per square kilometer (approximately 500 m sample spacing along streams), a sample volume of 10 l and sieving at 5 mm ensure that an anomaly source is detected. It was found that the dispersion of scheelite is typically less than 1 km. The methods applied to panned concentrates (mineralometric scheelite study, with or without multifractional grain size basis, and X-ray fluorescence tungsten analysis) give similar anomaly patterns and are efficient in exploration for scheelite mineralization. 相似文献
5.
The insular suburban site of Castillo de Bellver was selected for the study of the variability of PM levels and composition in the Western Mediterranean Basin (WMB).Mean annual (in 2004) PM10 and PM2.5 levels at this site were 29 and 20 µg/m3, respectively. These levels may be regarded as relatively low when compared with other suburban insular locations in the Eastern Mediterranean Basin (EMB), but they are higher than those recorded at most of the European suburban sites, especially in Northern and Western Europe. Seasonal variability of PM levels at this site is governed by meteorology rather than local emissions, whereas the daily cycles are clearly defined by the anthropogenic emissions, mainly coming from the urban area of Palma de Mallorca and the harbour area of the same city.Concerning the aerosol composition at this site, the main PM constituent is the mineral matter (29% in PM10 and 16 % in PM2.5), more than 50% (in PM10) being attributable to African dust. The amount of secondary inorganic aerosols is also very high (27% in PM10 and 34% in PM2.5), with the predominance of fine ammonium sulphate, and in a less proportion fine ammonium nitrate (in winter) and coarse Ca and Na nitrate (with higher importance in summer). The carbonaceous particles, dominantly fine, account for 17% of PM10 and 25% of PM2.5. The elemental carbon/organic carbon (EC/OC) ratio reached a mean value of 0.17, similar to those observed at regional background sites in the WMB coast of Spain. The sea spray aerosols (mainly coarse) represented around 10% of PM10, and only 4% in PM2.5. Finally, the unaccounted fraction increased from 15% to 20% in PM2.5, being mostly attributed to water.The concentrations of trace elements in PM10 and PM2.5 were usually in the range to those observed in regional background sites in the Iberian Peninsula, with the exception of the typical tracers of road traffic such as Cu, Sb, Zn, Sn and Ba, which presented concentrations in the range of urban sites of Iberia. Other elements such as Cr, Zr, Hf and Co have been identified as the main tracers of the harbour contributions. 相似文献
6.
B‐bar based algorithm applied to meshfree numerical schemes to solve unconfined seepage problems through porous media 
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下载免费PDF全文 The object of this work is to establish a meshfree framework for solving coupled, steady and transient problems for unconfined seepage through porous media. The Biot's equations are formulated in displacements (or u − w) assuming an elastic solid skeleton. The free surface location and its evolution in time are obtained by interpolation of pore water pressures throughout the domain. Shape functions based on the principle of local maximum entropy are chosen for the meshfree approximation schemes. In order to avoid the locking involved in the fluid phase of the porous media, a B‐bar based algorithm is devised to compute the average volumetric strain in a patch composed of various integration points. The efficiency of such an implementation for one phase problems is shown through the Benchmark problem, Cook's membrane loaded by a distributive shear load. The proposed methodology is firstly applied to various classical examples in unconfined steady seepage problems through earth dams, then to the dynamic consolidation of a soil column. The results obtained for both problems are quite satisfactory and demonstrate the feasibility of the proposed method in solving coupled problems in porous media. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
7.
A. Alastuey A. Jimnez F. Plana X. Querol I. Surez-Ruiz 《International Journal of Coal Geology》2001,45(4)
This study is focused on the occurrence and distribution of mineral matter and major and trace elements in the high volatile bituminous coal from Puertollano (south-central Spain). The relationship between ash behaviour and inorganic composition, as well as the possible formation of fouling and slagging deposits in boilers during the conversion process, were investigated. The Puertollano coals do not exhibit plastic properties, despite their rank, probably because of their high ash and inertinite contents.The Puertollano coal has medium to low total S content (0.48% to 1.63% db, with a mean of 1.0% db) and is characterised by relatively high contents of Si, Pb, Sb, and Cs. Some elements such as As, Cd, Co, Cr, Cu, Ge, Li, Mn, Ni, W, and Zn are also present in relatively high contents. The enrichment in a number of heavy metals could be attributed to the common sulphide ores occurring near the Puertollano coal deposit.The following trace elements affinities are deduced: (a) sulphide affinity: As, Co, Cd, Cu, Ni, Sb, Tl, and Zn; (b) aluminum–silicate affinity: K, Ti, B, Co, Cr, Cs, Cu Ga, Hf, Li, Nb, Rb, Sn, Ta, Th, V, Zr, and LREE; (c) Carbonate affinity: Ca, Mg, Mn, and B; (d) organic affinity: B.The very high Si levels and the anomalous enrichment in Cs, Ge, Pb, Sb, and Zn shown by the Puertollano coals account for the high contents of these elements in the Puertollano fly ash when compared with the other Spanish coal fly ashes.The chemical composition of the high temperature ash (HTA) is consistent with the trend shown by the ash fusion temperatures (AFT) and also with the predictive indices related to slagging and fouling propensities. Thus, the ash fusion temperatures increase with high values of Al2O3 as well as with the decrease in Fe2O3, CaO, and MgO. 相似文献
8.
A. M. Díaz J. P. Díaz F. J. Expósito P. A. Hernández-Leal D. Savoie X. Querol 《Journal of Atmospheric Chemistry》2006,53(1):63-90
The dynamics and the aerosol chemistry of the air masses reaching the free troposphere of the subtropical Northeast Atlantic region during the period 1995–98 have been studied. Seven days backward trajectories were calculated daily with HYSPLIT-4 model for Izaña Global Atmospheric Watch (GAW) Observatory (28.3°N 16.5°W, 2367 m a.s.l.). These back-trajectories were classified by means of a k-means clustering strategy. The daily air masses have been coded using 16 variables to detect the aerosol load of each one of them. Four clusters were found: Cluster 1, representative of Atlantic oceanic middle troposphere air masses, (OMT), has an average frequency of occurrence of 50.6%. Cluster 2, which includes air masses originated in the African continent (AfD), has been recorded in a 19.8% of time. Cluster 3 represents a mixture at least of two of the next sources: Europe, Africa and Ocean, (EAM), with a frequency of 12.7%. Finally, Cluster 4 includes air masses with a high load of maritime aerosols, (MaA), and it has been detected in a 16.9%. An analysis of four aerosol components: NO3 ?, NH4 +, non-sea-salt-SO4 2?, and mineral dust and its relation with the origin and transport of the air masses have been done. The highest quantities of mineral dust and nss-SO4 2? are linked with African air masses with a mean value of 86.5 and 1.9 μg/m3 respectively. Whereas the highest levels of NO3 ?, 1.0 μg/m3, and NH4 +, 0.4 μg/m3, were obtained for AfD and EAM. The lowest levels were associated with OMT and MaA air masses types: 12.7, 0.6, 0.2, and 0.5 μg/m3 for dust, NO3 ?, NH4 +, and nss-SO4 2? in average for the four studied years. However, it is remarkable that the values of the median for dust are 2.2 and 3.5 μg/m3 in clusters MaA and OMT respectively. Using non-parametric statistical tests the distributions of concentrations in each cluster by year have been compared in order to detect similarities. The results show that the aerosol loads of OMT and MaA air masses are quite similar and the same occurs for AfD and EAM air masses. However, the correlation analysis between the levels of anions and ammonium evidenced important differences among the air mass types. In AfD air masses is clear a low correlation between levels of nss-SO4 2? and NH4 + (r 2 = 0.08) suggesting that the sulfate speciation was dominated by sulfate species others than ammonium sulfate, such as calcium sulfate. CaSO4 ?2H2O (gypsum) is mainly present in the coarse mode, where the radiative effects of sulfate are less important that in the accumulative mode. For OMT air masses is noticeable an important increasing on the correlation between the levels of anions and those of NH4 + for the two last years of the study period (1997–1998, r 2 = 0.61 –0.85%) with respect to the first ones (1995–1996, r 2 = 0.25–0.49%), coinciding with the second strongest ENSO (El Niño Southern Oscillation) event recorded. This behavior indicates a change in the speciation of the aerosol component. 相似文献
9.
A new constitutive law for the behaviour of undrained sand subjected to dynamic loading is presented. The proposed model works for small and large strain ranges and incorporates contractive and dilative properties of the sand into the unified numerical scheme. These features allow to correctly predict liquefaction and cyclic mobility phenomena for different initial relative densities of the soil. The model has been calibrated as an element test, by using cyclic simple shear data reported in the literature. For the contractive sand behaviour a well‐known endochronic densification model has been used, whereas a plastic model with a new non‐associative flow rule is applied when the sand tends to dilate. Both dilatancy and flow rule are based on a new state parameter, associated to the stiffness degradation of the material as the shaking goes on. Also, the function that represents the rearrangement memory of the soil takes a zero value when the material dilates, in order to easily model the change in the internal structure. Proceeding along this kind of approach, liquefaction and cyclic mobility are modelled with the same constitutive law, within the framework of a bi‐dimensional FEM coupled algorithm developed in the paper. For calibration purposes, the behaviour of the soil in a cyclic simple shear test has been simulated, in order to estimate the influence of permeability, frequency of loading, and homogeneity of the shear stress field on the laboratory data. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
10.
M. Escudero A.F. Stein R.R. Draxler X. Querol A. Alastuey S. Castillo A. Avila 《Atmospheric Research》2011,99(3-4):518-527
A source apportionment technique has been applied to determine the geographical distribution of emissions in Northern Africa contributing to dust outbreaks that yield high PM10 levels at Spanish regional background stations. Seven dust episodes have been analyzed in this study. Total suspended particles have been sampled and chemically analyzed for these events at La Castanya background station (Montseny, NE Spain) and differences in the composition of airborne dust have been studied. The dominant role of northern and western source areas (Tunisia, Algeria, Mauritania and the Western Sahara) contrasted with the negligible contribution of major emission source areas such as the Bodelé depression, Libya, Niger, and Sudan. During the simulated events using the dust module of the HYSPLIT model, material from the latter regions is persistently transported across the Atlantic but not towards Western Europe. As a consequence, the composition of the dust turned out to be quite homogeneous since the mixing of dust occurs from various source areas with similar chemical composition. However, differences in Ca/Al ratios have been found in a number of samples that are mainly explained by vertical transport segregation of clay minerals (relatively richer in Al) from coarser dust particles (Ca-carbonate). 相似文献