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World-wide intercomparison runs has made possible the certification of two new Polish geological-environmental reference materials for multi-element trace analysis: Apatite Concentrate (CTA-AC-1) and Fine Fly Ash (CTA-FFA-1). "Recommended values' are established for 25 (CTA-AC-1) and 40 (CTA-FFA-1) elements respectively. In addition, "information values' are assigned for 12 elements in CTA-AC-1 and 10 elements in CTA-FFA-1. Our method of data evaluation has been further improved and a modified version of criteria for assigning recommended and information values is proposed.  相似文献   
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Ground Surface Temperature (GST) history in Poland was derived from the inversion of temperature-depth profiles in over 20 wells. Temperature histories for the period 1500 A.D. through 1977 A.D. agree well with the instrumental record of the surface-air temperature available for the last two centuries. A statistical correlation of the reconstructed histories (from the well temperature data) with the instrumental record (air temperature) from the homogeneous Warsaw series is high (>0.8). Functional space inversion (FSI) of the temperature data with depth shows that beginning in the early 19th century, temperatures warmed by 0.9 ± 0.1°C following a long period of colder climate before. The last number could be a minimal as higher warming was calculated using a simple model based on surface temperature for the observational period (homogenized Warsaw surface temperature series, Lorenc, 2000) and POM (pre-observational mean; Harris and Chapman, 1998) of –1.53oC below the 1951–1980 mean temperature level.  相似文献   
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Maize is grown by millions of smallholder farmers in South Asia (SA) under diverse environments. The crop is grown in different seasons in a year with varying exposure to weather extremes, including high temperatures at critical growth stages which are expected to increase with climate change. This study assesses the impact of current and future heat stress on maize and the benefit of heat-tolerant varieties in SA. Annual mean maximum temperatures may increase by 1.4–1.8 °C in 2030 and 2.1–2.6 °C in 2050, with large monthly, seasonal, and spatial variations across SA. The extent of heat stressed areas in SA could increase by up to 12 % in 2030 and 21 % in 2050 relative to the baseline. The impact of heat stress and the benefit from heat-tolerant varieties vary with the level of temperature increase and planting season. At a regional scale, climate change would reduce rainfed maize yield by an average of 3.3–6.4 % in 2030 and 5.2–12.2 % in 2050 and irrigated yield by 3–8 % in 2030 and 5–14 % in 2050 if current varieties were grown under the future climate. Under projected climate, heat-tolerant varieties could minimize yield loss (relative to current maize varieties) by up to 36 and 93 % in 2030 and 33 and 86 % in 2050 under rainfed and irrigated conditions, respectively. Heat-tolerant maize varieties, therefore, have the potential to shield maize farmers from severe yield loss due to heat stress and help them adapt to climate change impacts.  相似文献   
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The collapse of a section of the cliff at Stevns Klint, Denmark in 1986 provided a unique opportunity to collect about 50 kg of Fish Clay representing the Cretaceous-Tertiary (K-T) boundary layer. In this paper, details of the preparation of this sample are presented, together with preliminary analytical results to support the development of this sample as a reference material, particularly for the determination of iridium and the other platinum-group elements in clays and sediments associated with K-T boundary studies and in other environmental samples collected to study the effects of automobile exhaust catalysts.  相似文献   
5.
Despite much progress over the past years in fundamental gas hydrate research, frontiers to the unknown are the early beginning and early decomposition of gas hydrates in their natural, submarine environment: gas bubbles meeting ocean water and forming hydrate, and gas starting to escape from the surface of a hydrate grain. In this paper we report on both of these topics, and present three-dimensional microstructure results obtained by synchrotron radiation X-ray cryo-tomographic microscopy (SRXCTM). Hydrates can precipitate when hydrate-forming molecules such as methane exceed solubility, and combine with water within the gas hydrate stability zone. Here we show hydrate formation on surfaces of bubbles from different gas mixtures and seawater, based on underwater robotic in situ experiments in the deep Monterey Canyon, offshore California. Hydrate begins to form from the surrounding water on the bubble surfaces, and subsequently grows inward into the bubble, evidenced by distinct edges. Over time, the bubbles become smaller while gas is being incorporated into newly formed hydrate. In contrast, current understanding has been that hydrate decomposition starts on the outer surface of hydrate aggregates and grains. It is shown that in an early stage of decomposition, newly found tube structures connect well-preserved gas hydrate patches to areas that are dissociating, demonstrating how dissociating areas in a hydrate grain are linked through hydrate that is still intact and will likely decompose at a later stage.
Figure
The boundaries of a gas hydrate grain: excepting for the matrix (transparent, not shown), one can see tubular structures, pores from decomposition, and bubbles.  相似文献   
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The ‘low’ in the transient temperature versus depth borehole profiles around 120 m seen from deep temperature logs in the Canadian Prairies (southern Alberta–southern Saskatchewan), as well as in some of the European data, has been interpreted to be related to the Little Ice Age (LIA). Data point to the lowest ground surface and subsurface temperatures occurring in the very late eighteenth to nineteenth centuries. Inversion of these logs shows that surface temperature lows were followed by a recent warming period. Further, the synthetic profiles built on the basis of solar forcing history, stretching as far back as the beginning of the seventeenth century, suggest that the LIA signatures interpreted from the inversion of the borehole temperature logs would be difficult to be explained by known published models of past solar irradiation despite large range of assumed sensitivities for the couplings assumed, and that further forcing needs to be considered.  相似文献   
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