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1.
Water solubility in orthopyroxene 总被引：7，自引：0，他引：7
The solubility of water in pure enstatite was measured on samples synthesized at 1,100 °C and pressures to 100 kbar. Enstatite crystals were grown under water-saturated conditions from a stoichiometric mixture of high-purity SiO2 and Mg(OH)2. Water contents were calculated from polarized FTIR spectra measured on oriented single crystals. The water solubility in orthoenstatite increases with pressure to 867ᆷ ppm H2O by weight at 75 kbar. At 100 kbar, in the stability field of high-clinoenstatite, a water solubility of 714ᆷ ppm was observed. The water solubility in enstatite at 1,100 °C can be described by the equation cH2O=AfH2O exp(-P(V/RT), where fH2O is water fugacity, A=0.0204 ppm/bar and (V=12.3 cm3/mol. The infrared spectra of the hydrous enstatite crystals show a sharp, intense band at 3,363 cm-1 and a broad, weaker band at 3,064 cm-1. Both bands are strongly polarized parallel c. Most likely, pairs of protons attached to non-bridging oxygen atoms substitute for Mg2+. In order to investigate the effect of chemical impurities on water solubility in enstatite, an additional series of experiments was carried out with gels doped with Al, B, or Li as starting material. Whereas, the presence of Li and B had no detectable effect on water solubility, the addition of about 1 wt% Al2O3 increased water solubility in enstatite from 199 to 1,100 ppm at 1,100°C and 15 kbar. In the infrared spectra of these aluminous samples, additional bands occur in the range from 3,450 to 3,650 cm-1. Similar bands are also observed in natural, aluminous orthopyroxenes and are most likely caused by protons coupled with Al according to the substitution of Al3++H+ for Si4+. A series of hydrous annealing experiments on a natural, gem-quality aluminous enstatite from Tanzania yielded water solubilities generally consistent with the results from the synthetic model systems. The results presented here imply that pure enstatite has a similar storage capacity for water as olivine; however, aluminous orthopyroxenes in the mantle may dissolve much larger amounts of water comparable with the entire mass of the present hydrosphere. Moreover, the mechanism of aluminum substitution in orthopyroxenes, i.e., the distribution of Al between tetrahedral and octahedral sites, may be a potential probe of water fugacity. 相似文献
2.
S. Klimov S. Romanov E. Amata J. Blecki J. Büchner J. Juchniewicz J. Rustenbach P. Triska L. J. C. Woolliscroft S. Savin Yu. Afanas’yev U. de Angelis U. Auster G. Bellucci A. Best F. Farnik V. Formisano P. Gough R. Grard V. Grushin G. Haerendel V. Ivchenko V. Korepanov H. Lehmann B. Nikutowski M. Nozdrachev S. Orsini M. Parrot A. Petrukovich J. L. Rauch K. Sauer A. Skalsky J. Slominski J. G. Trotignon J. Vojta R. Wronowski 《Annales Geophysicae》1997,15(5):514-527
The plasma-wave experiment ASPI (analysis of spectra of plasma waves and instabilities) on board the INTERBALL spacecraft is a combined wave diagnostics experiment. It performs measurements of the DC and AC magnetic field vector by flux-gate and searchcoil sensors, the DC and AC electric field vector by Langmuir double probes and the plasma current by Langmuir split probe. Preliminary data analysis shows the low noise levels of the sensors and the compatibility of new data with the results of previous missions. During several months of in-orbit operation a rich collection of data was acquired, examples of which at the magnetopause and plasma sheet are presented in second part of the paper. 相似文献
3.
S. Savin A. Skalsky L. Zelenyi L. Avanov N. Borodkova S. Klimov V. Lutsenko E. Panov S. Romanov V. Smirnov YU. Yermolaev P. Song E. Amata G. Consolini T. A. Fritz J. Buechner B. Nikutowski J. Blecki C. Farrugia N. Maynard J. Pickett J. A. Sauvaud J. L. Rauch J. G. Trotignon Y. Khotyaintsev K. Stasiewicz 《Surveys in Geophysics》2005,26(1-3):95-133
We present both statistical and case studies of magnetosheath interaction with the high-latitude magnetopause on the basis of Interball-1 and other ISTP spacecraft data. We discuss those data along with recently published results on the topology of cusp-magnetosheath transition and the roles of nonlinear disturbances in mass and energy transfer across the high-latitude magnetopause. For sunward dipole tilts, a cusp throat is magnetically open for direct interaction with the incident flow that results in the creation of a turbulent boundary layer (TBL) over an indented magnetopause and downstream of the cusp. For antisunward tilts, the cusp throat is closed by a smooth magnetopause; demagnetized ‘plasma balls’ (with scale ∼ few RE, an occurrence rate of ∼25% and trapped energetic particles) present a major magnetosheath plasma channel just inside the cusp. The flow interacts with the ‘plasma balls’ via reflected waves, which trigger a chaotization of up to 40% of the upstream kinetic energy. These waves propagate upstream of the TBL and initiate amplification of the existing magnetosheath waves and their cascade-like decays during downstream passage throughout the TBL. The most striking feature of the nonlinear interaction is the appearance of magnetosonic jets, accelerated up to an Alfvenic Mach number of 3. The characteristic impulsive local momentum loss is followed by decelerated Alfvenic flows and modulated by the TBL waves; momentum balance is conserved only on time scales of the Alfvenic flows (1/fA
∼12 min). Wave trains at fA∼1.3 mHz are capable of synchronizing interactions throughout the outer and inner boundary layers. The sonic/Alfvenic flows, bounded by current sheets, control the TBL spectral shape and result in non-Gaussian statistical characteristics of the disturbances, indicating the fluctuation intermittency. We suggest that the multi-scale TBL processes play at least a comparable role to that of macro-reconnection (remote from or in the cusp) in solar wind energy transformation and population of the magnetosphere by the magnetosheath plasma. Secondary micro-reconnection constitutes a necessary chain at the small-scale (∼ion gyroradius) edge of the TBL cascades. The thick TBL transforms the flow energy, including deceleration and heating of the flow in the open throat, ‘plasma ball’ and the region downstream of the cusp. 相似文献
4.
Kevin P. Rauch & Brian Ingalls 《Monthly notices of the Royal Astronomical Society》1998,299(4):1231-1241
It has recently been shown by Rauch 38 Tremaine that the rate of angular momentum relaxation in nearly Keplerian star clusters is greatly increased by a process termed 'resonant relaxation'; it was also argued, via a series of scaling arguments, that tidal disruption of stars in galactic nuclei containing massive black holes could be noticeably enhanced by this process. We describe here the results of numerical simulations of resonant tidal disruption which quantitatively test the predictions made by Rauch 38 Tremaine. The simulation method is based on an N -body routine incorporating cloning of stars near the loss cone and a semirelativistic symplectic integration scheme. Normalized disruption rates for resonant and non-resonant nuclei are derived at orbital energies both above and below the critical energy, and the corresponding angular momentum distribution functions are found. The black hole mass above which resonant tidal disruption is quenched by relativistic precession is determined. We also briefly describe the discovery of chaos in the Wisdom–Holman symplectic integrator applied to highly eccentric orbits and propose a modified integration scheme that remains robust under these conditions. We find that resonant disruption rates exceed their non-resonant counterparts by an amount consistent with the predictions; in particular, we estimate the net tidal disruption rate for a fully resonant cluster to be about twice that of its non-resonant counterpart. No significant enhancement in rates is observed outside the critical radius. Relativistic quenching of the effect is found to occur for hole masses M > M Q = (8 ± 3) × 107 M . The numerical results combined with the observed properties of galactic nuclei indicate that for most galaxies the resonant enhancement to tidal disruption rates will be very small. 相似文献
5.
J.A. Breier C.G. Rauch K. McCartney B.M. Toner S.C. Fakra S.N. White C.R. German 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(9):1579-1589
To enable detailed investigations of early stage hydrothermal plume formation and abiotic and biotic plume processes we developed a new oceanographic tool. The Suspended Particulate Rosette sampling system has been designed to collect geochemical and microbial samples from the rising portion of deep-sea hydrothermal plumes. It can be deployed on a remotely operated vehicle for sampling rising plumes, on a wire-deployed water rosette for spatially discrete sampling of non-buoyant hydrothermal plumes, or on a fixed mooring in a hydrothermal vent field for time series sampling. It has performed successfully during both its first mooring deployment at the East Pacific Rise and its first remotely-operated vehicle deployments along the Mid-Atlantic Ridge. It is currently capable of rapidly filtering 24 discrete large-water-volume samples (30–100 L per sample) for suspended particles during a single deployment (e.g. >90 L per sample at 4–7 L per minute through 1 μm pore diameter polycarbonate filters). The Suspended Particulate Rosette sampler has been designed with a long-term goal of seafloor observatory deployments, where it can be used to collect samples in response to tectonic or other events. It is compatible with in situ optical sensors, such as laser Raman or visible reflectance spectroscopy systems, enabling in situ particle analysis immediately after sample collection and before the particles alter or degrade. 相似文献
6.
EC?11481–2303 is a peculiar, hot, high-gravity pre-white dwarf. Previous optical spectroscopy revealed that it is a sdOB star with T eff=41?790 K, log?g=5.84, and He/H = 0.014 by number. We present an on-going spectral analysis by means of non-LTE model-atmosphere techniques based on high-resolution, high-S/N optical (VLT-UVES) and ultraviolet (FUSE, IUE) observations.We are able to reproduce the optical and UV observations simultaneously with a chemically homogeneous NLTE model atmosphere with a significantly higher effective temperature and lower He abundance (T eff=55?000 K, log?g=5.8, and He/H=0.0025 by number). While C, N, and O appear less than 0.15 times solar, the iron-group abundance is strongly enhanced by at least a factor of ten. 相似文献
7.
The hydrogen-deficiency in extremely hot post-AGB stars of spectral class PG1159 is probably caused by a (very) late helium-shell flash or a AGB final thermal pulse that consumes the hydrogen envelope, exposing the usually-hidden intershell region. Thus, the photospheric element abundances of these stars allow us to draw conclusions about details of nuclear burning and mixing processes in the precursor AGB stars. We compare predicted element abundances to those determined by quantitative spectral analyses performed with advanced non-LTE model atmospheres. A good qualitative and quantitative agreement is found for many species (He, C, N, O, Ne, F, Si, Ar) but discrepancies for others (P, S, Fe) point at shortcomings in stellar evolution models for AGB stars. Almost all of the chemical trace elements in these hot stars can only be identified in the UV spectral range. The Far Ultraviolet Spectroscopic Explorer and the Hubble Space Telescope played a crucial role for this research. 相似文献
8.
David T. Adamson PhD PE Grayson Uhlir BS Sharon R. Rauch BA Tessa Klein BS Anthony S. Danko PhD PE 《Ground Water Monitoring & Remediation》2021,41(3):29-40
1,4-Dioxane is a contaminant of emerging concern, and there is significant uncertainty about how its environmental occurrence in groundwater is being assessed given the various analytical methods available. This study compiled public sampling records from 2000 to 2019 that included >106,000 analyses of 1,4-dioxane from 822 different U.S. sites. The 1,4-dioxane detection frequency in the entire dataset (including all methods) was 45%, and the median detected concentration was 10 μg/L, highlighting the dilute nature of 1,4-dioxane in environmental media and the importance of selecting methods with adequate sensitivity. The annual distribution of samples analyzed by each method type confirmed a shift towards methods designed for semi-volatile compounds (Method 8270 and Method 8270 SIM) that exhibited consistently lower reporting limits (median reporting limit for each year typically ≤1 μg/L). In contrast, the method designed for volatile compounds (Method 8260) exhibited less sensitivity for 1,4-dioxane (median reporting limit per year between 40 and 100 μg/L) and its use declined significantly over time with increasing use of the moderately sensitive Method 8260 SIM in later years. This shift contributed to an increase in the 1,4-dioxane detection frequency over time, with a strong correlation between the annual detection frequency and the median reporting limit. Sites where 1,4-dioxane was analyzed but not detected overwhelmingly used less-sensitive methods that may not have been adequate for the expected concentration levels. Given the sub-μg/L groundwater criteria issued for 1,4-dioxane by some regulatory agencies, more sensitive and accurate methods will be increasingly needed to assess compliance. 相似文献
9.
Although the effectiveness of best management practices (BMPs) in reducing urban flooding is widely recognized, the improved sustainability achieved by implementing BMPs in upstream suburban areas, reducing downstream urban floods, is still debated. This study introduces a new definition of urban drainage system (UDS) sustainability, focusing on BMP usage to enhance system performance after adaptation to climate change. Three types of hydraulic reliability index (HRI) plus robustness and improvability indices were used to quantify the potential enhanced sustainability of the system in a changing climate, together with a climate change adaptability index (CCAI). The sustainability of UDS for the safe conveyance of storm-water runoff was investigated under different land-use scenarios: No BMP, BMP in urban areas, and BMP inside and upstream of urban areas, considering climate change impacts. Rainfall–runoff simulation alongside drainage network modelling was conducted using a storm-water management model (US EPA SWMM) to determine the inundation areas for both base-line and future climatic conditions. A new method for disaggregating daily rainfall to hourly, proposed to provide a finer resolution of input rainfall to SWMM, was applied to a semi-urbanized catchment whose upstream runoff from mountainous areas may contribute to the storm-water runoff in downstream urban parts. Our findings confirm an increase in the number of inundation points and reduction in sustainability indices of UDS due to climate change. The results present an increase in UDS reliability from 4% to 16% and improvements in other sustainability indicators using BMPs in upstream suburban areas compared to implementing them in urban areas. 相似文献
10.
To improve the usefulness and accuracy of modeling Earth's anthrobiogeochemical metal cycles, global maps at approximately 1° × 1° are produced of the concentrations and masses of Fe, Al, Cu, and Zn contained in continental sediments and soils. The maps generated utilize inverse distance weighting (IDW) and cokriging to generate new estimates for geospatially weighted mean global concentrations for these metallic micronutrients. Sediment metal concentration maps are generated from IDW of sediment samples; global soil maps are produced via cokriging upon an underlying parent rock dataset composed of both surface bedrock and sediment samples. Derived are independent estimates for the global mean concentrations in continental sediments (Fe = 3.1 wt.%, Al = 6.1 wt.%, Cu = 45 μg/g, Zn = 86 μg/g) and soils (Fe = 2.5 wt.%, Al = 3.9 wt.%, Cu = 17 μg/g, Zn = 50 μg/g). While continental sediment concentrations for Cu are within the range of previous estimates, Zn concentrations are relatively higher, ~ 20 μg/g above previous estimates. Fe and Al are slightly depleted (~ 1 wt.%) in continental sediments relative to previous estimates, likely ascribable to sampling bias and error inherent in the comparative methodologies. Besides an estimated global mean, metal concentrations in soils are also broken down by FAO soil group. Metal masses in sediments and soils remain within 30% of previous, non-spatial estimates. These maps also illustrate the discernable spatial variability across the Earth's surface. Despite data gaps, maps of metal mass show regional patterns such as the high quantities of Al in the soils and biomass of the Amazonia and Congo regions. Concentrations of metals are relatively high in the anthrosols of China. Finally, this analysis highlights those areas for which generating and providing publically available geochemical data should be prioritized. For instance, gypsisols, lixisols, and nitisols have little to no analytical data available on metal contents. A sensitivity analysis suggests that the most poorly constrained soil metal concentrations occur in the thick, old tropical soils of central Africa and the anthrosols of eastern China. 相似文献