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1.
A family of related Pc1-2 (0.2–10 s) discrete daytime geomagnetic pulsations is presented using pulsation data obtained at Davis, Antarctica, a typical polar-cap station. The morphological properties of IPRP and Pclb pulsation regimes, which maximize in amplitude and frequency of occurrence under the projection of the polar cusp, are examined. Furthermore, two other variations of discrete pulsation bursts yet to be named are also presented, viz IPFP (Intervals of Pulsations with Falling Period) and IPAP (Intervals of Pulsations with Alternating Period) which are observed on rare occasions. It is also suggested that the Pc1b (0.2–5 s) should be extended to incorporate Pc2b (5–10 s) which from the results in this paper are physically the same phenomenon and could be collectively classified as IPCP (Intervals of Pulsations with Constant Period).  相似文献   
2.
A one‐dimensional thermodynamic model for simulating lake‐ice phenology is presented and evaluated. The model can be driven with observed daily or hourly atmospheric forcing of air temperature, relative humidity, wind speed, cloud amount and snowfall. In addition to computing the energy balance components, key model output includes the temperature profile at an arbitrary number of levels within the ice/snow (or the water temperature if there is no ice) and ice thickness (clear ice and snow‐ice) on a daily basis, as well as freeze‐up and break‐up dates. The lake‐ice model is used to simulate ice‐growth processes on shallow lakes in arctic, sub‐arctic, and high‐boreal forest environments. Model output is compared with field and remote sensing observations gathered over several ice seasons. Simulated ice thickness, including snow‐ice formation, compares favourably with field measurements. Ice‐on and ice‐off dates are also well simulated when compared with field and satellite observations, with a mean absolute difference of 2 days. Model simulations and observations illustrate the key role that snow cover plays on the seasonal evolution of ice thickness and the timing of spring break‐up. It is also shown that lake morphometry, depth in particular, is a determinant of ice‐off dates for shallow lakes at high latitudes. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
3.
The interaction of corotating iogenic plasma with the surface of Europa in light of recent ice sputtering, experimental results, and published Voyager data has been examined. It has been found that the residual atmosphere of Europa is made up of sputtered molecular oxygen and is exospheric from the surface outwards. It was also found that if sputtering, redistribution, and escape are considered and the sulfur dioxide/water mixing ratio is held constant over a UV observing depth, the observed sulfur dioxide density on the trailing hemisphere lends support to the hypothesis that liquid water from the interior of Europa is boiling out and being deposited as a frost layer on the surface at the rate of about 0.04 μm/year.  相似文献   
4.
Anoxic nitrification: Evidence from Humber Estuary sediments (UK)   总被引:3,自引:0,他引:3  
Conventional understanding of the nitrogen cycle in marine sediments has changed in recent years with the discovery of an alternative pathway for ammonia oxidation via the reduction of manganese oxides (during anoxic nitrification). In anoxic sediments, the potential for manganese oxides to serve as oxidant for nitrification may be considerable yet previous work on manganese-rich sediments has suggested anoxic nitrification may not be significant. In this study, the potential for anoxic nitrification in a range of sediment types was investigated. Laboratory incubation of sediment from three sites on the Humber Estuary, a microbially diverse environment, showed anoxic accumulation of nitrate, nitrite and dinitrogen gas, with and without the addition of synthetic manganese oxides. Incubation experiments confirmed anoxic nitrification as microbially mediated, with heat-killed controls yielding negative results. The anoxic nitrification reaction significantly depleted ammonia concentrations, and occurred simultaneously with manganese-, iron- and sulphate reduction, and methanogenesis. Taken in conjunction with other studies, results suggest anoxic nitrification may not only be dependent on total manganese concentrations but on manganese dynamics. Anoxic nitrification may be explained as a non-steady state reaction, dependent on the recent stability of a sediment system. Physical perturbation of sediments may cause the redistribution and/or introduction of manganese oxides and promote anoxic nitrification. The significance and persistence of anoxic nitrification is likely to depend on the frequency and magnitude of sediment perturbation, which explains why the reaction varies so widely across studied sites, and why it may not occur in some manganese-rich sediment.  相似文献   
5.
Multiple Internal Reflection Fourier Transform Infra-Red (MIR-FTIR) spectroscopy was developed and used for in situ flow-through experiments designed to study the process of organic acid promoted silicate dissolution. In tandem with the FTIR analysis, ex situ X-ray scattering was used to perform detailed analyses of the changes in the surface structure and chemistry resulting from the dissolution process. Phthalic acid and forsteritic glass that had been Chemically Vapour Deposited (CVD) onto an internal reflection element were used as reactants, and the MIR-FTIR results showed that phthalic acid may promote dissolution by directly binding to exposed Mg metal ion centers on the solid surface. Integrated infrared absorption intensity as a function of time shows that phthalic acid attachment apparently follows a t1/2 dependence, indicating that attachment is a diffusive process. The diffusion coefficient of phthalic acid was estimated to be approximately 7 × 10−6 cm2 s−1 in the solution near the interface with the glass. Shifts in the infrared absorption structure of the phthalate complexed with the surface compared to the solute species indicate that phthalate forms a seven-membered ring chelate complex. This bidentate complex efficiently depletes Mg from the glass surface, such that after reaction as much as 95% of the Mg may be removed. Surface depletion in Mg causes adsorbate density to fall after an initial attachment stage for the organic ligand. In addition, the infrared analysis shows that silica in the near surface polymerizes after Mg removal, presumably to maintain charge balance. X-ray reflectivity shows that the dissolution rate of forsteritic glass at pH 4 based on Mg removal in such flow-through experiments was equal to 4 × 10−12 mol cm−2 s−1 (geometric surface area normalized). Reflectivity also shows how the surface mass density decreases during reaction from 2.64 g cm−3 to 2.2 g cm−3, consistent with preferential loss of Mg from the surface. Auxiliary batch experiments with forsteritic glass films deposited onto soda glass were also completed to add further constraints to the mechanism of reaction. By combining reflectivity with diffuse scatter measurements it is shown that the primary interface changes little in terms of atomic-scale roughness even after removal of several hundred angstroms of material. These measurements unequivocally show how a dicarboxylic acid bonds to and may chelate the dissolution of a magnesium-bearing silicate. At the molecular level the solid surface retreat may best be described by a depinning model where Mg is preferentially removed and residual silica tetrahedra polymerize and act to episodically “pin” the surface.  相似文献   
6.
The fluorescence properties of groundwaters from sites in two UK aquifers, the Penrith Sandstone of Cumbria and the Sherwood Sandstone of South Yorkshire, were investigated using excitation–emission matrix (EEM) fluorescence spectroscopy. Both aquifers are regionally important sources of public supply water and are locally impacted by pollution. The Penrith Sandstone site is in a rural setting while the Sherwood Sandstone site is in suburban Doncaster. Fluorescence analysis of samples from discrete sample depths in the Penrith Sandstone shows decreasing fulvic-like intensities with depth and also shows a good correlation with CFC-12, an anthropogenic groundwater tracer. Tryptophan-like fluorescence centres in the depth profile may also provide evidence of rapid routing of relatively recent applications of organic slurry along fractures. Fluorescence analysis of groundwater sampled from multi-level piezometers installed within the Sherwood Sandstone aquifer also shows regions of tryptophan-like and relatively higher fulvic-like signatures. The fluorescence intensity profile in the piezometers shows tryptophan-like peaks at depths in excess of 50 m and mirrors the pattern exhibited by microbial species and CFCs highlighting the deep and rapid penetration of modern recharge due to rapid fracture flow. Fluorescence analysis has allowed the rapid assessment of different types and relative abundances of dissolved organic matter (DOM), and the fingerprinting of different sources of organic C within the groundwater system. The tryptophan:fulvic ratios found in the Penrith Sandstone were found to be between 0.5 and 3.0 and are characteristic of ratios from sheep waste sources. The Sherwood Sandstone has the lowest ratios (0.2–0.4) indicating a different source of DOM, most likely a mixture of terrestrial and microbial sources, although there is little evidence of pollution from leaking urban sewage systems. Results from these two studies suggest that intrinsic fluorescence may be used as a proxy for, or complementary tool to, other groundwater investigation methods in helping provide a conceptual model of groundwater flow and identifying different sources of DOM within the groundwater system.  相似文献   
7.
Circulation on the north central Chukchi Sea shelf   总被引:8,自引:0,他引:8  
Mooring and shipboard data collected between 1992 and 1995 delineate the circulation over the north central Chukchi shelf. Previous studies indicated that Pacific waters crossed the Chukchi shelf through Herald Valley (in the west) and Barrow Canyon (in the east). We find a third branch (through the Central Channel) onto the outer shelf. The Central Channel transport varies seasonally in phase with Bering Strait transport, and is 0.2 Sv on average, although some of this might include water entrained from the outflow through Herald Valley. A portion of the Central Channel outflow moves eastward and converges with the Alaskan Coastal Current at the head of Barrow Canyon. The remainder appears to continue northeastward over the central outer shelf toward the shelfbreak, joined by outflow from Herald Valley. The mean flow opposes the prevailing winds and is primarily forced by the sea-level slope between the Pacific and Arctic oceans. Current variations are mainly wind forced, but baroclinic forcing, associated with upstream dense-water formation in coastal polynyas might occasionally be important.Winter water-mass modification depends crucially on the fall and winter winds, which control seasonal ice development. An extensive fall ice cover delays cooling, limits new ice formation, and results in little salinization. In such years, Bering shelf waters cross the Chukchi shelf with little modification. In contrast, extensive open water in fall leads to early and rapid cooling, and if accompanied by vigorous ice production within coastal polynyas, results in the production of high-salinity (>33) shelf waters. Such interannual variability likely affects slope processes and the transport of Pacific waters into the Arctic Ocean interior.  相似文献   
8.
We find that early sea urchin embryos have the capability to induce programmed cell death, or apoptosis, in response to chemical and physical stress. Strongylocentrotus purpuratus embryos (fertilized, 4 cell, 16 cell, 64 cell, and early blastula) were exposed to known cytotoxins, in order to determine when apoptosis occurs naturally and in response to stress. Using cell permeability as an indicator of early stage apoptosis, caspase activation as a mid-stage indicator, and DNA fragmentation as a late stage indicator, we find that during the cleavage stage of embryogenesis apoptosis is almost completely absent. However, a statistically significant (p<0.001) rise in apoptosis in stressed embryos is evident around 24 h after fertilization, during the early blastula stage and shortly after hatching. Before this stage, exposed embryos show no statistically significant increases in apoptosis in comparison to the controls. This pattern of apoptosis in development is similar to that seen in lower vertebrate models in which stress-induced apoptosis occurs only around the mid-blastula transition. We conclude that apoptosis may be used to rid embryos of aberrant or damaged cells in early development, but this response is stage-dependant. Repair, rather than apoptosis, may be utilized during earlier stages, or alternatively, embryos exposed to such stressors may continue development with damaged cells and perhaps damaged DNA. Our continued studies will focus on these alternative hypotheses.  相似文献   
9.
The acute toxicity of bromochlorinated estuarine water (ca. 20%) was determined for several estuarine organisms. The most sensitive species were oysters (Crassostrea virginica, larvae and juveniles) and copepods (Acartia tonsa) with 48-h LC50's of 0·10 to 0·21 mg BrCl/litre. Palaemonetes pugio was most tolerant with a 96-h LC50 of 0·70 mg BrCl/litre. The fish species tested (Menidia menidia, Brevoortia tyrannus and Leiostomus xanthurus) all had a 96-h LC50 of 0·21–0·23 mg BrCl/litre.The BrCl toxicity data are compared with Cl2 toxicity data for the same species. When the LC50's are expressed as equivalents per litre, BrCl is found to be two to four times less toxic than Cl2. The ranking of species in terms of sensitivity is the same for both disinfectants.Some data are provided concerning the decay rates of BrCl and Cl2 in estuarine water. BrCl was found to decay more rapidly than Cl2 at higher ammonia levels (0·25 mg NH4-N/litre). The question of chemical speciation is discussed with particular reference to the differential toxicities.  相似文献   
10.
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