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1.
Elisa Sacchi Gian Maria Zuppi Luca Pizzino Fedora Quattrocchi Salvatore Lombardi 《Aquatic Geochemistry》2008,14(4):301-319
The EC funded Geochemical Seismic Zonation program (EEC GSZ Project 1996–1998) chose Sardinia as a low-seismicity site, in which the relationships between fluid geochemistry and seismo-tectonics
had to be investigated and results compared with outcomes from other selected high-seismicity sites. A first article, examining
the role of fault segmentation and seismic quiescence on the geochemical composition of groundwaters and gases, has already
been presented (Angelone et al. 2005). This article deals with environmental isotopes which, together with selected hydrochemical data, give hints on tectonically-related
fluid circulations. Four water-dominated hydrothermal systems were considered, all located along regional fault systems and
discharging groundwaters belonging to the Na–HCO3 and Na–Cl facies. In the considered systems, groundwater circulation takes place, principally, in the Palaeozoic Crystalline
Basement (PCB), with the exception of the Logudoro system, where hydrological circuits develop in the Mesozoic Carbonate Platform
(MCP). The high CO2 contents, the non-attainment of fluid-rock equilibrium and the large lithological variability prevent the construction of
a unique hydrogeological–geochemical conceptual model. In this case, stable isotopes provide a useful tool to describe the
origin of fluids and their subterranean movements. Stable isotopes of water, integrated with hydrochemical data, indicate
that fluids are derived from three main end members. The dominant component is a relatively recent local meteoric water; the
second one is marine water; and the third one is a fossil freshwater, depleted in heavy isotopes with respect to modern rains.
The latter end member entered the aquifer system in the past, when climatic conditions were greatly different from today.
At least two circulation systems can be recognised, namely a shallow cold system and a deep hydrothermal system, as well as
two distinct hydrological processes: (1) gravity-controlled descent of cold water towards greater depths and (2) convection
linked to a thermal gradient, causing deep fluids to rise up from the hydrothermal reservoir towards the surface. The highly
variable δ13CTDIC values suggest the presence of two distinct CO2 sources, namely, a biogenic one and a thermogenic one. The relation between the isotopic compositions of CO2 and He indicates an increased mantle signature in uprising CO2-rich fluids. 相似文献
2.
Mario Costa Giorgio Ferrara Rosalino Sacchi Sonia Tonarini 《International Journal of Earth Sciences》1992,81(2):487-500
The Proterozoic basement of the Province of Zambezia (Mozambique) is located near the southern end of the so called Mozambique Belt. Rb-Sr data derived from the analyses of 66 whole rocks and a few mineral samples bear witness of a magmatic and metamorphic episode referable to the Kibaran (ca. 1000 Ma) and helped to model the late-Proterozoic evolution as follows. At 1100–1050 Ma a pre-orogenic, calc-alkaline magmatism was responsible for the emplacement of now deformed granite and granodiorite. This phase was accompanied by rhyolitic volcanism. A subsequent peak of deformation and metamorphism occurred at 1000-950 Ma and was associated with a second generation of substantially post-tectonic granites. A thermal event resulting in the emplacement of a final generation of granites and pegmatites can be dated to around 500-450 Ma.The metamorphic basement has not preserved its protolith age, probably as a result of extensive isotopic homogeneization of Sr in Kibaran times. Its maximum time of differentiation from the mantle should be around 1600 Ma.The very low values of initial Sr isotopic ratios suggest the absence of Archean crustal precursors and support the rather young, yet pre-Pan-African evolution of the southernmost Mozambique Belt.
Zusammenfassung Das proterozoische Grundgebirge der Provinz Zambesi (Mosambique) befindet sich in der Nähe des südlichen Endes des sogenannten Mozambique Belt. Rb/Sr Daten aus 66 Ganzgesteins- und einigen Mineralanalysen zeugen von einer magmatischen und metamorphen Episode die sich dem Kibaran (ca. 1000 Ma) zuordnen läßt, und wie sich im folgenden zeigt, hilfreich bei der Modellisierung der spätproterozoischen Entwicklung ist. Um 1100 bis 1050 Ma erfolgte ein präorogener kalkalkalischer Magmatismus, bestehend aus Graniten und Granodioriten, die heute deformiert vorliegen. Diese Phase wurde von rhyolithischem Vulkanismus begleitet. Von 1000 bis 950 Ma folgte der Höhepunkt der Deformation und Metamorphose, begleitet von einer bedeutenden 2. Generation posttektonischer Granite. Bedingt durch ein weiteres thermales Ereignis intrudierte die letzte Granit- und Pegmatitgeneration vor 500 bis 450 Ma.Im metamorphen Grundgebirge ist das Eduktalter vermutlich aufgrund der starken isotopischen Homogenisierung von Sr während der Kibara-Zeit nicht erhalten. Seine maximale Differentiationszeit vom Mantel muß vor 1600 Ma gewesen sein.Die sehr niedrigen Gehalte der initialen Sr-Isotopenverhältnisse lassen die Abwesenheit von archaischen Krustenvorläufern vermuten, und unterstützen die sehr junge, bis jetzt Prä-Pan-Afrikanische Entwicklung des südlichsten Mozambique Belts.
Résumé Le socle protérozoïque de la province du Zambèze, au Mozambique, se trouve à proximité de l'extrémité sud du «Mozambique Belt». Des mesures Rb/Sr effectuées sur 66 roches totales et sur quelques minéraux témoignent d'un épisode magmatique et métamorphique attribuable au Kibarien (environ 1.000 Ma), ce qui permet de se représenter comme suit l'histoire de cette région au Protérozoïque supérieur. Il y a 1.100 à 1.050 Ma, la région a connu une phase de magmatisme calco-alcalin qui s'est traduite par la mise en place de granites et granodiorites, aujord'hui déformés. Cette phase s'est accompagnée d'un volcanisme rhyolitique. Elle a été suivie, entre 1.000 et 950 Ma, d'une activité tectono-métamorphique majeure, à laquelle est associée une deuxième et importante génération de granites, post-tectoniques. Ultérieurement, la région a connu encore un épisode thermique, daté à 500-450 Ma, responsable de la mise en place d'une dernière génération de granite et de pegmatite.Le socle métamorphique n'a pas gardé de témoins de l'âge de son protolithe, en raison probablement de la forte homogénisation isotopique du Sr à l'époque kibarienne. Lâge maximal de sa différenciation à partir du manteau doit se situer autour de 1.600 Ma.La valeur très basse des rapports isotopiques initiaux du Sr suggère l'absence de précurseurs crustaux archéens et incite à admettre une évolution relativement jeune — bien que pré-panafricaine — du «Mozambique Belt» méridional.
() .. . , Rb/Sr 66 , , Kibara, 1000 , , , . 1100 1050 - - , , . . 1000 950 , - . , 500 450 . , , , Kibara. , , 1600 my . - .相似文献
3.
Giorgio Pilla Elisa Sacchi Gianmaria Zuppi Giovanni Braga Gianfranco Ciancetti 《Hydrogeology Journal》2006,14(5):795-808
A multicriteria approach in studying hydrodynamics of a multilayer aquifer system has been used in the Lomellina region (Northern Italy). It involves the reconstruction of the hydrogeological framework coupled to the definition of the hydrochemical and isotopic features of the aquifers. A shallow phreatic aquifer, reaching depths of about 60–80 m from the surface, and deeper aquifers containing confined groundwater, were distinguished. Groundwater generally shows mineralisation decreasing with depth; dissolved ions depict calcium-bicarbonate hydrochemical facies and stable isotopes define the recharge mechanisms, the origin of groundwater, and the hydraulic confinement of deep aquifers. The phreatic aquifer is fed by local infiltration and by streams and irrigation channels. Tritium and Carbon-14 groundwater dating indicate long residence times (on the order of thousands of years) for confined aquifers. The confined aquifers show essentially passive hydrodynamic conditions and maintain a higher piezometric level than the phreatic aquifer. This inhibits the possibility of recent water penetrating far below the surface. The hydrogeological setting of the Lomellina region displays features which are common to other sectors of the Po plain. As a consequence, the results of this study, although conducted on a restricted area, are highly illustrative of groundwater hydrodynamics in large sedimentary aquifers. 相似文献
4.
Delineation of detailed mantle structure frequently requires the separation of source signature and structural response from seismograms recorded at teleseismic distances. This deconvolution problem can be posed in a log-spectral domain where the operation of time-domain convolution is reduced to an additive form. The introduction of multiple events recorded at many stations leads to a system of consistency equations that must be honoured by both the source time functions and the impulse responses associated with propagation paths between sources and receivers. The system is inherently singular, and stabilization is accomplished through the supply of an initial estimate of the source time function. Although alternative choices exist, an effective estimate is derived from the eigenimage associated with the largest eigenvalue in a singular-value decomposition of the suite of aligned seismograms corresponding to a given event. The relation of the deconvolution scheme to simultaneous least-squares deconvolution is examined. Application of the methodology to broadband teleseismic P waveforms recorded on the Canadian National Seismograph Network demonstrates the retrieval of effective Green's functions including secondary phases associated with upper-mantle structure. 相似文献
5.
In this paper, we present a new approach to estimate high-resolution teleseismic receiver functions using a simultaneous iterative time-domain sparse deconvolution. This technique improves the deconvolution by using reweighting strategies based on a Cauchy criterion. The resulting sparse receiver functions enhance the primary converted phases and its multiples. To test its functionality and reliability, we applied this approach to synthetic experiments and to seismic data recorded at station ABU, in Japan. Our results show Ps conversions at approximately 4.0 s after the primary P onset, which are consistent with other seismological studies in this area. We demonstrate that the sparse deconvolution is a simple, efficient technique in computing receiver functions with significantly greater resolution than conventional approaches. 相似文献
6.
We present a new inversion method to estimate, from prestack seismic data, blocky P‐ and S‐wave velocity and density images and the associated sparse reflectivity levels. The method uses the three‐term Aki and Richards approximation to linearise the seismic inversion problem. To this end, we adopt a weighted mixed l2, 1‐norm that promotes structured forms of sparsity, thus leading to blocky solutions in time. In addition, our algorithm incorporates a covariance or scale matrix to simultaneously constrain P‐ and S‐wave velocities and density. This a priori information is obtained by nearby well‐log data. We also include a term containing a low‐frequency background model. The l2, 1 mixed norm leads to a convex objective function that can be minimised using proximal algorithms. In particular, we use the fast iterative shrinkage‐thresholding algorithm. A key advantage of this algorithm is that it only requires matrix–vector multiplications and no direct matrix inversion. The latter makes our algorithm numerically stable, easy to apply, and economical in terms of computational cost. Tests on synthetic and field data show that the proposed method, contrarily to conventional l2‐ or l1‐norm regularised solutions, is able to provide consistent blocky and/or sparse estimators of P‐ and S‐wave velocities and density from a noisy and limited number of observations. 相似文献
7.
In this paper we discuss a beyond‐alias multidimensional implementation of the multi‐step autoregressive reconstruction algorithm for data with missing spatial samples. The multi‐step autoregressive method is summarized as follows: vital low‐frequency information is first regularized adopting a Fourier based method (minimum weighted norm interpolation); the reconstructed data are then used to estimate prediction filters that are used to interpolate higher frequencies. This article discusses the implementation of the multi‐step autoregressive method to data with more than one spatial dimension. Synthetic and real data examples are used to examine the performance of the proposed method. Field data are used to illustrate the applicability of multidimensional multi‐step autoregressive operators for regularization of seismic data. 相似文献
8.
L.?PaleariEmail author G.?Cappelli S.?Bregaglio M.?Acutis M.?Donatelli G.?A.?Sacchi E.?Lupotto M.?Boschetti G.?Manfron R.?Confalonieri 《Climatic change》2015,132(4):661-675
Using crop models as supporting tools for analyzing the interaction between genotype and environment represents an opportunity to identify priorities within breeding programs. This study represents the first attempt to use simulation models to define rice ideotypes improved for their resistance to biotic stressors (i.e., diseases); moreover, it extends approaches for evaluating the impact of changes in traits for tolerance to abiotic constraints (temperature shocks inducing sterility). The analysis—targeting the improvement of 34 varieties in six Italian rice districts—was focused on the impact of blast disease, and of pre-flowering cold- and heat-induced spikelet sterility. In silico ideotypes were tested at 5-km spatial resolution under current conditions and climate change scenarios centered on 2020, 2050, and 2085, derived according to the projections of two general circulation models–Hadley and NCAR–for two IPCC emission scenarios–A1B and B1. The study was performed using a dedicated simulation platform, i.e., ISIde, explicitly developed for ideotyping studies. The ideotypes improved for blast resistance obtained clear yield increases for all the combinations GCM?×?emission scenario?×?time horizon, i.e., 12.1 % average yield increase under current climate, although slightly decreasing for time windows approaching the end of the century and with a marked spatial heterogeneity in responses across districts. Concerning abiotic stressors, increasing tolerance to cold-induced sterility would lead to a substantial yield increase (+9.8 %) only for Indica-type varieties under current climate, whereas no increases are expected under future conditions and, in general, for Japonica-type varieties. Given the process-based logic behind the models used—supporting coherence of model responses under future scenarios—this study provides useful information for rice breeding programs to be realized in the medium-long term. 相似文献
9.
Whole-rock geochemical analysis of metavolcanic and plutonic rocks from Mai Kenetal-Negash area, Tigrai, northern Ethiopia was carried out to evaluate their magma type and original tectonic environment. Their major element content has been modified by secondary alteration, and trace and rare-earth elements have been used to investigate their petrogenesis. The low content of compatible elements of the metavolcanic rocks and their relatively high content of incompatible elements and light REE point to a depleted source region, whereas the plutonic rocks show a more pronounced REE fractionation (LaN/LuN >4). Metavolcanic and plutonic rocks seem to be cogenetic. Discriminant diagrams suggest that the majority of the metavolcanic and all the plutonic rocks are members of a calc-alkaline suite developed in a volcanic arc setting. The overall geochemical characteristics of both sets of rocks are consistent with the arc accretion models postulated in Sudan, Egypt and Saudi Arabia for the Neoproterozoic evolution of the Arabian-Nubian Shield. 相似文献
10.
Andrea I. Pasquini Stella M. Formica Gabriela A. Sacchi 《Environmental Earth Sciences》2012,65(2):453-467
Suquía River is a medium-sized hydrological system (basin area of ~7,700 km2) that supplies fresh water to Córdoba city, a town of ~1,500,000 inhabitants in central Argentina. This paper examines the
present-day hydrochemistry of Suquía River urban catchment analyzing its major and minor dissolved components, and the nutrients
variability by means of QUAL-2K modeling software. The Suquía River has bicarbonate-type waters upstream the city and sulfate-type
waters right downstream, whereas they exhibit a mixed-to-alkali-type cationic composition. The seasonal analysis of its major
dissolved constituents clearly showed a dilution process during the wet season (i.e. austral summer). In the last 20 years,
the Suquía River has modified its anionic composition, now showing higher relative concentrations of SO4
2− as a consequence of urban activities. However, trace elements dissolved concentrations do not evidence a strong pollution
effect. Nutrients [nitrogen species, total phosphorous (TP)] and related parameters, such as biochemical oxygen demand (BOD),
and dissolved oxygen (DO), evidence a clear influence of human activities. The QUAL-2K model was used to evaluate the spatial
behavior of selected nutrients and associated variables, (i.e. TP, N–NH4
+, N–NO3
−, DO, BOD). Nutrient concentrations are affected by point sources of contaminants, particularly domestic waste and sewage,
as well as by diffuse agricultural pollution. A calibrated QUAL-2K modeling exercise clearly shows the impact of the Córdoba
city’s municipal wastewater treatment plant on the Suquía River water quality. 相似文献