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1.
The leaching of coal and coal/asphaltite/wood-ashes in sulfuric acid (pH 1.0, 25 °C, S/L, 1:10) was studied as a function of time; acid consumption and extracted metal concentrations are presented. Whole coals consumed acid rapidly during the first few minutes, followed by slow acid consumption. Wood-, lignite-, and asphaltite-ashes consumed acid in two stages, the rapid phase extending < 30 min and the slow phase extended up to 10 days. The rapid phase was dominated by the dissolution of Ca, K and Mg ions for wood-ash, by Ca, Al and Mg ions for lignite-ash and Ca and Mg ions for asphaltite-ash. The sulfur concentration in solution and the concentrations of Ca, Fe, K, Mg, Na, P, Al and Mn in the aqueous phase verified the neutralizing capacity of the untreated ashes as well as the formation of insoluble sulfates in the residues. The slow phase kinetics differed for different fuels and exhibited leaching of several abundant elements—Fe, Al, K, Na and Mn. Trace elements (Ba, Cd, Co, Cr, Cu, Mo, Ni, Pb, Th, U, V, Zn) sometimes required up to 32 h for maximal extraction from ashes. Suggestions are presented regarding the chemical nature of trace elements in the untreated coals and ashes and suitable residence times for economical industrial processes. We think it possible to combine bacteriological oxidation of sulfidic concentrates of acid leaching from ash of various qualities or even whole coals.  相似文献   
2.
Geotechnical and Geological Engineering - Shallow and deep seated landslides in natural slopes are often induced by rainfall. The cause of the failure is usually considered to be due to the...  相似文献   
3.
Variation in growth, physiology and ionic relations patterns of Allenrolfea occidentalis, a perennial halophyte of dry habitats, was studied under field conditions from May 1996 to November 1997. An A. occidentalis community has a characteristic soil pH of 7·3–8·3. During the two years, the population was exposed to great variations in soil salinity, from 29 to 146 dS m−1, and soil moisture, ranging from drought (9·2%) to wet (19%). The salt concentrations were significantly higher in the surface soil layers than in the subsurface layers. Seasonal changes in dry weight are directly related to soil salinity stress. Allenrolfea occidentalis had greater growth and biomass production under saline conditions. Na+and Clions were accumulated in plant tissues in much greater amounts than K+, Ca2+, and Mg2+. Soil salinities were significantly reduced at the end of the growing season. Water potentials of the shoots decreased significantly with increasing salinity. The plant (Fv/Fmratio) was more affected by salinity and irradiation levels during the summer period.  相似文献   
4.
Geotectonics - Vendian and Permian–Triassic plagiogranite magmatism is distinguished for the Ust-Belsky and Algansky terranes of West Koryak fold system. The U‒Pb zircon ages from...  相似文献   
5.
The Daeri Member, a Cretaceous volcanic–sedimentary succession, can be divided into lower, middle, and upper parts based on vertical changes in its lithologic characters. The lower Daeri Member is composed of siliciclastic deposits formed in a semi‐arid floodplain environment, which is overlain by the middle Daeri Member consisting mainly of andesite lava flow. After the emplacement of the andesite, activities of intrabasinal normal faults created accommodation on hanging wall blocks together with the development of intrabasinal topographic relief. The upper Daeri Member occurs only in hanging wall blocks and is composed of rhyolitic volcaniclastic sediments formed during an explosive volcanic eruption. Following the eruption, owing to semi‐arid climatic conditions and the destruction of vegetation, the eruptive materials were easily remobilized and deposited by episodic sediment gravity flows, resulting in deposition of the resedimented volcaniclastic deposits with sheet‐like geometry. Away from the intrabasinal normal faults, the resedimented volcaniclastic deposits show a decrease in grain size together with changes in inferred depositional processes from debris flows to hyperconcentrated flows and supercritical sheetfloods. This suggests that the resedimented volcaniclastic deposits were stacked on alluvial fan environments induced by intrabasinal topographic relief associated with normal fault activities. In addition, episodic movement of the faults gave rise to periodic fluctuation of the accommodation and an increase in gradient of the alluvial fan surface, resulting in the development of coarsening‐upward trends in the resedimented volcaniclastic deposits. The development of the alluvial fan and the coarsening‐upward trends indicate that dynamic tectonic subsidence and concomitant changes in the intrabasinal physiographic relief influenced the depositional processes and sizes of the transported volcaniclastic sediments of the upper Daeri Member. Thus, it is necessary to carefully observe tectonic signatures in volcaniclastic successions, particularly the syneruptive lithofacies, in order to reconstruct the tectonic and volcanic histories of receiving basins.  相似文献   
6.
Stochastic Environmental Research and Risk Assessment - Occupational safety issues encountered in the worksite environment are the issues that companies should consider in improving their...  相似文献   
7.
8.
In the present study, the retention capacity of carbonaceous material obtained from the diesel engine exhaust mufflers for Cr(VI) removal has been investigated. The physicochemical properties such as density, pH of aqueous slurry, pH at point of zero charge, ash content, moisture content, volatile matter, surface area, scanning electron microscopy and electron dispersive spectroscopy of the carbonaceous material were determined. The capacity of adsorbent for removal of Cr(VI) from aqueous solution was observed under different experimental condition like contact time, initial concentration of metal ions, pH and temperatures on the adsorption capacity of the adsorbent. Maximum adsorption of Cr(VI) ions was found at low pH. The adsorption process was found to follow second-order kinetics. The rate constant was evaluated at different temperatures along with other thermodynamic parameters like activation energy, Gibbs free energy change, enthalpy change and entropy change. Both Langmuir and Freundlich isotherms were used to describe the adsorption equilibrium of carbonaceous material at different temperatures. Langmuir isotherm shows better fit than Freundlich isotherm at given conditions. The result shows that low-cost carbonaceous material from diesel engine exhaust mufflers can be efficiently used for wastewater treatment containing Cr(VI) ions.  相似文献   
9.
Saner  Halit Serdar  Yucesan  Melih  Gul  Muhammet 《Natural Hazards》2022,111(2):1603-1635
Natural Hazards - Hospitals are the first point of contact for people in the face of disasters that interfere with the daily functioning of life and endanger health and social life. All...  相似文献   
10.
Salt playa are common in the Great Basin area with halophytes as the dominant flora. The relationship between the seed bank flora and existing vegetation was studied. The seed bank flora showed a high degree of similarity with that of perennial and annual halophytic vegetation. Both above and below ground components of the community are dominated by halophyte species like Allenrolfea occidentalis, Holosteum umbellatum, Salicornia rubra and Salicornia utahensis. Seasonal variation in the seed bank was also studied for the 1995–1996 and 1996–1997 growing seasons. The seeds of A. occidentalis persist in the soil of the upper zone in large densities. Salicornia utahensis was much higher in the upper zone throughout the study period. Most species demonstrated the persistent nature of the seed banks with their numbers increasing after seed dispersal and decreasing in subsequent months. The variation illustrates the transient nature of the seed bank. We concluded that A. occidentalis is more dependent on a large seed bank for maintaining its population than the two annual halophytes. The significance of the seed bank and their variation due to environmental conditions for perennial and annual species of the Great Basin salt playa community is discussed.  相似文献   
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