排序方式： 共有11条查询结果，搜索用时 15 毫秒
1.
2.
T. Anttila A. Kiendler-Scharr Th. F. Mentel R. Tillmann 《Journal of Atmospheric Chemistry》2007,57(3):215-237
Organic aerosol formation resulting from the ozonolysis of α-pinene, myrcene and sabinene was investigated in a large aerosol
chamber in the presence of aqueous seed aerosols. The chemical composition of the particles was monitored by an aerosol mass
spectrometer (Aerodyne Research Inc.) as a function of time and the particle size. Smaller particles were found to contain
more organics relative to sulfate than the larger ones. In contrast, the water to sulfate mass ratio was not dependent on
the particle size. These experimental findings indicate the formation of organic layers on the particles. With the aid of
an aerosol dynamic model we demonstrate that the observations are consistent with the formation of multilayered organic films
having thicknesses of approximately 10 nm. The results also suggest that the films were formed through condensation of low-volatile
oxidation products that did not take up water considerably. Even though dissolution of oxidation products into the particle
aqueous phase cannot be conclusively ruled out, the most plausible interpretation of the results is that the monoterpene ozonolysis
lead to the formation of organic coatings on aqueous aerosols. Such films are likely to form in regions with monoterpene emissions. 相似文献
3.
4.
Zsuzsanna Nyári Ali Ismet Kanlı János Stickel Axel Tillmann 《Journal of Applied Geophysics》2010,70(3):255-265
The spatial distribution of the electrical resistivity data provides useful information for investigating and modeling the fluid transport processes. 3D electrical resistivity distribution provides information about water flow and changes in electrical resistivity of the pore fluid.Therefore, to assist in understanding and modeling of the fluid transport process, 3D spatial distribution of the electrical resistivity data with the corresponded 3D geological section were mapped and interpreted in the test site located in western Germany. A process of deriving electrical resistivity values from the mechanical and radioactive parameters of cone penetration tests (CPT) and geological information of boreholes was presented. A reliable method which gives accurate resistivity values in cases of near surface sediments was introduced. Then a field test was executed where the calculated resistivity values were compared with the measured CPTe resistivity data. The CPTe (cone penetration test with electrical extension) data were also used in correlating to the ERT (electrical resistivity tomography) data. Consequently, obtained dense CPT surveys give us the possibility to determine a high resolution resistivity distribution of the investigated area. 相似文献
5.
6.
Timothy A. Kral Travis S. Altheide Adrienne E. Lueders Andrew C. Schuerger 《Planetary and Space Science》2011,59(2-3):264-270
Conditions on the surface of Mars would appear to be too hostile for life as we know it. But the subsurface is another matter. If liquid water is present, even intermittently, life forms present would at least be protected from the lethal radiation bombarding the surface. However, life would have to contend with variations in pressure and possibly extended periods of desiccation. The research reported here involves both active metabolism (methanogenesis) at 400 and 50 mbar of pressure, pressures that would be found in the near subsurface of Mars, and survival following desiccation at both 1 bar (a pressure that would be found in the Martian subsurface) and 6 mbar (the lowest pressure at the surface and very near subsurface). The three methanogens tested for active metabolism, Methanothermobacter wolfeii, Methanosarcina barkeri and Methanobacterium formicicum, all demonstrated methane production at both 400 and 50 mbar on JSC Mars-1, a Mars soil simulant. Methane production at 50 mbar was much reduced compared to that at 400 mbar, most likely due to the greater stress at the lower pressure. In desiccation survival experiments, M. barkeri had survived 330 days of desiccation at 1 bar, while M. wolfeii and M. formicicum survived 180 and 120 days, respectively. Methanococcus maripaludis did not survive desiccation at all at 1 bar. At 6 mbar, M. wolfeii, M. barkeri and M. formicicum survived 120 days of desiccation while M. maripaludis survived 60 days. These results along with results from previous research would seem to indicate that there is no reason that methanogens could not inhabit the subsurface of Mars. 相似文献
7.
Hans J. Rick Silke Rick Urban Tillmann Uwe Brockmann Uwe Gärtner Claus Dürselen Jürgen Sündermann 《Estuaries and Coasts》2006,29(1):4-23
Within the KUSTOS program (Coastal Mass and Energy Fluxes-the Land-Sea Transition in the Southeastern North Sea) 28 to 36
German Bight stations were seasonally surveyed (summer 1994, spring 1995, winter 1995–1996) for light conditions, dissolved
inorganic nutrient concentrations, chlorophylla (chla), and photosynthesis versus light intensity (P:E) parameters. Combining P:E curve characteristics with irradiance, attenuation,
and chlorophyll data resulted in seasonal estimates of the spatial distribution of total primary production. These data were
used for an annual estimate of the total primary production in the Bight. In winter 1996 the water throughout the German Bight
was well mixed. Dissolved inorganic nutrient concentrations were relatively high (nitrogen [DIN], soluble reactive phosphorus
[SRP], and silicate [Si]: 23, 1, and 10 μM, respectively). Chla levels generally were low (< 2 μg l−1) with higher concentrations (4–16 μg l−1) in North Frisian coastal waters. Phytoplankton was limited by light. Total primary production averaged 0.2 g C m−2 d−1. Two surveys in April and May 1995 captured the buildup of a strong seasonal thermo-cline accompained by the development
of a typical spring diatom bloom. High nutrient levels in the mixed layer during the first survey (DIN, SRP, and Si: 46, 0.45,
and 11 μM, respectively) decreased towards the second survey (DIN, SRP, and Si: 30.5, 0.12, and 1.5 μM, respectively) and
average nutrient ratios shifted further towards highly imbalanced values (DIN:SRP: 136 in survey 1, 580 in survey 2; DIN:Si:
13.5 in survey 1, 96 in survey 2). Chla ranged from 2 to 16 μg l−1 for the first survey and rose to 12–50 μg l−1 in the second survey. Phytoplankton in nearshore areas continued to be light limited during the second survey, while data
from the stratified regions in the open German Bight indicates SRP and Si limitation. Total primary production ranged from
4.0 to 6.3 g C m−2 d−1. During summer 1994 a strong thermal stratification was present in the German Bight proper and shallow coastal areas showed
unusually warm (up to 22°C), mixed waters. Chla concentrations ranged from 2 to 18 μg l−1. P:E characteristics were relatively high despite the low nutrient regime (DIN, SRP, and Si: 2, 0.2, and 1.5 μM, respectively),
resulting in overall high total primary production values with an average of 7.7 g C m−2 d−1. Based on the seasonal primary production estimates of the described surveys a budget calculation yielded a total annual
production of 430 g C m−2 yr−1 for the German Bight. 相似文献
8.
9.
D. Poppe T. Brauers H. -P. Dorn M. Karl T. Mentel E. Schlosser R. Tillmann R. Wegener A. Wahner 《Journal of Atmospheric Chemistry》2007,57(3):203-214
Degradation of isoprene, m-xylene, n-octane, propene, and methacrolein by hydroxyl radicals has been studied in the simulation chamber SAPHIR under burden of
trace gases as they are typical for the moderately polluted planetary boundary layer. Measured time series of the hydrocarbon
mixing ratios and the OH concentrations were used to determine the rate constants. The hydrocarbons were measured with gas
chromatography and proton transfer reaction mass spectrometry. OH was measured with the Jülich DOAS (differential optical
absorption spectroscopy) instrument. In all cases except methacrolein good agreement was found with the reference rate constants
taken from the Master Chemical Mechanism (MCM3.1). The data for methacrolein are consistent with the results of Karl et al.
(J. Atmos. Chem 55, 2006, doi:) who reported a 12% smaller value. The degradation of hydrocarbons provides an independent method to analyse precision and
accuracy of the OH measurements. A precision of better than 4% over a period of nearly 4 months was found. The accuracy is
within the limitations given by the light absorption cross section of OH. Both results are consistent with earlier results
by Hausmann et al. (J. Geophys. Res. 102:16011–16022, 1997). 相似文献
10.
Eric Schlosser Birger Bohn Theo Brauers Hans-Peter Dorn Hendrik Fuchs Rolf Häseler Andreas Hofzumahaus Frank Holland Franz Rohrer Lutz Olaf Rupp Manfred Siese Ralf Tillmann Andreas Wahner 《Journal of Atmospheric Chemistry》2007,56(2):187-205
At the atmosphere simulation chamber SAPHIR in Jülich both Laser-Induced Fluorescence Spectroscopy (LIF) and Long-Path Differential
Optical Laser Absorption Spectroscopy (DOAS) are operational for the detection of OH radicals at tropospheric levels. The
two different spectroscopic techniques were compared within the controlled environment of SAPHIR based on all simultaneous
measurements acquired in 2003 (13 days). Hydroxyl radicals were scavenged by added CO during four of these days in order to
experimentally check the calculated precisions at the detection limit. LIF measurements have a higher precision (σ= 0.88×106 cm–3) and better time resolution (Δt = 60 s), but the DOAS method (σ= 1.24×106 cm–3, Δt = 135 s) is regarded as primary standard for comparisons because of its good accuracy. A high correlation coefficient of
r = 0.95 was found for the whole data set highlighting the advantage of using a simulation chamber. The data set consists of
two groups. The first one includes 3 days, where the LIF measurements yield (1 – 2) ×106 cm–3 higher OH concentrations than observed by the DOAS instrument. The experimental conditions during these days are characterized
by increased NOx concentration and a small dynamic range in OH. Excellent agreement is found within the other group of 6 days. The regression
to the combined data of this large group yields unity slope without a significant offset. 相似文献