Compositional variation in Hg-bearing sphalerite from the polymetallic Eskay Creek deposit, British Columbia, Canada   总被引：1，自引：0，他引：1  

Tassos A. Grammatikopoulos  Oleg Valeyev  Tina Roth 《Chemie der Erde / Geochemistry》2006,66(4):307-314

The Eskay Creek, British Columbia, Canada, is a polymetallic, gold- and silver-rich, volcanic-hosted, massive sulfide deposit. The ore in the deposit is divided into subzones distinguished by mineralogy, texture, grade and metallurgical characteristics. This study presents the results of a mineralogical examination of three composite field samples, with emphasis on the chemistry of sphalerite. Sphalerite is associated with variable amounts of Hg-tetrahedrite and cinnabar, and an array of sulfides, sulphosalts and non-opaque minerals. Electron micro probe analyses of sphalerite in the three composite samples reveal wide variations in compositions. The Hg content in sphalerite in the three samples varies between 0.08 and 16.35 wt%, whereas the Fe content ranges from 0.33 to 2.29 wt%. The chemical formula of the sphalerite shows the compositional range (Zn_0.89–0.98Hg_0.01–0.09.Fe_0.005–0.02)S. Sphalerite exhibits an almost perfect substitution of Hg and Zn, as shown by the negative covariance between them. Sphalerite with the highest Hg contents tends to have the lowest Fe concentrations. The highest Hg contents in sphalerite are recorded in the samples with the highest bulk Hg concentrations and with the highest cinnabar contents.

The compositional variations of sphalerite are important because they can be used in mapping ore forming fluids and indicate possible temporal variations. Second, determination of the compositional variation of the sphalerite in the mine has metallurgical implications because the mineral is an important Zn source. The mineralogical data indicate that non-physical processes (e.g. pyrometallurgy) must be used to separate Hg from Zn concentrates, with direct environmental implications, that is, release of metals, such as Hg, into the environment during mining and processing.  相似文献   

Lower crustal melting and the role of open-system processes in the genesis of syn-orogenic quartz diorite–granite–leucogranite associations: constraints from Sr–Nd–O isotopes from the Bandombaai Complex, Namibia     

Tina van de Flierdt  Stephan Hoernes  Stefan Jung  Peter Masberg  Edgar Hoffer  Urs Schaltegger  Hans Friedrichsen 《Lithos》2003,67(3-4):205-226

The Bandombaai Complex (southern Kaoko Belt, Namibia) consists of three main intrusive rock types including metaluminous hornblende- and sphene-bearing quartz diorites, allanite-bearing granodiorites and granites, and peraluminous garnet- and muscovite-bearing leucogranites. Intrusion of the quartz diorites is constrained by a U–Pb zircon age of 540±3 Ma.

Quartz diorites, granodiorites and granites display heterogeneous initial Nd- and O isotope compositions (_{Nd (540 Ma)}=−6.3 to −19.8; δ¹⁸O=9.0–11.6‰) but rather low and uniform initial Sr isotope compositions (⁸⁷Sr/⁸⁶Sr_initial=0.70794–0.70982). Two leucogranites and one aplite have higher initial ⁸⁷Sr/⁸⁶Sr ratios (0.70828–0.71559), but similar initial _Nd (−11.9 to −15.8) and oxygen isotope values (10.5–12.9‰). The geochemical and isotopic characteristics of the Bandombaai Complex are distinct from other granitoids of the Kaoko Belt and the Central Zone of the Damara orogen. Our study suggests that the quartz diorites of the Bandombaai Complex are generated by melting of heterogeneous mafic lower crust. Based on a comparison with results from amphibolite-dehydration melting experiments, a lower crustal garnet- and amphibole-bearing metabasalt, probably enriched in K₂O, is a likely source rock for the quartz diorites. The granodiorites/granites show low Rb/Sr (<0.6) ratios and are probably generated by partial melting of meta-igneous (intermediate) lower crustal sources by amphibole-dehydration melting. Most of the leucogranites display higher Rb/Sr ratios (>1) and are most likely generated by biotite-dehydration melting of heterogeneous felsic lower crust. All segments of the lower crust underwent partial melting during the Pan-African orogeny at a time (540 Ma) when the middle crust of the central Damara orogen also underwent high T, medium P regional metamorphism and melting. Geochemical and isotope data from the Bandombaai Complex suggest that the Pan-African orogeny in this part of the orogen was not a major crust-forming episode. Instead, even the most primitive rock types of the region, the quartz diorites, represent recycled lower crustal material.  相似文献   

Seismic Image Waves     

Peter Hubral  Martin Tygel  Jöurg Schleicher 《Geophysical Journal International》1996,125(2):431-442

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Hot Spots of Nitrification in the Elbe Estuary and Their Impact on Nitrate Regeneration     

Tina Sanders  Andreas Schöl  Kirstin Dähnke 《Estuaries and Coasts》2018,41(1):128-138

Estuaries act as an organic matter and nutrient filter in the transition between the land, rivers and the ocean. In the past, high nutrient and organic carbon load and low oxygen concentration made the Elbe River estuary (NW Europe) a sink for dissolved inorganic nitrogen. A recent reduction in loads and subsequent recovery of the estuary changed its biogeochemical function, so that nitrate is no longer removed on its transition towards the coastal North Sea. Nowadays in the estuary, nitrification appears to be a significant nitrate source. To quantify nitrification and determine actively nitrifying regions in the estuary, we measured the concentrations of ammonium, nitrite and nitrate, the dual stable isotopes of nitrate and net nitrification rates in the estuary on five cruises from August 2012 to August 2013. The nitrate concentration increased markedly downstream of the port of Hamburg in summer and spring, accompanied by a decrease of nitrate isotope values that was clearest in summer exactly at the location where nitrate concentration started to increase. Ammonium and nitrite peaked in the Hamburg port region (up to 18 and 8 μmol L^?1, respectively), and nitrification rates in this region were up to 7 μmol L^?1 day^?1. Our data show that coupled re-mineralization and nitrification are significant internal nitrate sources that almost double the estuary’s summer nitrate concentration. Furthermore, we find that the port of Hamburg is a hot spot of nitrification, whereas the maximum turbidity zone (MTZ) only plays a subordinate role in turnover of nitrate.  相似文献   

Open-system chemical behavior in deep Wilcox Group mudstones,Texas Gulf Coast,USA     

Ruarri J. Day-Stirrat  Kitty L. Milliken  Shirley P. Dutton  Robert G. Loucks  Stephen Hillier  Andrew C. Aplin  Anja M. Schleicher 《Marine and Petroleum Geology》2010

Wilcox Group mudstones have been mechanically and geochemically transformed over a temperature range of 20–200 °C. Our research controlled for provenance and age by sampling from five wells, parallel to the paleodepositional axis, all within the Houston delta system. Across the sampled depths, mudstone porosity has been reduced from ∼25 to <10% and bulk mineralogical change as documented by quantitative X-ray diffraction includes decreases in quartz, K-feldspar and kaolinite content whereas illite + illite − smectite, chlorite, and plagioclase increase. These mineral transformations transfer elements at a scale of less than 1 mm from one mineralogical form to another, however, X-ray fluorescence data suggest that among major elements only Al₂O₃ and TiO₂ are fully conserved within the system (trace-element ZrO₂ is also conserved). K₂O has been added to and SiO₂ released from the Wilcox Group mudstones. Cathodoluminescence and secondary electron imaging did not find this SiO₂ locally precipitated. We, therefore, document an open-system geochemical behavior.  相似文献   

Leaching and differential recrystallization of metamict zircon under experimental hydrothermal conditions   总被引：14，自引：0，他引：14  

Thorsten Geisler  Marcus Ulonska  Helmut Schleicher  Robert T. Pidgeon  Wilhelm van Bronswijk 《Contributions to Mineralogy and Petrology》2001,141(1):53-65

We report results of hydrothermal experiments on four alluvial zircons from Sri Lanka, which cover a wide range of radiation damage, at 450 °C and 1.3 kbar for 744 h with 2 M CaCl₂ solution as reactive fluid. After the hydrothermal treatment, the most metamict samples show micrometer-thick reaction rims, which surround apparently unreacted zircon, as revealed by cathodoluminescence (CL) and Nomarski differential interference contrast (NDIC) images. These rims have sharp, curved, and transgressive boundaries with unreacted zircon and are, in some cases, spread out along cracks. The thickness of reaction rims increases with increasing cumulated !-dosage of the starting materials. The reaction rims are strongly enriched in Ca (up to 7000 ppm) and a water species and depleted in radiogenic Pb, Zr, and Si, as revealed by electron microprobe analyses. A significant Th loss from the reaction rims was detected in the case of the most metamict sample, whereas U remained in the structure. FT-infrared spectrometry and X-ray diffraction measurements revealed that the bulk run products were recrystallized. Using micro-Raman spectrometry, we were able to demonstrate that differential recrystallization took place. The reaction rims are strongly recrystallized, whereas the unreacted grain interiors underwent only minor recrystallization. Recrystallization of the rims is accompanied by an enhancement of the integral CL intensity. It is suggested that recrystallization in the reaction rims was catalyzed by water infiltration and ion exchange and prevented significant congruent zircon dissolution under the given experimental conditions. Previous zircon studies have shown that (1) a transgressive morphology, (2) a reduced Th-U ratio, and (3) an enhanced CL emission are also characteristics of rims in zircons from high-grade metamorphic rocks. Based on these similarities between natural and experimentally produced rims, it is suggested that leaching-catalyzed recrystallization is an important alteration process in zircon under wet geological conditions and can account for many complex core-rim structures found in natural zircons. Furthermore, the strong enrichment of Ca in the reaction rims supports previous assumptions that high Ca concentrations in natural zircons are of secondary origin. It is suggested that lower U-Pb concordia intercept ages obtained from single-phase zircons with high Ca contents date a leaching event.  相似文献   

Velocity Field of a Complex Sunspot with Light Bridges     

Schleicher  H.  Balthasar  H.  Wöhl  H. 《Solar physics》2003,215(2):261-280

For the leading part of sunspot group NOAA 8323, which rapidly changed its complex structure, a time series of the line-of-sight (LOS) component of the velocity field was obtained. With a two-dimensional Fabry–Pérot spectrometer, the magnetically insensitive line Fei 557.6 nm was scanned. The inclination of the LOS (heliographic angle) to the vertical was =28.5°. The umbra of the observed spot was divided by a system of light bridges into several parts. The spatial and temporal velocity field also exhibits a considerable complexity: in one extended umbral area there is a downward flow of 1 km s^–1 relative to other dark sub-umbrae. At the center-side penumbra, with a line-of-sight Evershed outflow of 1.5 km s^–1, a persistent patch, somewhat darker than the average penumbra, has a LOS velocity of 1.3 km s^–1 in opposite direction, probably a downflow. At the limb-side penumbra, a photosphere-like area is interspersed, interrupting the Evershed flow which resumes with typical strength beyond this feature towards the outer penumbral boundary. Most interesting is the behavior of the light bridges, which have a slight blue shift, interrupted by short events of strong blue or red shifts which – within the time resolution of 35 s – instantly affect a considerable part of a light bridge.  相似文献   

Morphology of HCN and CN in Comet Hale-Bopp (1995 O1)     

L.M. Woodney  M.F. A'HearnDavid G. Schleicher  Tony L. FarnhamJ.P. McMullin  M.C.H. WrightJ.M. Veal  Lewis E. SnyderImke de Pater  J.R. ForsterPatrick Palmer  Y.-J. KuanWendy R. Williams  Chi C. CheungBridget R. Smith 《Icarus》2002,157(1):193-204

We compare images of Comet Hale-Bopp (1995 O1) in HCN and CN taken near perihelion (April 1, 1997) to determine the origin of CN in comets. We imaged the J=1→0 transition of HCN at λ=3 mm with the BIMA Array. Data from two weeks around perihelion were summed within four phase bins based on the rotational period of the comet. This increases both the signal-to-noise ratio and the u-v coverage while decreasing the smearing of the spatial features. The similarly phased narrowband CN images were taken at Lowell Observatory within the same range of dates as the HCN images. We find that there is a better correlation between HCN and CN than between HCN and the optically dominant dust. If the CN in jets does have a dust source it would have to have a very low albedo and/or small particle size. The production rates are consistent with HCN being a primary parent of CN, although there are discrepancies between the HCN destruction scalelength and the CN production scalelength which we discuss.  相似文献   

Velocity Oscillations in Active Sunspot Groups     

Balthasar  H.  MartÍnez Pillet  V.  Schleicher  H.  Wöhl  H. 《Solar physics》1998,182(1):65-72

Time series of two-dimensional spectra were taken with the Göttingen 2D spectrometer at the VTT on Tenerife in 1996. They were investigated for Doppler velocities and velocity oscillations in small spots and pores of rapidly evolving sunspot groups. For the present measurements the magnetically insensitive lines Fe i 557.6 nm and Fe i 709.0 nm were selected. Spots with penumbrae exhibit the Evershed effect. Some pores seem to be connected with downflows, but the centres of the downflows are somewhat displaced from their associated pores. The surroundings of the pores show red shifts relative to the whole field of view. The power in the 5-min range is reduced inside the spots and pores as well as in their immediate vicinity. This reduction inside the spots is in agreement with former results. Outside the area of the spot group the 5-min power has a patchy structure with a typical size of 5 arc sec. For periods below 3.3 min, the behaviour of individual spots and pores is different. Some spots show clearly enhanced power for these periods, and it remains high down to the Nyquist period at 1.5 min. The small pores do not show enhanced three-minute oscillations compared with their vicinity. Inside one spot we find a ring of enhanced power in the period range between 8 and 20 min corresponding to the time scales of granular variations. This result could be an indication of a relation between spots and convection, but magneto-accoustic waves are also possible. The same ring exhibits also enhanced power for short periods.  相似文献   

Deep-sea coral aragonite as a recorder for the neodymium isotopic composition of seawater     

Tina van de Flierdt  Laura F. Robinson 《Geochimica et cosmochimica acta》2010,74(21):6014-6032

Deep-sea corals have been shown to be useful archives of rapid changes in ocean chemistry during the last glacial cycle. Their aragonitic skeleton can be absolutely dated by U-Th data, freeing radiocarbon to be used as a water-mass proxy. For certain species of deep-sea corals, the growth rate allows time resolution that is comparable to ice cores. An additional proxy is needed to exploit this opportunity and turn radiocarbon data into rates of ocean overturning in the past.Neodymium isotopes in seawater can serve as a quasi-conservative water-mass tracer and initial results indicate that deep-sea corals may be reliable archives of seawater Nd isotopes. Here we present a systematic study exploring Nd isotopes as a water-mass proxy in deep-sea coral aragonite. We investigated five different genera of modern deep-sea corals (Caryophyllia, Desmophyllum, Enallopsamia, Flabellum, Lophelia), from global locations covering a large potential range of Nd isotopic compositions. Comparison with ambient seawater measurements yields excellent agreement and suggests that deep-sea corals are reliable archives for seawater Nd isotopes.A parallel study of Nd concentrations in these corals yields distribution coefficients for Nd between seawater and coral aragonite of 1-10, omitting one particular genus (Enallopsamia). The corals and seawater did however not come from exactly the same location, and further investigations are needed to reach robust conclusions on the incorporation of Nd into deep-sea coral aragonite.Lastly, we studied the viability of extracting the Nd isotope signal from fossil deep-sea corals by carrying out stepwise cleaning experiments. Our results show that physical removal of the ferromanganese coating and chemical pre-cleaning have the highest impact on Nd concentrations, but that oxidative/reductive cleaning is also needed to acquire a seawater Nd isotope signal.  相似文献