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1.
Chondrules and isolated forsterites in five low-subtype ordinary chondrites [NWA 3127 (LL3.1), Sahara 97210 (LL3.2), Wells (LL3.3), Chainpur (LL3.4), and Sahara 98175 (LL3.5)] were studied using petrographic, EMPA, and SIMS techniques to better constrain the origin of chondrules and the olivine grains within them. Our results imply that igneous crystallization, vapor fractionation, redox effects, and open-system behavior were important processes. All olivine grains, including normal, relict, and isolated forsterite grains, show evidence for igneous fractionation under disequilibrium conditions, with olivine crystallizing during rapid cooling (closer to 2000 °C/h than to 100 °C/h). Vapor fractionation is manifested by anti-correlated abundances between refractory elements (Al, Sc, Y, Ti, Ca, V) and volatile elements (Cr, Mn, P, Rb, Fe) in olivine. Redox effects are evidenced in various ways, and imply that Fe, Co, Ni, and P were partitioned more into metal, and V was partitioned more into olivine, under reducing conditions in the most FeO-poor melts. There is no obvious evidence for systematic variations in olivine composition according to meteorite subtype, but shock melting in Sahara 97210 resulted in the injection of glass-derived melt into olivine, resulting in artificially high abundances of Ba, Sr, Na, Ti, and some other incompatible elements in olivine. Terrestrial weathering in a hot desert environment may have mobilized Ba and Sr in some glasses.Our data suggest that chondrules in ordinary chondrites experienced repeated thermal, chemical, and mechanical processing during a “recycling” process over an extended time period, which involved multiple episodes of melting under fluctuating redox and heating conditions, and multiple episodes of chondrule break-up in some cases. Forsterite grains, including normal grains in forsterite-bearing type I chondrules, the cores of isolated forsterites, and relict forsterite in type II chondrules, all crystallized from similar, refractory melts under reducing conditions; relict Mg-olivine and isolated forsterite grains were thus derived from type I chondrules. Olivine in type II chondrules, including normal grains and ferroan overgrowths on relict Mg-olivine, crystallized from more volatile-rich, oxidized, and relatively unfractionated melts. Relict dusty olivine grains in type I chondrules were derived from type II chondrules during incomplete melting episodes involving reduction and some vaporization, with clear (non-dusty) grains in dusty olivine-bearing chondrules crystallizing from the reduced and partly vaporized melts. Melt compositions parental to normal olivine grains in type I and II chondrules are systematically enriched in refractory elements compared to bulk chondrule compositions, implying that chondrules often experienced open-system exchange with more volatile-rich surroundings after some olivine had crystallized, possibly while the chondrules were still partly molten. Type II chondrules could have been derived from type I chondrules by the addition of relatively volatile-rich material, followed by re-melting and little evaporation under oxidizing conditions. In contrast, type I chondrules could have been derived from type II chondrules by re-melting involving more-or-less evaporation under reducing conditions. Chemical, oxygen isotope, and petrographic data are best accommodated by a model in which there were several (>2-3, sometimes ?4-5) melting episodes for most chondrules in ordinary chondrites. 相似文献
2.
Three-dimensional visualization of mission planning and control forthe NPS autonomous underwater vehicle 总被引:1,自引:0,他引:1
Zyda M.J. McGhee R.B. Kwak S. Nordman D.B. Rogers R.C. Marco D. 《Oceanic Engineering, IEEE Journal of》1990,15(3):217-221
The Naval Postgraduate School (NPS) is constructing a small autonomous underwater vehicle (AUV) with an onboard mission control computer. The mission controller software for this vehicle is a knowledge-based artificial intelligence (AI) system requiring thorough analysis and testing before the AUV is operational. The manner in which rapid prototyping of this software has been demonstrated by developing a controller code on a LISP machine and using an Ethernet link with a graphics workstation to simulate the controller's environment is discussed. The development of a testing simulator using a knowledge engineering environment (KEE) expert system shell that examines AUV controller subsystems and vehicle models before integrating them with the full AUV for its test environment missions is discussed. This AUV simulator utilizes an interactive mission planning control console and is fully autonomous once initial parameters are selected 相似文献
3.
4.
This paper assesses the feasibility of applying remote sensing algorithms based on blue/green reflectance ratios to Case 2 waters. Two algorithms from the SeaDAS (NASA) image processing package, OC4v4 for surface chlorophyll concentration, Chl, and K(490) for the attenuation coefficient for downward irradiance at 490 nm, Kd(490), were investigated using an extensive set of observations from the Irish and Celtic Seas. In situ data from a profiling radiometer were used as inputs for the algorithms to avoid uncertainties in atmospheric correction procedures, and direct measurements of Chl and Kd490 and were used for validation purposes. The standard versions of the algorithms performed poorly: OC4v4 generally overestimated Chl (with a very low coefficient of determination), and K(490) progressively underestimated Kd490 for values greater than 0.3 m−1. A two-step procedure for level 2 product generation was therefore devised in which the numerical coefficients of OC4v4 and K(490) were tuned for the two optical water types known to occur most frequently in this region (McKee, D., Cunningham, A., 2006. Identification and characterisation of two optical water types in the Irish Sea from in situ inherent optical properties and seawater constituents. Estuarine, Coastal and Shelf Science 68, 305–316) by statistical regression on a data set of 102 stations from the Irish and Celtic Seas. The water types were distinguished by the magnitude of their normalised water leaving radiance signals at 665 nm, nLw(665), and appropriate versions of the tuned algorithms applied to each water type. When this procedure was tested on an independent data set of 19 stations from the Bristol Channel, Chl values were recovered with an RMS error of 0.36 mg m−3 and Kd(490) values with an RMS error of 0.095 m−1. The identification of water types from water-leaving radiance signals, and the application of band-ratio algorithms tuned for specific water types, may therefore provide a simple means of improving the quality of remote sensing products in optically complex shelf seas. 相似文献
5.
Vegetation change and surface elevation dynamics in estuarine wetlands of southeast Australia 总被引:1,自引:1,他引:1
Vertical accretion and surface elevation trends were studied in mangrove and saltmarsh wetlands in southeast Australia. A total of 69 surface elevation tables, each associated with three feldspar marker horizons, was deployed in 10 wetlands across 7 estuaries, and monitored for three years. Saltmarsh and mangrove vegetation distributions were mapped for the same estuaries, and elevation characteristics of the wetlands were modelled. Rates of vertical accretion were found to correlate with tidal range. No relationship was found between rates of vertical accretion and surface elevation increase. A positive relationship was demonstrated between contemporary rates of saltmarsh surface elevation change and longer-term rates of mangrove encroachment into saltmarsh. We conclude that landward mangrove encroachment may be facilitated by local factors contributing to saltmarsh compaction during drought conditions. 相似文献
6.
An energy balance model has been developed to investigate how the Martian atmospheric environment could influence a community of photosynthetic microorganisms with properties similar to those of a cyanophyte (blue-green algal mat) and a lichen. Surface moisture and soil nutrients are assumed to be available. The model was developed to approximate equatorial equinox conditions and includes parameters for solar and thermal radiation, convective and conductive energy transport, and evaporative cooling. Calculations include the diurnal variation of organism temperature and transpiration and photosynthetic rates. The influences of different wind speeds and organism size and resistivity are also studied. The temperature of organisms in mats less than a few millimeters thick will not differ from the ground temperature by more than 10°K. Water loss is actually retarded at higher wind speeds, since the organism temperature is lowered, thus reducing the saturation vapor pressure. Typical photosynthetic rates lead to the production of 10?6 to 10?7 mole O2 cm?2 day?1. 相似文献
7.
Bruce A. Paterson Graeme Rogers W. Edryd Stephens 《Contributions to Mineralogy and Petrology》1992,111(3):378-390
This study presents evidence to show that, in addition to preserving U–Pb isotope systematics, refractory zircons also preserve, at least in part, an inherited Sm–Nd isotope component. The zircons analyzed during this study were taken from the Strontian granitoid (NW Scotland). The inner intrusion of this composite pluton is known from a previous study to contain substantial U–Pb zircon inheritance, whereas the outer part has only minor inheritance. Zircons from the inner intrusion were found to have significantly lower Nd425 values than either their host rock, separated apatite or monazite. It is argued that this isotopic disequilibrium is due to the presence of an inherited Sm–Nd isotope component, rather than being due to a post-crystallization disturbance of the zircons. The preservation of inherted Sm–Nd isotopes within refractory zircons implies that they remain closed systems with respect to the diffusion of Sm and Nd (and presumably the other REE) to temperatures in excess of 700°C. The fact that zircons commonly have high Sm/Nd ratios, relative to sialic crustal material, means that the Nd isotopic evolution of inherited zircons will be very different to that of much of the continental crust. 相似文献
8.
Manuela A. Fehr Mark Rehkämper Alex N. Halliday Maria Schönbächler Bodo Hattendorf 《Geochimica et cosmochimica acta》2006,70(13):3436-3448
Tellurium isotope data acquired by multiple-collector inductively coupled plasma-mass spectrometry (MC-ICPMS) are presented for sequential acid leachates of the carbonaceous chondrites Orgueil, Murchison, and Allende. Tellurium isotopes are produced by a broad range of nucleosynthetic pathways and they are therefore of particular interest given the isotopic anomalies previously identified for other elements in these meteorites. In addition, the data provide new constraints on the initial solar system abundance of the r-process nuclide 126Sn, which decays to 126Te with a half-life of 234,500 years. The 126Te/128Te ratios of all leachates were found to be identical, within uncertainty, despite variations in 124Sn/128Te of between about 0.002 and 1.4. The data define a 126Sn/124Sn ratio of <7.7 × 10−5 at the time of last isotopic closure, consistent with the value of <18 × 10−5 previously reported for bulk carbonaceous chondrites. How close this is to the initial 126Sn/124Sn ratio of the solar system depends on when the investigated samples last experienced redistribution of Sn and Te. No clear evidence is found for nucleosynthetic anomalies in the abundances of p-, s-, and r-process nuclides. The largest effect detected in this study is a small excess of the r-process nuclide 130Te in a nitric acid leachate of Murchison. This fraction displays an anomalous ε130Te of +3.5 ± 2.5. Although barely resolvable given the analytical uncertainties, this is consistent with the presence of a small excess r-process component or an s-process deficit. The general absence of anomalies contrasts with previous results obtained for K, Cr, Zr, Mo, and Ba isotopes in similar leachates, which display nucleosynthetic anomalies of up to 3.8%. The reason for this discrepancy is unclear but it may reflect volatility and more efficient mixing of Te in the solar nebula. 相似文献
9.
Micro-spectroscopic investigations of highly heterogeneous waste repository materials 总被引:1,自引:0,他引:1
A.M. Scheidegger D. Grolimund C.R. Cheeseman R.D. Rogers 《Journal of Geochemical Exploration》2006,88(1-3):59
Assuring safe disposal and long-term storage of radioactive and toxic wastes corresponds to a primary environmental task of present societies. To improve any technical limitation, a mechanistic understanding of the processes governing the binding of heavy metals and radionuclides is required. In this study, the significance of synchrotron-based X-ray microprobes for elucidating the spatial distribution and the speciation of radionuclides in highly heterogeneous waste repository materials will be outlined. A case study on the uptake process of Co in cementitious engineered barrier materials exposed to microbial degradation will be presented. 相似文献
10.
This paper explores what happens when corporations engage explicitly in practices of organisational learning not only to become better capitalists by generating ever more innovative ways of maintaining profitability, improving competitiveness and maximising shareholder value, but also to become more responsible corporate citizens in their business practices. In particular, I evaluate the ways in which UK food and clothing retailers are learning to develop their ethical trading programmes in response to political calls for more responsible trading. Thrift’s [Thrift, N., 2005. Knowing Capitalism. Sage, London] notion of ‘knowledgeable, or soft, capitalism’ is adopted to understand the creative and experimental ways in which retailers and their mentors (ethical consultancies, social auditors and multi-stakeholder organisations) are learning to trade ethically. Two specific examples of formal learning spaces experienced by UK food and clothing retailers are examined: (i) training courses on social auditing and (ii) corporate awareness-raising courses on ethical trade. These courses are shown to encompass various participative and affective practices of learning. And while particular limits to the success of these courses are argued to exist, ethical learning practices discussed in this paper are nonetheless suggested to play a role in the making of new, albeit moderate, forms of responsible capitalism. 相似文献